Deep-seated gravitational slope deformations and their influence on consequent mass movements (case studies from the highest part of the Czech Carpathians)

Gravitational spreading of mountain ridges displays primary disequilibrium of flysch mountain areas of the Czech Carpathians. The progression of various types of mass movements is a product of long-term ridge disintegration and is predisposed by the geological structure of the area and the upper Tertiary-Quaternary morphogenesis of the mountain area. Deep-seated slope deformations are spatially interconnected by the occurrence of some other types of slope deformations (e.g. debris flows, debris slides, slumps, rock avalanches, etc.), which pose a considerable risk for the existence of human society. An important causative factor in these dynamically developing hazardous processes is, among other factors, the way in which land has been used in the last three centuries. Therefore, the occurrence of various types of slope deformations is studied in terms of their relation to deep-seated gravitational deformations and in terms of other limiting factors (structural geological, morphological and climatic factors, manmade impacts, etc.). The paper presents several case studies of slope deformations (Velká Čantoryje Mt, Lysá hora Mt, Ropice Mt and Smrk Mt) in the area of the Outer Carpathians within the territory of the Czech Republic and also adverts to some consequences in terms of the socioeconomic structure of the landscape.     

New chitinozoans from the historical type area of the Hirnantian Stage and additional key sections in the Wye Valley,Wales, UK

The type locality for several core elements of the Hirnantia brachiopod fauna is a small disused quarry on the western slopes of Cwm Hirnant. There, the Hirnant Limestone Member of the Foel‐y‐Ddinas Mudstone Formation yields a new, well‐preserved chitinozoan assemblage, attributed to the Spinachitina taugourdeaui Biozone. This allows tight correlation with the Hirnantian of Baltica and Laurentia and neatly ties the chitinozoan zonation with the classical brachiopod fauna. Nearby, the chitinozoan assemblage from the Caradoc Cymerig Limestone Member at Gelli‐grîn belongs to the Spinachitina cervicornis Biozone?, and is identical to that recovered from the Burrellian in the Onny Valley, Welsh Borderland. A Silurian assemblage higher up section, discovered in the Cwm‐yr‐Aethnen Formation, is attributed to the globally recognized Eisenackitina dolioliformis Biozone. Attempts to integrate the chitinozoan and graptolite biozonation, in the central Welsh Rhayader area, were less successful. Copyright © 2008 John Wiley & Sons, Ltd.     

Leaching capabilities of iodine monochloride (ICl) and diethylenetriamine pentaacetic acid (DPTA) at different concentrations and pH for some major and trace metals from coal and coal fly ash

In the present study, coal from Chakwal (Pakistan) was leached with an aqueous solutions of iodine monochloride (ICl) and diethylenetriamine pentaacetic acid (DPTA) of different concentrations. The effect of stirring time, concentration and pH was studied on the leaching of different metals from coal. The physicochemical parameters indicated that the coal was of reasonably good quality. The results indicated that with increase in time duration, the extraction of metals increased. In most of the cases, metal concentration increased in the leachate with increasing the concentration of the leaching agents. DPTA was found to be the best leaching agent for most of the metals. Higher extraction of metals from coal fly ash indicated that coal organic matter has a pronounced effect on the leaching. Higher concentration of metals was extracted from virgin coal and coal fly ash at low pH (p?>?0.00) as compared to high pH. DPTA extracted metals in higher concentration from virgin coal and coal fly ash at low pH as compared to ICl. Based on the present study, the most leached metals were Fe, Cu, Mn and the least were Pb, Ni, Cd and Cr.     

Organic geochemistry and petrology of barren and Mo–Ni–PGE mineralized marine black shales of the Lower Cambrian Niutitang Formation (South China)

Marine black shales of the Lower Cambrian Niutitang Formation in southern China host Mo–Ni–platinum group elements (PGE) mineralization confined to a phosphate- and pyrite-rich stratiform body (max. 20-cm thick). The H/C atomic ratio, carbon isotopic composition, FTIR spectra of bulk organic matter, and spectra of extractable part of organic matter indicate similar sources and thermal evolution of organic matter in barren and mineralized black shales.The morphology and relative abundance of organic particles in barren and mineralized shales are different. In barren black shales, organic particles comprise only elongated bodies and laminae 2–10 μm across or elongated larger bodies (> 10 μm) with R_max = 2.96–5.21% (Type I particles). Mineralized black shales contain Type I particles in rock matrix (90–95 vol%), small veinlets or irregular organic accumulations (Type II particles, 1–5 vol%) that display weak to well developed mosaic texture and a variable reflectance (R_max = 3.55–8.65%), and small (< 1 to 5 μm) rounded or irregular Type III organic particles (1–4 vol%) distributed within phosphate nodules and sulphide rip-up clasts. Type III particles show similar reflectance as particles of Type I in rock matrix. Type I particles are interpreted as remnants of in situ bacterially reworked organic matter of cyanobacteria/algal type, Type II as solidified products or oil-derived material (migrabitumen), and Type III particles as remnants of original organic matter in phosphatized or sulphidized algal/microbial oncolite-like bodies. Equivalent vitrinite reflectances of Type I and III particles in barren and mineralized rocks are similar and correspond to semi-anthracite and anthracite. Micro-Raman spectra of organic particles in rocks display a wide belt in the area of 1600 cm^− 1 (G belt) and approximately the same belt in the area of 1350 cm^− 1 (D belt). The ratio of integrated areas of the two belts correlate with R_max values.The Mo–Ni–PGE mineralized body is interpreted as to represent a remnant of phosphate- and sulphide-rich subaquatic hardground supplied with organic material derived from plankton and benthic communities as well as with algal/microbial oncolite-like bodies that originated in wave-agitated, shallow-water, nearshore environment.     

