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961.
Yuan-Bao Wu John M. Hanchar Shan Gao Paul J. Sylvester Mike Tubrett Hua-Ning Qiu Jan R. Wijbrans Fraukje M. Brouwer Sai-Hong Yang Qi-Jun Yang Yong-Sheng Liu Hong-lin Yuan 《Earth and Planetary Science Letters》2009,277(3-4):345-354
In situ LA-ICPMS U-Pb, trace element, and Hf isotope data in zircon demonstrate a Carboniferous age for eclogite-facies metamorphism in Siluro-Devonian protoliths in the Huwan shear zone, Dabie Mountains, Central China. This age contrasts with the more prevailing Triassic age for high- to ultrahigh pressure (HP to UHP) metamorphism in the Qinling-Dabie-Sulu orogen. Metamorphic zircon in two eclogite samples from Sujiahe is characterized by low Th/U ratios, small negative Eu anomalies, flat HREE patterns, and low 176Lu/177Hf ratios. These geochemical signatures suggest that the zircon crystallized in the presence of garnet and in the absence of plagioclase feldspar. Furthermore, temperatures of ~ 655 and ~ 638 °C, calculated using the Ti content of zircon, are consistent with their formation during eclogite-facies metamorphism. The weighted mean 206Pb/238U age of 309 ± 4 Ma (2δ) for this zircon improves previous age estimates for eclogite-facies metamorphism in the Huwan shear zone, ranging from 420 to 220 Ma. Metamorphic zircon from one eclogite sample from Hujiawan, most likely formed during prograde metamorphism, yields an equivalent age estimate of 312 ± 11 Ma. Magmatic zircon cores in the three samples yield ages for the magmatic protoliths of the eclogites ranging from 420 ± 7 to 406 ± 5 Ma, and post-dating the middle Paleozoic collision of the North China and the Qinling terrain. The zircon crystals in the three eclogite samples display a large variation of εHf (t) values of ? 4.9 to 21.3. The metamorphic zircon overgrowths show the same range of εHf (t) values as those of the inherited magmatic crystal interiors. This suggests that the metamorphic zircon overgrowths may have formed by dissolution-reprecipitation of pre-existing magmatic zircon thereby preserving their original Hf isotopic composition. The high εHf (t) values suggest that the protoliths were derived from depleted mantle sources, most likely Paleotethyan oceanic crust; while the low εHf (t) values are attributed to crustal contamination. Some eclogites in the Huwan shear zone have a distinctive signature of continental crust most probably derived from the Yangtze Craton. The coexistence of Paleozoic oceanic crust and Neoproterozoic continental crust with similar metamorphic ages in the Huwan shear zone implies that Paleozoic Paleotethyan oceanic crust was produced within a marginal basin of the northern Yangtze Craton. The opening of the Paleo-Tethyan ocean was slightly younger than the collision of the North China Craton and the Qinling terrain during the Late Paleozoic in the Qinling-Dabie-Sulu orogen. Subduction of the Paleo-Tethyan oceanic crust and associated continental basement resulted in the 309 ± 2 Ma (2σ) eclogite-facies metamorphism in the Huwan shear zone. The subsequent Triassic continent-continent collision led to the final coalescence of the Yangtze and Sino-Korean cratons. Amalgamation of the Yangtze and North China cratons was, therefore, a multistage process extending over at least 200 Ma. 相似文献
962.
