Tracer tests and the structure of permeability in the Corallian limestone aquifer of northern England, UK

The Corallian limestone of northern England (UK) is widely exploited for water supplies and exhibits the karstic phenomena of sinking rivers, conduit development and groundwater velocities of several kilometres per day. To test a number of model-derived source protection zones and elucidate contaminant transport mechanisms in the aquifer, three tracer tests were conducted from a set of swallow-holes draining the River Derwent toward public water supply wells in the eastern part of the aquifer. Tracers used included: Enterobacter cloacae (bacteriophage), Photine C (optical brightener), sodium fluorescein (fluorescent dye) and sulphur hexafluoride (dissolved gas), the varying properties of which make them suitable analogues for different types of potential contaminant. Observed tracer transport times and arrival patterns indicate that tracer transport occurs through karstic channels embedded in a network of primary fissures which exert control over tracer concentrations once initial tracer plumes have passed. A dipole flow system is observed between the swallow-holes and the closest abstraction well, whilst previously modelled source protection zones do not accurately reflect either groundwater velocity or those areas of the aquifer supplying the wells. These findings imply that managing such aquifers for potential contamination should rely upon empirical tracer evidence for source-protection zone modelling.     

对就地养老的反思——“人”与“地方”关系视角①

在有关养老的老年学和地理学研究中,“就地养老”是一个广泛使用的概念,并一直被认为是解决老龄人口养老需求的有效政策手段。迄今为止,关于就地养老的研究主要关注了很多能够让老年人健康就地(或在家)养老的物质方面的因素,比如住房条件或家庭照护。有些老年学研究者们认识到,就地养老受到居住环境中实体环境和社会、情感因素的共同影响。但我们认为,在养老体验研究中,要更加深入地审视“人”和“地方”之间的复杂关系。特别是,我们主张就地养老成功的因素是地方具有维持良好关系的潜力。提到“地方(place)”一词的时候,人们过分局限于关注老年人身体上接近的地理空间,或是具有实体边界的地方,例如房子或社区。而我们通过回顾现有文献发现,对许多选择就地养老的人来说,更具有意义的是随着时间的推移,他们在不同空间尺度上所建立起来的多元的、网络化的社会和非社会关系。基于这个新的视角,可以更好地理解老年人与地方的多层次的联系,以及从不同尺度和不同类型的人与地方的关系来考察就地养老的意义。     

New K-Ar ages,chemical analyses and magnetic data of rocks from the islands of santa maria (azores), porto santo and madeira (madeira archipelago) and gran canaria (Canary Islands)

K/Ar-determinations, major and trace element chemical analyses and magnetic data are reported for rocks from Santa Maria (Azores), Madeira and Porto Santo, and Gran Canaria. Based on these data, the age of the basement of Santa Maria is believed to have formed between about 5.2. and 4.6 m.y.; the unconformably overlying pillow complex interbedded with fossiliferous calcarenites about 3.8 to 3.3 m.y. with the capping subaerial basalt being part of the same magmatic phase. The major erosional phase levelling the basement is thus approximately synchronous with the major Pliocene regression (R2) on Gran Canaria (Lietz andSchmincke, 1975), possibly indicating a widespread eustatic event. The upper part of the submarine, partly fossiliferous series of Porto Santo was dated as ca. 12 to 13 m.y., and the Quaternary age for the major basalt formation in Eastern Madeira (Watkins andAbdel Monem, 1971) is confirmed. The ages of several formations on Gran Canaria were slightly revised. Chemical differences between basement (shield) and later posterosional series on Gran Canaria are re-emphasized by the new data, while such differences are much less pronounced between the basement and younger series on Santa Maria.     

Pedogenetic and diagenetic fabrics in the Upper Proterozoic Sarnyëré formation (Gourma, Mali)

Several diagenetic fabrics are described in the uppermost member of the Sarnyéré formation, an Upper Proterozoic dolomite (700-600 Ma). Micronodular micrite, microsparite showing nodulisation processes, orbicular crusts and oncoids are thought to be due to the pedogenetic alteration of an algal (Porostromata) boundstone. Further evolution in a vadose zone creates a network of cavities which are later filled by “cave stromatolites”, micropopcorn micrite and multilayered cements. A rhythmical repetition of facies evidences a polyphased pedogenetic history, leading to a 30 m thick highly complex section. Such numerous and diversified structures are rarely preserved, especially in Proterozoic rocks, but each of them have equivalents in recent examples of caliche soil profiles.     

The effect of willow control using a glyphosate formulation on aquatic invertebrates within a New Zealand wetland

Exotic trees, such as willow (Salix spp.), have become invasive around New Zealand waterways. Lowland wetlands in particular are vulnerable, with invasions changing hydrology and causing biodiversity loss. Applying herbicide to the willow canopy is a cost-effective control method, however uncertainty remains around effects on wetland aquatic invertebrates. Within a North Island, New Zealand, wetland, we conducted a paired before-after, control-impact study to determine if aerially applied glyphosate (with adjuvants) affected invertebrate assemblages. No effect on communities was detected during the first year after glyphosate treatment, however significant differences between control and spray-exposed communities were found during the second year, coinciding with a significant drought event in March 2013. By the third year, no statistically significant differences were found between communities from control and spray-exposed sites. This study suggests that glyphosate use, in comparable environments, is unlikely to affect aquatic invertebrates. Furthermore, the study illustrates invertebrate communities’ resilience to drought events.     

