Layered ultramafic-gabbro bodies in the Lewisian of northwest Scotland: geochemistry and petrogenesis

Layered ultramafic-gabbro bodies occur widely in the Archaean of northwest Scotland. They were metamorphosed at granulite or high amphibolite facies and were tectonically thinned and broken up during deformation. They comprise repeated ultramafic-gabbro layers, locally with Ni-poor sulphide-rich tops, each rhythmic unit showing decreasing MgO, Ni and normative anorthite with stratigraphic height. Major, trace and rare earth element data are presented for the range of rock types. In ultramafic rocks, MgO varies from 22 to 37 wt.%, Ni from 1000 to 2500 ppm and TiO₂ from 0.08 to 0.40 wt.%, while the MgO content of the gabbros ranges from 14 to 6 wt.%. The REE patterns are flat to LREE enriched with no significant Eu anomalies. In ultramafic rocks REE are from 4 to 10 times chondrite, and in the gabbros LREE range from 8 to 30 times chondrite and HREE from 6 to 15 times chondrite. Study of incompatible elements (Ti, Zr, Y) which are relatively immobile during metamorphism shows that neither garnet nor hornblende were involved in fractionation. Trace element modelling shows it is improbable that the ultramafic rocks represent primary MgO-rich liquids even though their incompatible element contents are quite high. The chemical trends are interpreted in terms of olivine and pyroxene settling from a tholeiitic high-Mg magma with 15–20 wt.% MgO derived by 30–40% partial melting of an undepleted mantle. The ultramafic rocks are the cumulates and the gabbros the derived liquids.     

The role of horizontal resolution in simulating drivers of the global hydrological cycle

The role of atmospheric general circulation model (AGCM) horizontal resolution in representing the global energy budget and hydrological cycle is assessed, with the aim of improving the understanding of model uncertainties in simulating the hydrological cycle. We use two AGCMs from the UK Met Office Hadley Centre: HadGEM1-A at resolutions ranging from 270 to 60 km, and HadGEM3-A ranging from 135 to 25 km. The models exhibit a stable hydrological cycle, although too intense compared to reanalyses and observations. This over-intensity is explained by excess surface shortwave radiation, a common error in general circulation models (GCMs). This result is insensitive to resolution. However, as resolution is increased, precipitation decreases over the ocean and increases over the land. This is associated with an increase in atmospheric moisture transport from ocean to land, which changes the partitioning of moisture fluxes that contribute to precipitation over land from less local to more non-local moisture sources. The results start to converge at 60-km resolution, which underlines the excessive reliance of the mean hydrological cycle on physical parametrization (local unresolved processes) versus model dynamics (large-scale resolved processes) in coarser HadGEM1 and HadGEM3 GCMs. This finding may be valid for other GCMs, showing the necessity to analyze other chains of GCMs that may become available in the future with such a range of horizontal resolutions. Our finding supports the hypothesis that heterogeneity in model parametrization is one of the underlying causes of model disagreement in the Coupled Model Intercomparison Project (CMIP) exercises.     

The scramble for the Waste Lands: Tracking colonial legacies,counterinsurgency and international investment through the lens of land laws in Burma/Myanmar

This article traces the revenue category and legal concept of the Waste Land in Burma/Myanmar from its original application by the British colonial apparatus in the nineteenth century, to its later use in tandem with Burma Army counterinsurgent tactics starting in the 1960s, and finally to the 2012 land laws and current issues in international investment. This adaptation of colonial ideas about territorialization in the context of an ongoing civil war offers a new angle for understanding the relationship between military tactics and the political economy of conflict and counterinsurgent strategies which crucially depended on giving local militias—both government and nongovernment—high degrees of autonomy. The recent government changes, including the more civilian representation in parliament and its shift to engage with Western economies, raise questions regarding the future of the military, as well as local autonomy and the rural peasantry's access to land. As increasing numbers of international investors are poised to enter the Myanmar market, this article will revisit notions of land use and appropriation, and finally the role of the army and its changing relationship with Waste Lands.     

Long-term changes in polychaete assemblages of Botany Bay (NSW, Australia) following a dredging event

The long-term effects of marine aggregate dredging on near-shore benthic assemblages are still largely unknown, despite a global increase in demand for, and extraction of, marine aggregates. This study assessed the state of recovery of polychaete assemblages in Botany Bay, temperate NSW, Australia, at sites dredged for aggregate material more than 10 years previously. Sedimentary and faunal samples were collected from impact sites in Botany Bay, and from reference sites in nearby Pittwater estuary. This study was based on, and included data from, a study conducted by the Australian Museum at the same sites in the 2 years following cessation of dredging. Abundance, species richness and evenness of polychaetes, as well as overall polychaete assemblage structure, were compared between localities over time.     

