On the Effect of Surface Heat-Flux Heterogeneities on the Mixed-Layer-Top Entrainment

We used a set of large-eddy simulations to investigate the effect of one-dimensional stripe-like surface heat-flux heterogeneities on mixed-layer top entrainment. The profiles of sensible heat flux and the temporal evolution of the boundary-layer depth revealed decreased entrainment for small heat-flux amplitudes and increased entrainment for large heat-flux amplitudes, compared to the homogeneously-heated mixed layer. For large heat-flux amplitudes the largest entrainment was observed for patch sizes in the order of the boundary-layer depth, while for significantly smaller or larger patch sizes entrainment was similar as in the homogeneous case. In order to understand the underlying physics of this impact, a new approach was developed to infer local information on entrainment by means of the local flux divergence. We found an entrainment maximum over the centre of the stronger heated surface patch, where thermal energy is accumulated by the secondary circulation (SC) that was induced by the surface heterogeneity. Furthermore, we observed an entrainment maximum over the less heated patch as well, which we suppose is to be linked to the SC-induced horizontal flow convergence at the top of the convective boundary layer (CBL). For small heat-flux amplitudes a counteracting effect dominates that decreases entrainment, which we suppose is the horizontal advection of cold air in the lower, and warm air in the upper, CBL by the SC, stabilizing the CBL and thus weakening thermal convection. Moreover, we found that a mean wind can reduce the heterogeneity-induced impact on entrainment. If the flow is aligned perpendicular to the border between the differentially-heated patches, the SC and thus its impact on entrainment vanishes due to increased horizontal mixing, even for moderate wind speeds. However, if the flow is directed parallel to the border between the differentially-heated patches, the SC and thus its impact on entrainment persists.     

Phytoplankton, nutrients, and transparency in Danish coastal waters

We present a comparative analysis of 1400 data series of water chemistry (particularly nitrogen and phosphorus concentrations), phytoplankton biomass as chlorophylla (chla) concentrations, concentrations of suspended matter and Secchi depth transparency collected from the mid-1980s to the mid-1990s from 162 stations in 27 Danish fjords and coastal waters. The results demonstrate that Danish coastal waters were heavily eutrophied and had high particle concentrations and turbid waters. Median values were 5.1 μg chla 1⁻¹, 10.0 mg DW 1⁻¹ of suspended particles, and Secchi depth of 3.6 m. Chlorophyll concentration was strongly linked to the total-nitrogen concentration. The strength of this relationship increased from spring to summer as the concentration of total nitrogen declined. During summer, total nitrogen concentrations accounted for about 60% of the variability in chlorophyll concentrations among the different coastal systems. The relationship between chlorophyll and total phosphorus was more consistant over the year and correlations were much weaker than encountered for total nitrogen. Secchi depth could be predicted with good precision from measurements of chlorophyll and suspended matter. In a multiple stepwise regression model with In-transformed values the two variables accounted for most of the variability in water transparency for the different seasons and the period March–October as a whole (c. 80%). We were able to demonstrate a significant relationship between total nitrogen and Secchi depth, with important implications for management purposes.     

The structural state of iron in oxidized vs. reduced glasses at 1 atm: A57Fe Mössbauer study