Assessment of gully erosion rates through interviews and measurements: a case study from northern Ethiopia

Gullying has been widespread in the Ethiopian Highlands during the 20th century. It threatens the soil resource, lowers crop yields in intergully areas through enhanced drainage and desiccation, and aggravates flooding and reservoir siltation. Knowing the age and rates of gully development during the last few decades will help explain the reasons for current land degradation. In the absence of historical written or photographic documentation, the AGERTIM method (Assessment of Gully Erosion Rates Through Interviews and Measurements) has been developed. It comprises measurements of contemporary gully volumes, monitoring of gully evolution over several years and semi‐structured interview techniques. Gully erosion rates in the Dogu'a Tembien District, Tigray, Ethiopia, were estimated in three representative case‐study areas. In Dingilet, gullying started around 1965 after gradual environmental changes (removal of vegetation from cropland in the catchment and eucalyptus plantation in the valley bottom); rill‐like incisions grew into a gully, which increased rapidly in the drier period between 1977 and 1990. The estimated evolution of the total gully volume in the other areas show patterns similar to those of the Dingilet gully. Average gully erosion rate over the last 50 years is 6·2 t ha^?1 a^?1. Since 1995, no new gullies have developed in the study area. Area‐specific short‐term gully erosion rates are now on average 1·1 t ha^?1 a^?1. The successful application of the AGERTIM method requires an understanding of the geomorphology of the study area and an integration of the researchers with the rural society. It reveals that rapid gully development in the study area is some 50 years old and is mainly caused by human‐induced environmental degradation. Under the present‐day conditions of ‘normal’ rain and catchment‐wide soil and water conservation, gully erosion rates are decreasing. Copyright © 2006 John Wiley & Sons, Ltd.     

Comparison of Positron Emission Tomography and X-ray radiography for studies of physical processes in sandstone

The migration of moisture in cores of porous homogeneous sandstone of Ledian age (Belgian Eocene, Tertiary) is monitored with PET (Positron Emission Tomography) and micro-focus X-ray radiography. In the case of PET, a nuclear medical imaging technique, ⁵⁵Co-EDTA (Ethylenediamine Tetraacetic acid) and R-¹⁸F were used as water-soluble tracers. The X-ray projection method has evolved from the better-known medical technique and allows a fast and accurate determination of the two-dimensional transient moisture content profiles. Results indicate that both techniques can deliver important information concerning physical processes in situ.     

Catabolic and anabolic energy for chemolithoautotrophs in deep-sea hydrothermal systems hosted in different rock types

Active deep-sea hydrothermal vents are hosted by a range of different rock types, including basalt, peridotite, and felsic rocks. The associated hydrothermal fluids exhibit substantial chemical variability, which is largely attributable to compositional differences among the underlying host rocks. Numerical models were used to evaluate the energetics of seven inorganic redox reactions (potential catabolisms of chemolithoautotrophs) and numerous biomolecule synthesis reactions (anabolism) in a representative sampling of these systems, where chemical gradients are established by mixing hydrothermal fluid with seawater. The wide ranging fluid compositions dictate demonstrable differences in Gibbs energies (ΔG_r) of these catabolic and anabolic reactions in three peridotite-hosted, six basalt-hosted, one troctolite-basalt hybrid, and two felsic rock-hosted systems. In peridotite-hosted systems at low to moderate temperatures (<∼45 °C) and high seawater:hydrothermal fluid (SW:HF) mixing ratios (>10), hydrogen oxidation yields the most catabolic energy, but the oxidation of methane, ferrous iron, and sulfide can also be moderately exergonic. At higher temperatures, and consequent SW:HF mixing ratios <10, anaerobic processes dominate the energy landscape; sulfate reduction and methanogenesis are more exergonic than any of the aerobic respiration reactions. By comparison, in the basalt-hosted and felsic rock-hosted systems, sulfide oxidation was the predominant catabolic energy source at all temperatures (and SW:HF ratios) considered. The energetics of catabolism at the troctolite-basalt hybrid system were intermediate to these extremes. Reaction energetics for anabolism in chemolithoautotrophs—represented here by the synthesis of amino acids, nucleotides, fatty acids, saccharides, and amines—were generally most favorable at moderate temperatures (22-32 °C) and corresponding SW:HF mixing ratios (∼15). In peridotite-hosted and the troctolite-basalt hybrid systems, ΔG_r for primary biomass synthesis yielded up to ∼900 J per g dry cell mass. The energetics of anabolism in basalt- and felsic rock-hosted systems were far less favorable. The results suggest that in peridotite-hosted (and troctolite-basalt hybrid) systems, compared with their basalt (and felsic rock) counterparts, microbial catabolic strategies—and consequently variations in microbial phylotypes—may be far more diverse and some biomass synthesis may yield energy rather than imposing a high energetic cost.