A note on specific variability of long surface gravity waves and drag coefficient in coastal upwelling zone

In this paper we solve analytically wave kinematic equations and the wave energy transport equation, for basic long surface gravity wave in the coastal upwelling zone. UsingGent andTaylor's (1978) parameterization of drag coefficient (which includes interaction between long surface waves and the air flow) we find variability of this coefficient due to wave amplification and refraction caused by specific surface water current in the region. The drag coefficient grows towards the shore. The growth is faster for stronger current. When the angle between waves and the current is less than 90° the growth is mainly connected with the waves steepness, but when the angle is larger, it is caused by relative growth of the wave phase velocity.     

Seasonal acceleration of the rate of total ozone decreases over Central Europe: impact of tropopause height changes

Total ozone data from some European stations have been analyzed to detect the ozone decrease in different seasons from 1979 to 1995. The differences between the winter–spring (December–March) and summer (May–August) total ozone means have decreased distinctly during the last three decades, by 10 Dobson Units per decade, showing that the winter–spring decrease is significantly stronger than the summer one. Applying a multiple regression model to the monthly means of tropopause height, positive trends in the summer and winter–spring seasons have been found, especially since 1979. This corresponds to the accelerating ozone decrease then. The possibility of using tropopause height variations as an indicator of dynamical variability in the total ozone trend model is discussed. The total ozone response to the changes of tropopause height seems to be independent of timescale over which the tropopause-total ozone relationship has been examined (month-to-month, interannual). The total ozone trends, as well as the accelerated rate of ozone decrease since 1979 in the winter–spring and summer seasons, respectively, are reduced by about 0.5–1% per decade after inclusion of the tropopause height effect on the ozone model.     

Radio emission regions in pulsars

We study the concept of radius-to-frequency mapping using a geometrical method for the estimation of pulsar emission altitudes. The semi-empirical relationship proposed by Kijak &38; Gil is examined over three decades of radio frequency. It is argued that the emission region in a millisecond pulsar occupies the magnetosphere over a distance of up to about 30 per cent of the light-cylinder radius, and that in a normal pulsar occupies up to approximately 10 per cent of the light-cylinder radius.     

Stochastic models in the DORIS position time series: estimates for IDS contribution to ITRF2014

This paper focuses on the investigation of the deterministic and stochastic parts of the Doppler Orbitography and Radiopositioning Integrated by Satellite (DORIS) weekly time series aligned to the newest release of ITRF2014. A set of 90 stations was divided into three groups depending on when the data were collected at an individual station. To reliably describe the DORIS time series, we employed a mathematical model that included the long-term nonlinear signal, linear trend, seasonal oscillations and a stochastic part, all being estimated with maximum likelihood estimation. We proved that the values of the parameters delivered for DORIS data are strictly correlated with the time span of the observations. The quality of the most recent data has significantly improved. Not only did the seasonal amplitudes decrease over the years, but also, and most importantly, the noise level and its type changed significantly. Among several tested models, the power-law process may be chosen as the preferred one for most of the DORIS data. Moreover, the preferred noise model has changed through the years from an autoregressive process to pure power-law noise with few stations characterised by a positive spectral index. For the latest observations, the medians of the velocity errors were equal to 0.3, 0.3 and 0.4 mm/year, respectively, for the North, East and Up components. In the best cases, a velocity uncertainty of DORIS sites of 0.1 mm/year is achievable when the appropriate coloured noise model is taken into consideration.     

Effects of continuous flow centrifugation on measurements of trace elements in river water: intrinsic contamination and particle fragmentation

Continuous flow centrifugation (CFC) is a well‐established technique used in natural surface water studies to collect large amounts of suspended solids, thus allowing a broad spectrum of measurements. However, a potential contamination or changes in the particle size distribution during the centrifugation may restrain the use of CFC effluents for element analysis in the colloidal and dissolved fractions. In this paper we evaluate the possibility of using the effluent of a Westfalia centrifuge (type KA2‐06‐075, 9700 rpm) for such analysis. This evaluation is based on two laboratory experiments with deionized and tap water and two field experiments in rivers. Elemental concentration changes across the CFC were assessed from the CFC influent and effluent after a filtration at 0·45 µm. Significant increases were found, mainly in the field experiments at a high suspended solids level and a slightly acid pH. A hypothesis was made on the origin of these increases as a superposition of a centrifuge intrinsic contamination and a particle fragmentation effect. A numerical model based on elemental concentration measurements (inductively coupled plasma mass spectrometry) gave a particle fragmentation level of 0·55% (mass percentage of particles broken up into smaller fragments during centrifugation). In another experiment, a direct particle counting (single particle counter) shows an excess of particles smaller than 500 nm in the CFC effluent, corresponding to a fragmentation level of 0·11%. In consequence, the use of CFC effluent for element analysis is possible in low‐turbidity river or lake waters, but should be carefully considered in waters with high suspended matter contents. Copyright © 2006 John Wiley & Sons, Ltd.     

Measurements of biomarker levels in flounder (Platichthys flesus) and blue mussel (Mytilus trossulus) from the Gulf of Gdańsk (southern Baltic)

In the framework of the EU funded BEEP project a set of biomarkers, gross morphometric indices and tissue concentrations of selected organic pollutants were measured in flounder (Platichthys flesus) and mussels (Mytilus trossulus) collected twice a year (April and October) from three sites in the inner Gulf of Gdańsk between autumn 2001 and spring 2003. In flounder, seasonal differences in most biomarkers were observed, but no correlations with tissue pollutant levels could be found. In mussels, highly variable levels in biomarker responses were seen, but no clear seasonal or spatial trends, directly related to tissue concentrations, could be established. The observed biomarkers distribution the study sites are probably mostly caused by interannual, seasonal and individual variability and, in case of flounder, possibly by exchange of stocks between the sampling sites.     

Use of biliary PAH metabolites as a biomarker of pollution in fish from the Baltic Sea

During field campaigns of the BEEP project (Biological Effects of Environmental Pollution in Marine Coastal Ecosystems) in 2001-2002, metabolites of polycyclic aromatic hydrocarbons (PAHs) were determined in bile samples from three fish species, flounder (Platichthys flesus), perch (Perca fluviatilis) and eelpout (Zoarces viviparus), from four separate areas in the Baltic Sea. Two determination methods were applied: fixed wavelength fluorescence (FF) for pyrene-type metabolites and high-performance liquid chromatography with fluorescence detection (HPLC). There was a good correlation between the FF method and 1-OH pyrene determined by HPLC. Normalisation of the FF data for absorbance at 380 nm or bile protein concentrations greatly increased variance in one third and decreased it in two thirds of the cases and resulted in a loss of significant differences (protein normalisation) between the sampling stations, but normalisation of the HPLC data had little effect on the results. The biliary PAH metabolite content was usually higher in males than in females. In perch and eelpout the biliary PAH contents were at similar levels, whereas in flounder the levels were lower. The sampling areas arranged in decreasing order of biliary PAH contents were: Wismar Bay > Gulf of Gdansk > Lithuanian coast > Kvadofj?rden (reference area). It is concluded that FF with un-normalised data is a reliable and simple method for monitoring purposes and only one sex of a selected species should be used.