A general model for the structural state of iron in a variety of silicate and aluminosilicate glass compositions in the systems Na₂O-Al₂O₃-SiO₂-Fe-O, CaO-Al₂O₃-SiO₂-Fe-O, and MgO-Al₂O₃-SiO₂-Fe-O is proposed. Quenched melts with variable Al/Si and NBO/T (average number of nonbridging oxygens per tetrahedrally coordinated cation), synthesized over a range of temperatures and values of oxygen fugacity, are analyzed with⁵⁷Fe Mössbauer spectroscopy. For oxidized glasses with Fe³⁺/∑Fe>0.50, the isomer shift for Fe³⁺ is in the range ～0.22–0.33 mm/s and ～0.36 mm/s at 298 K and 77 K, respectively. These values are indicative of tetrahedrally coordinated Fe^3?. This assignment is in agreement with the interpretation of Raman, luminescence, and X-ray,K-edge absorption spectra. The values of the quadrupole splitting are ～0.90 mm/s (298 K and 77 K) in the Na-aluminosilicate glasses and compare with the values of 1.3 mm/s and 1.5 mm/s for the analogous Ca- and Mg-aluminosilicate compositions. The variations in quadrupole splittings for Fe³⁺ are due to differences in the degree of distortion of the tetrahedrally coordinated site in each of the systems. The values of the isomer shifts for Fe²⁺ ions in glasses irrespective of Fe³⁺/∑Fe are in the range 0.90–1.06 mm/s at 298 K and 1.0–1.15 mm/s at 77 K. The corresponding range of values of the quadrupole splitting is 1.75–2.10 mm/s at 298 K and 2.00–2.35 mm/s at 77 K. The temperature dependence of the hyperfine parameters for Fe²⁺ is indicative of noninteracting ions, but the values of the isomer shift are intermediate between those values normally attributable to tetrahedrally and octahedrally coordinated Fe²⁺. The assignment of the isomer-shift values of Fe²⁺ to octahedral coordination is in agreement with the results of other spectral studies. For reduced glasses (Fe³⁺/∑Fe≈<0.50), the value of the isomer shift for Fe³⁺ at both 298 K and 77 K increases and is linearly correlated with decreasing Fe³⁺/∑Fe in the range of \(f_{O_2 } \) between 10^?3 and 10^?6 atm when a single quadrupole-split doublet is assumed to represent the absorption due to ferric iron. The increase in value of the isomer shift with decreasing \(f_{O_2 } \) is consistent with an increase in the proportion of Fe³⁺ ions that are octahedrally coordinated. The concentration of octahedral Fe³⁺ is dependent on the \(T - f_{O_2 } \) conditions, and in the range of log \(f_{O_2 } \) between 10^?2.0 and 10^?5 a significant proportion of the iron may occur as iron-rich structural units with stoichiometry similar to that of inverse spinels such as Fe₃O₄, in addition to isolated Fe²⁺ and Fe³⁺ ions.     

Calibration of estuarine current crosses

Tethered current crosses are simple, reliable tools in making measurements of estuarine currents in the absence of surface waves. The standard error of the estimate of current speed is less than 5 cm s^?1 for the particular crosses and weights used in a calibration experiment. The useful velocity range of these current crosses was 8–147 cm s^?1, corresponding to a measured angle, α, from 2° to 30°. Regression of the independently measured current speed on $\text{(tan α)}{}^{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}$ yielded coefficients of determination greater than 0·94, indicating that the drag coefficient is not a function of current speed. However, the calculated drag coefficients varied widely from 0·66 to 2·55, depending on the particular combination of cross and weight, varying drastically from the commonly assumed drag coefficient value of 1·12. Thus, in using current crosses, it is imperative to calibrate each cross against a current meter reading to determine an appropriate value for the drag coefficient for a particular current cross and weight.     

Formation of De Geer moraines and implications for deglaciation dynamics

De Geer moraines are very common in the Møre area, western Norway. These moraines occur below the marine limit and outside the Younger Dryas ice limit and occupy tributaries that connect the main fjords through the mountain passes. During deglaciation, ice in these tributaries flowed to the major ice streams. Sections across three De Geer moraines show that the ridges are composed of diamictons and fine-grained sediment, partly in stacked sequences. The diamicton units are interpreted as being composed of water-lain tills, lodgements tills and subaqueous flow deposits. The fine-grained sediment is though to have formed in a proglacial marine environment. Clast fabric of diamictons and deformation structures in underlying sands show that depositional directions for diamicton units and the direction of deformation for the sands is perpendicular to the ridge crests. Mainly based on this evidence, the ridges are thought to have formed by push at the glacier grounding line. The formation of transverse ridges (relative to ice flow) do occur in basal crevasses on modern glaciers, as do swarms of ridges along the front of retreating glaciers. The first mechanism of deposition does not seem to explain the ridges studied in the present paper and hence the importance of this process in the formation of De Geer moraines is questioned. The De Geer moraines were deposited by ice lobes advancing from one main fjord into another; therefore by studying the drainage pattern of the tributary lobes and their sequence of deglaciation, many features of the style of deglaciation of the ice sheet across the area can be determined. The northwestern part of the area was deglaciated earliest. After that, deglaciation proceeded to the southwest parallel to the coast. Subsequently the outer and the central part of Romsdalsfjorden were deglaciated causing ice to drain towards this fjord from both the north and south. The last fjord to be deglaciated was Storfjorden in the south.     

