The effects of oil exploration and production in the Fladen Ground: composition and concentration of hydrocarbons in sediment samples collected during 2001 and their comparison with sediment samples collected in 1989

Due to the potentially accumulative nature of the Fladen Ground, an area of intense oil activity in the North Sea, a survey was carried out in 1989 to map the distribution of contamination in relation to these oil activities. All the sediments collected were screened by ultraviolet fluorescence (UVF) for polycyclic aromatic hydrocarbons (PAHs) and selected samples were analysed for n-alkanes (by GC-FID), PAHs and biomarkers (by GC-MSD). This survey was repeated in 2001, with all the 1989 sites being resampled. All of these sediments were analysed for UVF oil equivalents, PAHs, n-alkanes and biomarkers. The concentrations of these parameters decreased between 1989 and 2001, with average decreases ranging from 43% to 88%. In addition, no significant difference was found, for all the parameters, between near field (<5 km from an oil installation) and far field (>5 km from an oil installation) sites in 2001 indicating that the Fladen Ground is approaching a 'steady state' or background concentration for contamination.     

Different levels of mussel (Mytilus edulis) DNA strand breaks following chronic field and acute laboratory exposure to polycyclic aromatic hydrocarbons

Levels of polycyclic aromatic hydrocarbons (PAHs) including benzo[a]pyrene (B[a]P) were at least seven-fold higher in mussels sampled from a polluted site (Loch Leven, in Scotland, UK) compared to a nearby clean reference site (Loch Etive) throughout the year 2000. Levels of DNA strand breaks (alkaline COMET assay) using both gill and digestive gland nuclei were similar at both sites despite the difference in contaminant load (total PAH). In contrast, mussels collected from a reference site (Port Quin, Cornwall, UK) had an increase in DNA strand breaks in digestive gland cells following laboratory exposure to B[a]P-dosed Isochrysis galbana. However, after 14 days high dose (20 ppb-exposed diet) animals had returned to levels similar to the controls. There was no evidence of increased necrosis or apoptosis after treatments. The results from these two studies suggest that an adaptive response may prevent ongoing DNA damage in mussels exposed to high levels of B[a]P and PAH contamination.     

Introduction: Toward More Inclusive and Comparative Perspectives in the Histories of Geographical Knowledge

Over the past three decades, feminist historiography of geography has begun to situate women's contribution to the production of geographical knowledge within the histories of geography, at times against the conviction of skeptical colleagues. In this Focus Section introduction, we renew Domosh's (1991a Domosh, M. 1991a. Beyond the frontiers of geographical knowledge. Transactions of the Institute of British Geographers 16 (4): 488–90.[Crossref], [Web of Science ®] , [Google Scholar], 1991b ———. 1991b. Toward a feminist historiography of geography. Transactions of the Institute of British Geographers 16 (1): 95–104.[Crossref], [Web of Science ®] , [Google Scholar]) call for creating more inclusive feminist histories of geography by situating the three focus section articles on the careers and contributions of women in twentieth-century geographical practice and knowledge production in the United Kingdom and the United States within wider debates about diverse, unfamiliar, and previously hidden aspects of geographical knowledge production. We argue that feminist historiography of geography and feminist historical geography could benefit from continuously diversifying inclusive and comparative research perspectives, and from unlocking diverse archives, to enhance understanding of why and how some male and some female gatekeepers have been more supportive of women than others.     

Implications from a field study regarding the relationship between polycyclic aromatic hydrocarbons and glutathione S-transferase activity in mussels

An aluminium smelter on the west coast of Scotland discharges an aqueous effluent containing polycyclic aromatic hydrocarbons (PAHs) at the head of Loch Leven. The loch also supports two mussel (Mytilus edulis) farms. Data are presented on burdens of PAHs in the soft tissues of mussels and the effect of these contaminants on glutathione S-transferase (GST) activity in mussel hepatopancreas. GST activity is shown to be correlated with total PAH burden and also with the concentrations of certain individual PAHs. These field data show that high molecular weight PAHs are closely correlated to GST activity, whereas low molecular weight PAHs are not. This suggests that 5- and 6-ring PAHs have a more pronounced role than 2- to 4-ring compounds in inducing GST activity in mussels from Loch Leven. It is proposed that it may be more appropriate to link GST activity with 5- and 6-ring compounds only, rather than with the total PAH burden.     