Radionuclides as tracers of water fronts in the South Indian Ocean—ANTARES IV Results

Anthropogenic ⁹⁰Sr, ^239,240Pu and ²⁴¹Am were used as tracers of water mass circulation in the Crozet Basin of the South Indian Ocean, represented by three main water fronts—Agulhas (AF), Subtropical (STF) and Subantarctic (SAF). Higher ⁹⁰Sr concentrations observed north of 43°S were due to the influence of AF and STF, which are associated with the south branch of the Subtropical gyre, which acts as a reservoir of radionuclides transported from the North to the South Indian Ocean. On the other hand, the region south of 43°S has been influenced by SAF, bringing to the Crozet Basin Antarctic waters with lower radionuclide concentrations. The ²³⁸Pu/^239,240Pu activity ratios observed in water and zooplankton samples indicated that, even 35 years after the injection of ²³⁸Pu to the Indian Ocean from the burn-up of the SNAP-9A satellite, the increased levels of ²³⁸Pu in surface water and zooplankton are still well visible. The radionuclide concentrations in seawater and their availability to zooplankton are responsible for the observed ²¹⁰Po, ^239,240Pu and ²⁴¹Am levels in zooplankton.     

Intercalibration of Mg Isotope Delta Scales and Realisation of SI Traceability for Mg Isotope Amount Ratios and Isotope Delta Values

The continuous improvement of analytical procedures using multi‐collector technologies in ICP‐mass spectrometry has led to an increased demand for isotope standards with improved homogeneity and reduced measurement uncertainty. For magnesium, this has led to a variety of available standards with different quality levels ranging from artefact standards to isotope reference materials certified for absolute isotope ratios. This required an intercalibration of all standards and reference materials, which we present in this interlaboratory comparison study. The materials Cambridge1, DSM3, ERM‐AE143, ERM‐AE144, ERM‐AE145, IRMM‐009 and NIST SRM 980 were cross‐calibrated with expanded measurement uncertainties (95% confidence level) of less than 0.030‰ for the δ^25/24Mg values and less than 0.037‰ for the δ^26/24Mg values. Thus, comparability of all magnesium isotope delta (δ) measurements based on these standards and reference materials is established. Further, ERM‐AE143 anchors all magnesium δ‐scales to absolute isotope ratios and therefore establishes SI traceability, here traceability to the SI base unit mole. This applies especially to the DSM3 scale, which is proposed to be maintained. With ERM‐AE144 and ERM‐AE145, which are product and educt of a sublimation–condensation process, for the first time a set of isotope reference materials is available with a published value for the apparent triple isotope fractionation exponent θ_app, the fractionation relationship ln α(^25/24Mg)/ln α(^26/24Mg).     

Middle Pleistocene (Saalian) lake outburst floods in the Münsterland Embayment (NW Germany): impacts and magnitudes

During the late Saalian Drenthe glaciation ice-damming of the Upper Weser Valley led to the formation of glacial Lake Weser. The lake drained catastrophically into the Münsterland Embayment as the western ice dam failed, releasing up to 110 km³ of water with a calculated peak discharge of 2.5 × 10⁵ m³/s to 1.3 × 10⁶ m³/s. Geographic information systems (GIS) and high-resolution digital elevation models (DEM) were used to map streamlined landforms and channel systems in front of lake overspills. Geological maps, 2450 boreholes and the DEM were integrated into the 3D modeling program GOCAD to reconstruct the distribution of flood-related deposits, palaeotopographic surfaces and the internal facies architecture of streamlined hills. The drainage pathways are characterized by the occurrence of deep plunge pools, channels, streamlined hills and 4 km long and 12 m deep V-shaped megaflutes. Plunge pools are deeply incised into Mesozoic basement rocks and occur in front of three major overspill channels. The plunge pools are up to 780 m long, 400 m wide and 35 m deep. Approximately 1–10.5 km downslope of the overspill channels fan shaped arrays of streamlined hills are developed, each covering an area of 60–130 km², indicating rapid flow expansion. The hills commonly have quadrilateral to elongated shapes and formed under submerged to partly submerged flow conditions, when the outburst flood entered a shallow lake in the Münsterland Embayment. Hills are up to 4300 m long, 1200 m wide, 11 m high and have characteristic average aspect ratios of 1:3.3. They are separated by shallow, anabranching channels in the outer zones and up to 30 m deep channels in the central zones. Hills partly display V-shaped chevron-like bedforms that have apices facing upslope, are 1.6–2.5 km long, 3–10 m high, 0.8–1.2 m from limb to limb, with limb separation angels of 20–35°. These bedforms are interpreted as mixed erosional depositional features. It is hypothesized that the post-Saalian landscape evolution of the Münsterland Embayment has considerably been influenced by catastrophic floods of glacial Lake Weser, creating large and deep valleys, which subsequently became the new site of river systems. The outburst floods probably followed the east-west-trending Saalian Rhine-Meuse river system eventually flowing into the North Sea, the Strait of Dover and the Bay of Biscay. It is speculated that the Hondsrug ice stream may have been enhanced or even triggered by the formation and outburst of glacial lakes in the study area.