Are all maps mental maps?

The article focuses on the way in which map content reflects the cartographer's World view and system of values. Different World views are illustrated historically. Examples of topographical, land-use and vegetation maps from different parts of the World indicate the prevalence of Eurocentric perceptions in cartography. Different geological maps of Norden show how the visual image depends on the classification system adopted. All maps are mental maps in that their content is culturally determined and ethnocentric in origin.     

The evershed flow in the transition region chromosphere-photosphere

The Mgb₁ line profile is studied as a function of spatial position in the sunspot region. Comparing the wavelengths of the core and the wing, in and just outside the penumbra, a reversal in the shift is detected. The displacements of the core and the wing are interpreted as horizontal motions directed into the spot in the chromosphere and as a flow directed out of the spot in deeper layers.Systematic wavelength shifts are detected in the line core in some regions outside the penumbra. This is interpreted as a chromospheric velocity field usually directed horizontally away from the spot.     

A magnetostratigraphic comparison between 14C years and varve years during the Late Weichselian,indicating significant differences between the time-scales

A ¹⁴C-dated magnetostratigraphy of absolute declination and inclination between 12500 and 10000 ¹⁴C yr BP was recently developed for southern Sweden. Recently also the Swedish geochronological time-scale, based on c. 11 500 annually deposited clay-varves, was connected with the present. It should therefore be possible to compare the two chronologies with a reliable magnetostratigraphic record in an appropriate clay-varve section. We have found such a site within the Middle Swedish end-moraine zone. Statistical correlations between the two independently dated time-scales suggest that at 10500–10200 ¹⁴Cy r BP the varve chronology exceeds the ¹⁴C chronology by the order of 500-600 varve yr. Other correlations indicate that the difference between the two chronologies was less at 11000 ¹⁴C yr BP, and further correlations between the time-scales at 12000 ¹⁴C yr BP suggest that the difference between the chronologies increased steadily from 12000 to 10000 ¹⁴C yr BP. If these correlations are correct they imply that the ¹⁴C production rate increased steadily during the Late Weichselian.     

Velocity fields in quiescent prominences

Three quiescent prominences were observed in the Ca ii K-line and a fourth one also in the H-line at Oslo Solar Observatory, Harestua, and reduced by Rustad (1974) and by Engvold et al. (1980). These data are used to study the distribution of the line-of-sight velocity component, N(u ₀). It is pointed out that in a stationary and isotropic case, N(u ₀) should be a gaussian distribution. For each of the sets of measurements gaussians were therefore fitted by a least square procedure. The range in observed velocities varies considerably between the prominences. For the best observed prominence more than 70% of the kinetic energy is in the supersonic range. In the other cases none or only an insignificant part of the observations exceed the velocity of sound. Considerable deviations from gaussian distributions are apparent for the smallest velocities. This distortion shows up conspicuously in the slope of the energy spectrum, a parameter that may be used as a rough measure of spectral resolution.If it is assumed that we have to do with MHD-turbulence as described by Kraichnan (1965), a characteristic relationship should exist between velocity and eddy size. When supersonic velocities are present, compressibility effects may severely alter this relationship. The possibility of observational confirmation is discussed.If a turbulent velocity field is indeed present, the heat conductivity and other transport coefficients may be significantly altered as compared to the atomic values.