Decomposition of mineral absorption bands using nonlinear least squares curve fitting: Application to Martian meteorites and CRISM data

This study advances curve-fitting modeling of absorption bands of reflectance spectra and applies this new model to spectra of Martian meteorites ALH 84001 and EETA 79001 and data from the Compact Reconnaissance Imaging Spectrometer for Mars (CRISM). This study also details a recently introduced automated parameter initialization technique. We assess the performance of this automated procedure by comparing it to the currently available initialization method and perform a sensitivity analysis of the fit results to variation in initial guesses. We explore the issues related to the removal of the continuum, offer guidelines for continuum removal when modeling the absorptions and explore different continuum-removal techniques. We further evaluate the suitability of curve fitting techniques using Gaussians/Modified Gaussians to decompose spectra into individual end-member bands. We show that nonlinear least squares techniques such as the Levenberg–Marquardt algorithm achieve comparable results to the MGM model (Sunshine and Pieters, 1993, Sunshine et al., 1990) for meteorite spectra. Finally we use Gaussian modeling to fit CRISM spectra of pyroxene and olivine-rich terrains on Mars. Analysis of CRISM spectra of two regions show that the pyroxene-dominated rock spectra measured at Juventae Chasma were modeled well with low Ca pyroxene, while the pyroxene-rich spectra acquired at Libya Montes required both low-Ca and high-Ca pyroxene for a good fit.     

Evaluation of the importance of clay confining units on groundwater flow in alluvial basins using solute and isotope tracers: the case of Middle San Pedro Basin in southeastern Arizona (USA)

As groundwater becomes an increasingly important water resource worldwide, it is essential to understand how local geology affects groundwater quality, flowpaths and residence times. This study utilized multiple tracers to improve conceptual and numerical models of groundwater flow in the Middle San Pedro Basin in southeastern Arizona (USA) by determining recharge areas, compartmentalization of water sources, flowpaths and residence times. Ninety-five groundwater and surface-water samples were analyzed for major ion chemistry (water type and Ca/Sr ratios) and stable (¹⁸O, ²H, ¹³C) and radiogenic (³H, ¹⁴C) isotopes, and resulting data were used in conjunction with hydrogeologic information (e.g. hydraulic head and hydrostratigraphy). Results show that recent recharge (<60 years) has occurred within mountain systems along the basin margins and in shallow floodplain aquifers adjacent to the San Pedro River. Groundwater in the lower basin fill aquifer (semi confined) was recharged at high elevation in the fractured bedrock and has been extensively modified by water-rock reactions (increasing F and Sr, decreasing ¹⁴C) over long timescales (up to 35,000 years BP). Distinct solute and isotope geochemistries between the lower and upper basin fill aquifers show the importance of a clay confining unit on groundwater flow in the basin, which minimizes vertical groundwater movement.     

A comparative synoptic climatology of cool-season rainfall in major grain-growing regions of southern Australia

Two distinct synoptic weather systems, cut-off lows and fronts, deliver most of the cool-season rainfall to the cropping regions of southern Australia. A comparative synoptic climatology of daily rainfall events over approximately five decades reveals both spatial and temporal variations of the dominant synoptic types. The rainfall characteristics and associated large-scale drivers differ between the two synoptic types. Understanding regional rainfall depends on understanding these differences. Cut-off lows contribute one half of growing season rainfall in southeast Australia, while frontal systems associated with Southern Ocean depressions contribute about a third. The proportions are reversed in the Central Wheat Belt (CWB) of Western Australia where Southern Ocean fronts are the dominant source of growing season rainfall. In the southern island state of Tasmania, topography strongly influences the outcome with cut-off lows contributing about half the rainfall near the east coast and fronts dominating a short distance to the west. Cut-off lows generally contribute their highest proportion of rainfall in the austral autumn and spring while frontal rainfall is at its maximum in late winter. Cut-off low rainfall contributes more strongly in percentage terms to the recent decline in rainfall. The distribution of synoptic types is explained by the dominant long-wave structure in the winter half of the year. The major trough near Western Australia favours frontogenesis to the southwest of the CWB but fronts moving out of the region encounter a persistent meridional ridge in the Tasman Sea where there is a high frequency of blocking events.     