Jan C. M. de Hoog Manfred J. van Bergen 《Contributions to Mineralogy and Petrology》2000,139(4):485-502
Potassium-rich calc-alkaline lavas of Lewotolo volcano, situated in the East Sunda Arc, Indonesia, contain the rare mineral
zirconolite (CaZrTi2O7). Samples in which tiny grains of this mineral (3–25 μm in size) were found span the entire range of lava compositions (47–62 wt%
SiO2). To the best of our knowledge, this is the first record of primary zirconolite in juvenile arc volcanics. The mineral forms
part of a vesicle-filling assemblage consisting of a network of quenched feldspar crystals and an SiO2 phase, probably cristobalite. High contents of Th, U and REE (up to 9.3, 4.3 and 15.6 wt% oxide respectively) and very high
Fe contents (up to 13.5 wt% Fe2O3) distinguish these zirconolites from those of other rock types. The extraction of volatile-rich phases with changing compositions
in successive stages is considered to be responsible for the zirconolite formation. We hypothesise that a fluid capable of
transporting HFSE, REE, Th and U was extracted from the magma and (partly) crystallised within voids which had formed earlier
upon saturation of an aqueous fluid. Assuming that zirconolite compositions largely reflect trace metal contents of the coexisting
fluid phase, significant amounts of `immobile' elements must have been transported on a macroscopic scale. Our findings thus
point to a late-stage transfer of HFSE, REE, Th and U between different domains in a cooling magma body. Such a volatile-induced
redistribution of trace elements at shallow levels of high-K volcanic systems may be significant for conventional geochemical
modelling of magma evolution and for Th–U disequilibrium studies.
Received: 3 November 1999 / Accepted: 29 February 2000 相似文献
963.
The fossil H chondrite Brunflo, found in a slab of Ordovician limestone from central Sweden, is pervasively altered to an assemblage dominated by calcite and barite. The meteorite is surrounded by a 15–20 cm wide zone of lighter colors than the unaffected limestone due to dissolution of hematite. Here we present detailed geochemical analyses of two meteorite samples, 14 limestone samples at distances from 0 to 29 cm along two profiles from the meteorite, and a reference sample of Brunflo limestone. Element concentrations in Brunflo and surrounding bleached limestone have been strongly disturbed during two stages of alteration (early oxygenated and deep burial). In the meteorite, the Ni/Co ratio has changed from an initial value of 20 to 0.8 and redox sensitive elements like V, As, Mo, Re and U are strongly enriched. The sulfur isotope composition of barite from Brunflo (δ34S=+35‰) indicates initial loss of meteoritic sulfide, followed by later accumulation of sea water sulfate as barite. During deep burial under more reducing conditions, reduction processes supported by an externally derived reductant possibly derived from alum shale underlying the limestone, were largely responsible for the observed redox phenomena. In spite of massive redistribution of many elements, concentrations of Pt, Ir and Au remain at chondritic levels. The geochemistry and mineralogy of alteration determined for Brunflo are similar to those in “reduction spots” in red beds, where accumulation of a similar suite of elements (except Mo, Re) occurred as a result of isolated reduction activity. 相似文献
964.
三峡库区奉节县宝塔坪小区大型复杂滑坡特征及成因机制 总被引:12,自引:1,他引:11
奉节县新城宝塔坪小区的地质灾害问题是当前学术界关注的焦点,也是库区具有普遍性问题。本文首次提出,在小区发育有5个复杂结构的滑坡。滑坡具3种成因:(1)碎裂-溶蚀-杏黄色泥质条带发育-滑坡;(2)碎裂-溶蚀-T2b^2粉砂质泥岩顶层泥化-滑坡;(3)T2b^4泥岩溶蚀-滑坡。岩溶蚀作用为主导作用。断裂的发育为溶蚀作用提供了通道。 相似文献
965.