Textural history of recent basaltic-andesites and plutonic inclusions from Merapi volcano

Mt. Merapi in Central Java is one of the most active stratovolcanoes on Earth and is underlain by a multistage plumbing system. Crystal size distribution analyses (CSD) were carried out on recent Merapi basaltic-andesites and co-eruptive magmatic and plutonic inclusions to characterise the crystallisation processes that operate during storage and ascent and to obtain information on respective time scales. The basaltic-andesites exhibit log-linear, kinked-upwards CSD curves for plagioclase and clinopyroxene that can be separated into two main textural populations. Large plagioclase phenocrysts (≥1.6 mm) make up one population, but correspond to crystals with variable geochemical composition and reflect a period of crystal growth at deep to mid-crustal levels. This population was subsequently influenced by crystal accumulation and the onset of crustal assimilation, including the incorporation of high-Ca skarn-derived xenocrysts. Textural re-equilibration is required for these crystals to form a single population in CSD. A second episode of crystal growth at shallower levels is represented by chemically homogenous plagioclase crystals <1.6 mm in size. Crustal assimilation is indicated by, for example, oxygen isotopes and based on the CSD data, crystallisation combined with contamination is likely semi-continuous in these upper crustal storage chambers. The CSD data observed in the basaltic-andesite samples are remarkably consistent and require a large-volume steady state magmatic system beneath Merapi in which late textural equilibration plays a significant role. Plagioclase CSDs of co-eruptive magmatic and plutonic inclusions may contain a third crystal population (<1 mm) not found in the lavas. This third population has probably formed from enhanced degassing of portions of basaltic-andesite magma at shallow crustal levels which resulted in increased crystallinity and basaltic-andesite mush inclusions. A suite of coarse plutonic inclusions is also present that reflects crystallisation and accumulation of crystals in the deep Merapi plumbing system, as deduced from CSD patterns and mineral assemblages.     

Fe isotopic fractionation during mineral dissolution with and without bacteria

Fe released into solution is isotopically lighter (enriched in the lighter isotope) than hornblende starting material when dissolution occurs in the presence of the siderophore desferrioxamine mesylate (DFAM). In contrast, Fe released from goethite dissolving in the presence of DFAM is isotopically unchanged. Furthermore, Δ⁵⁶Fe_{solution-hornblende} for Fe released to solution in the presence of ligands varies with the affinity of the ligand for Fe. The extent of isotopic fractionation of Fe released from hornblende also increases when experiments are agitated continuously. The Fe isotope fractionation observed during hornblende dissolution with organic ligands is attributed predominantly to retention of ⁵⁶Fe in an altered surface layer, while the lack of isotopic fractionation during goethite dissolution in DFAM is consistent with the lack of an altered layer. When a siderophore-producing soil bacterium is added to the system (without added organic ligands), Fe released to solution from both hornblende and goethite differs isotopically from Fe in the bulk mineral: Δ⁵⁶Fe_{solution-starting material} = −0.56 ± 0.19 (hornblende) and −1.44 ± 0.16 (goethite). Increased isotopic fractionation is attributed in this case to the fact that as bacterial respiration depletes the system in oxygen and aqueous Fe is reduced, equilibration between aqueous ferrous and ferric iron creates a pool of isotopically heavy ferric iron that is assimilated by bacterial cells. Adsorption of isotopically heavy ferrous iron (Fe(II) enriched in the heavier isotope) or precipitation of isotopically heavy Fe minerals may also contribute to observed fractionations.To test whether these Fe isotope signatures are recorded in natural systems, we also investigated extractions of samples of soils from which the bacteria were isolated. These extractions show variability in the isotopic signatures of exchangeable Fe and Fe oxyhydroxide fractions from one soil sample to another, but exchangeable Fe is observed to be lighter than Fe in soil Fe oxyhydroxides and hornblende. This observation is consistent with isotopically light Fe-organic complexes in soil pore water derived from the Fe-silicate starting materials in the presence of growing microorganisms, as documented in experiments reported here. The contributions from phenomena including organic ligand-promoted nonstoichiometric dissolution of Fe silicates, uptake of ferric iron by organisms, adsorption of isotopically heavy ferrous iron, and precipitation of iron minerals should create complex isotopic signatures in soils. Better understanding of these processes and the timescales over which they contribute to fractionation is needed.