Hydrologic functioning of the deep critical zone and contributions to streamflow in a high‐elevation catchment: Testing of multiple conceptual models

High‐elevation mountain catchments are often subject to large climatic and topographic gradients. Therefore, high‐density hydrogeochemical observations are needed to understand water sources to streamflow and the temporal and spatial behaviour of flow paths. These sources and flow paths vary seasonally, which dictates short‐term storage and the flux of water in the critical zone (CZ) and affect long‐term CZ evolution. This study utilizes multiyear observations of chemical compositions and water residence times from the Santa Catalina Mountains Critical Zone Observatory, Tucson, Arizona to develop and evaluate competing conceptual models of seasonal streamflow generation. These models were tested using endmember mixing analysis, baseflow recession analysis, and tritium model “ages” of various catchment water sources. A conceptual model involving four endmembers (precipitation, soil water, shallow, and deep groundwater) provided the best match to observations. On average, precipitation contributes 39–69% (55 ± 16%), soil water contributes 25–56% (41 ± 16%), shallow groundwater contributes 1–5% (3 ± 2%), and deep groundwater contributes ~0–3% (1 ± 1%) towards annual streamflow. The mixing space comprised two principal planes formed by (a) precipitation‐soil water‐deep groundwater (dry and summer monsoon season samples) and (b) precipitation‐soil water‐shallow groundwater (winter season samples). Groundwater contribution was most important during the wet winter season. During periods of high dynamic groundwater storage and increased hydrologic connectivity (i.e., spring snowmelt), stream water was more geochemically heterogeneous, that is, geochemical heterogeneity of stream water is storage‐dependent. Endmember mixing analysis and ³H model age results indicate that only 1.4 ± 0.3% of the long‐term annual precipitation becomes deep CZ groundwater flux that influences long‐term deep CZ development through both intercatchment and intracatchment deep groundwater flows.     

Comparative dating of a Bison-bearing late-Pleistocene deposit,Térapa,Sonora, Mexico

A recently discovered Bison-bearing fossil locality at Térapa, Sonora, Mexico, had previously been dated to 440 ± 130 ka using whole rock ⁴⁰Ar/³⁹Ar on a basalt flow that impounds the deposit. This age is considerably older than the accepted age of about 240–160 ka for the migration of Bison into greater North America. The Térapa deposit also contains a mixture of fossils from extralimital or extinct tropical animals and temperate animals. Constraining the age of the deposit is critical to interpret the paleontologic and paleoclimatologic implications of this unique Sonoran fossil locality. Three additional geochronological methods have been applied to this deposit (infrared stimulated luminescence (IRSL), amino acid racemization (AAR), and radiocarbon) and the data from the original ⁴⁰Ar/³⁹Ar age were revisited. The IRSL data suggest that the impounding basalt flow and the sediments that abut it were emplaced 43 ka ago and that the oldest sediments were deposited shortly after. Two radiocarbon ages suggest the fossiliferous sediments were emplaced by 42 ka. Effective diagenetic temperatures inferred from the AAR results, combined with AAR data from a similar-age deposit in southern Arizona, are in accordance with the 40–43 ka age estimates. For the AAR results to corroborate the ⁴⁰Ar/³⁹Ar age, the effective diagenetic temperature for the area would need to be approximately 3 °C, which is unrealistically low for northern Mexico. The new geochronological results suggest the Térapa deposit and fossils are 40–43 ka old. The anomalously old ⁴⁰Ar/³⁹Ar age for the impounding basalt is probably the result of low ⁴⁰Ar* concentrations and inherited ⁴⁰Ar.     

Late Holocene paleohydrology of Kluane Lake, Yukon Territory, Canada

We have gained new insight into the dynamic late Holocene paleohydrology and paleolimnology of Kluane Lake by reconstructing lakewater δ¹⁸O using sediment cellulose as an oxygen-isotope archive. Our data suggest that the lake was regularly open hydrologically between 5000 and 1000 cal year BP, although with substantially lower water levels and with greater evaporative loss in relation to inflow than under contemporary conditions. During part of this period the lake was meromictic and may have undergone intermittent hydrologic closure, but southward drainage to the Pacific Ocean via the Alsek River system was generally maintained. Isotopic evidence confirms that Kluane Lake underwent complete hydrologic closure 430–300 cal year BP (AD 1520–1650) after a major advance of Kaskawulsh Glacier blocked southward drainage. Closure persisted as the lake overtopped the Duke River fan, initiating northward drainage to the Bering Sea via the Yukon River system. Although incision of the new outlet channel led to a rapid decline in lake level, northward discharge via the Kluane River has been maintained for the past three centuries because of abundant inflow from the Slims River. Substantial quantities of glacial meltwater and seasonal runoff continue to drain via the Slims River from Kaskawulsh Glacier and its catchment in the St. Elias Mountains. During this period Kluane River has also become an important route for migrating anadromous salmon. The modern isotope hydrology of Kluane Lake confirms that its current positive water balance is highly dependent on discharge from Slims River. Declining glacial meltwater contributions to Slims River will likely lead to lower water levels in Kluane Lake over the coming decades and possible re-establishment of intermittent or perennial hydrologic closure.