Mark Dyer Erwin van Heiningen Jan Gerritse 《Geotechnical and Geological Engineering》2000,18(4):313-334
Historic spillages of chlorinated hydrocarbons at a vinyl chloride plant in the Rotterdam–Botlek area in The Netherlands has lead to deep-seated pollution of the underlying aquifer. The principal pollutant is 1,2-dichloroethane (1,2-DCA). As a temporary measure, the contamination is being contained using a pump and treat system. In the long term, in-situ bioremediation has been proposed using a biologically active zone where pollutants would be dechlorinated by microorganisms that simultaneously degrade other carbon sources. In order to investigate the suitability of this new technology, a programme of laboratory tests was carried out. The laboratory programme involved a series of anaerobic soil column tests, where the selection and delivery of different carbon substrates that stimulated 1,2-DCA dechlorination were investigated. The soil columns were prepared using soil and groundwater samples from boreholes. Groundwater was flushed through the columns under anaerobic conditions. A comparison was made between the transformation of 1,2-DCA without a carbon substrate and in the presence of sugars (molasses) and alcohol (methanol) respectively. In addition, different modes of delivery were investigated. In the case of molasses, the material was injected into the column as a plug to simulate grout injection in the field, whereas methanol was delivered as a constant flow dissolved in the influent. Both carbon substrates resulted in the biotransformation of 1,2-DCA. However, fermentation of molasses produced secondary effects that led to a drop in pH and an excessive production of carbon dioxide, which temporarily blocked the flow of groundwater. 相似文献
966.
967.
The western part of the Bohemian Massif has played an exceptional role in recent geodynamic activity of the region. It is characterised by repeated occurrences of earthquake swarms and by other manifestations of deep tectonic processes (CO
2
emissions, anomalous
3
He content, mineral waters, mofettes, etc.). The purpose of this paper is to introduce some other intraplate regions with earthquake swarm occurrence (French Massif Central; Colli Albani and Vulsini Mts., central Italy; Southern Apennines, Italy; the Danville and Long Valley regions, California; central Arkansas), and with artificially induced earthquake swarms (Larderello, Italy, geothermal field; Coso, California, geothermal field; NE Bavaria, Germany, deep drilling project). Although these areas represent different tectonic environments, the manifestations of recent geodynamic and/or man-made activity are similar in many aspects. This coincidence most probably issues from a common cause of both tectonic and artificially induced earthquake swarms – intrusions/injections of fluids. Since the regions with earthquake swarm occurrence of tectonic origin are situated as a rule in the close neighbourhood of Quaternary volcanoes, the intruding fluids seem to be derived from magma recently transported to upper crustal layers. 相似文献
968.
Čermák Vladimír Šafanda Jan Krešl Milan Dědeček Petr Bodri Louise 《Studia Geophysica et Geodaetica》2000,44(3):430-441
Long-term (1961 – 1996) meteorological air temperature series together with the reconstructed ground surface temperature histories, obtained by inverting borehole temperature-depth profiles, were used to project regional patterns of the recent (climate) warming rate on the territory of the Czech Republic. The characteristic magnitude of the warming rate of 0.02 –0.03 K/yr was confirmed by the results of several years of monitoring the temperature in two experimental boreholes. The monitoring of shallow temperatures at depths of about 30 –40 m, i.e. below the reach of the seasonal surface temperature variations, can serve as an alternative tool of direct quantitative assessment of the present warming rate. The data also seem to sustain a potential man-made component contributing to the more pronounced recent warming rate observed in the areas of large agglomeration. 相似文献
969.
Růžek Bohuslav Zedník Jan Klíma Karel Ruprechtová Libuše 《Studia Geophysica et Geodaetica》2000,44(2):175-187
The routine location of regional seismic events using data from the Czech National Seismological Network (CNSN) is based on Pn, Pg, Sn, Sg phases. A simple velocity model derived from Kárník's (1953) interpretation of an earthquake in Northern Hungary in 1951 has hitherto been used. At present, numerous local seismic networks record and locate local events, which are occasionally recorded at regional distances as well. Due to the relatively small dimensions of local networks, hypocenters (and origin times) determined by a local network might be considered as nearly exact from the point of view of regional-scale CNSN. The comparison of common locations performed by CNSN and by a local network enables us to estimate the accuracy of CNSN locations, as well as to optimize a simple velocity model. The joint interpretation of the CNSN bulletin and the catalogues of four local seismic networks WEBNET, OSTRAVA, KLADNO and LUBIN produced a new ID velocity model. The most frequent epicentral error in this model is less than 5 km, and most foci lie up to 15 km from the true position. The performed analysis indicates bimodal distribution of Sn residuals. 相似文献
970.