Evidence for fullerenes in solid bitumen from pillow lavas of Proterozoic age from Mítov (Bohemian Massif, Czech Republic)

Andesitic pillow lavas containing biogenic, solid bitumen (SB) are a constituent of a Neoproterozoic volcanosedimentary sequence (Teplá-Barrandian unit, Bohemian Massif) in the Mítov area of the Czech Republic. A black shale formation that is crosscut by these andesitic basalts is 565 Ma old. Carbon disulfide extracts of two powdered samples of SB contain 0.2 and 0.3 ppm of C₆₀, respectively, as determined by high-pressure liquid chromatography. The peak assignment based on retention time is fully supported by high-resolution electron ionization mass spectrometry (EI-MS). No C₇₀ was detected, nor was C₆₀ found in two other SB samples from this locality. Other investigated carbonaceous samples from Bohemia (coals and anthracites of Upper Paleozoic age and anthraxolite, graphitoids, and graphite of Upper Proterozoic age) did not contain fullerenes at concentrations above the detection limit of 0.01 ppm. The absence of C₆₀ in these samples was confirmed by EI-MS. The proposed mechanism of fullerene formation involves a primary algal phase, generation of a hydrocarbonaceous mixture in the course of thermal evolution of the sedimentary series, and their high-temperature transformation related to the extrusion of basalt. An important feature for fullerene conservation was the enclosure of fullerenes in SB with a structure similar to glasslike carbon, where the fullerene was protected against oxidation.     

Tracing the flow of organic matter from primary producers to filter feeders in Ria Formosa lagoon, Southern Portugal

The flow of organic matter along the main navigation channel of Ria Formosa, Portugal, was assessed using determinations of suspended particulate matter (SPM), particulate organic matter (POM), and chlorophyll a (chla) concentrations in conjunction with stable isotope values of primary producers, particulate matter, and two filter feeders. SPM in the lagoon is dominated by inorganic particles comprising 80% of total weight with organic matter averaging about 20%. The algal component of the POM averaged about 5% with the remainder comprised of detritus. The δ¹³C values of primary producers ranged from ?9.1‰ in the intertidal seagrassZostera noltii to ?30.7‰ in the red seaweedBostrychia scorpioides revealing underlying differences in the mechanisms of carbon uptake. The δ¹³C value ofB. scorpioides, which develops entangled on the salt marsh speciesSpartina maritima, suggests that its main source of inorganic carbon is atmospheric CO₂. The δ¹³C values of the high marsh macrophyteSarcocornia perennis significantly increased with distance from the ocean while δ¹³C values ofZ. noltii decreased, probably because higher decomposition of organic matter at inner stations lowers the δ¹³CO₂ value in the water. The δ¹⁵N values of Ulvales, seagrasses, and marsh plants significantly increased from outer stations to inner stations. This increase may be due either to recycling of nitrogen (N) within the marsh (with loss of light N₂ or NH₄) or to inputs of isotopically heavy N from sewage. The δ¹⁵N values of particulate matter showed an opposite trend, which indicates higher microbial degradation of organic matter at the inner lagoon. The data demonstrate that the seston in the lagoon is a mixture of detritus from lagoon primary producers with a minor contribution of microalgae. The filter feeders are most likely assimilating a mixture of phytoplankton and microphytobenthos. Digestion of lagoon seston is selective. The δ¹⁵N values of both muscle and digestive gland of filter feeders showed the opposite gradient of particulate matter indicating that the depleted δ¹⁵N of SPM at inner stations was not assimilated or even ingested. Stable isotopes values did not differ between the filter-feeders—the musselMytilus galloprovincialis collected on buoys and the clamTapes decussatus collected in the sediment—suggesting a considerable mixture of benthic-pelagic organic matter throughout the water column. Assessment of the changes in isotopic decomposition of detritus as it decays is required to refine our understanding of organic matter transfers in detrital food webs.     

Use of phytoplankton species indicators to track the origin of phytoplankton blooms in Willapa Bay, Washington

We focus on the question of whether high phytoplankton production events observed in a United States Pacific Northwest estuary consist of estuarine species blooms fueled by oceanic nutrient input or reflect offshore oceanic blooms that have advected into the estuary. Our approach is to use certain phytoplankton species as indicators associated with water mass origin, either estuarine or oceanic, to help resolve this question in Willapa Bay, Washington. We used species analysis and primary production data from 10 selected dates in May–September of 1998 and 1999, representing periods of high through low productivity. Out of 108 phytoplankton species identified from Willapa Bay, nine were selected and tested as indicators of oceanic species, six as estuarine, and two as surf zone. Our test results demonstrated the oceanic and estuarine species to be satifactory indicators of source waters. The prevalence of these species indicators in our samples revealed that the highest primary production and the appearance ofPseudo-nitzschia spp. were associated with oceanic intrusions of phytoplankton biomass into Willapa Bay. While the largest blooms were oceanic in origin, numerous medium-sized production events were from either oceanic, surf zone, or estuarine sources, indicating a complex situation.     

In-situ Formation of Light-Absorbing Organic Matter in Cloud Water

Current climate models seem to underestimate the flux of solar energy absorbed by the global troposphere. All of these models are constrained with the assumption that cloud droplets consist of pure water. Here we demonstrate in a simple laboratory experiment that aromatic hydroxy-acids which are found in continental fine aerosol can react with hydroxyl radicals under typical conditions prevalent in cloud water influenced by biomass burning. The reactions yield colored organic species which do absorb solar radiation. We also suggest that the products of such reactions may be humic-like substances whose presence in continental aerosol has been confirmed but their source mechanisms are still much sought after. We also attempt to give a first order estimate of the enhancement of water absorption at a visible wavelength under atmospheric conditions.     

Simulation of a long-lived meso-β scale convective system over the mediterranean coast of Spain. Part II: Sensitivity to external forcings

Summary The numerical simulation of a long-lived, stationary mesoscale convective system (MCS) already described in a previous paper (Fernández et al., 1995) is analyzed in greater detail. The influence of various external forcings, such as sea surface temperature, local orography or terrain roughness, upon the characteristics of the system is studied. This analysis makes it possible not only to identify the most important factors, but also to deduce the importance of some other internal forcings and to propose explanations for some dynamic features of the system that were difficult to understand. Hence, the sensitivity test methodology applied seems to be a useful tool to clarify the complex dynamics of some moist convective events. In the modelled MCS, sea surface temperature and orography are identified as key factors. The results also indicate that the upstream triggering of convection provoked by an orographic blocking effect is the main cause of the development of the system, while upslope triggering plays a secondary role.With 18 Figures     

Influence of the Load Wavelength on the Permeability of a Viscosity Interface in the Mantle

Assuming a radially stratified Newtonian mantle in a steady-state approximation, we demonstrate that the permeability of a viscosity interface at 660-km depth strongly depends on the wavelength of buoyancy forces driving the flow. The flow induced by long-wavelength loads penetrates through the boundary freely even if the viscosity increases by two orders. In contrast, the boundary is practically impermeable for short-wavelength loads located in the upper mantle. Thus, a stepwise increase of viscosity is a significant obstacle for small descending features in the upper mantle, but huge upper mantle downwellings, or upwellings formed in the-lower mantle can overcome it easily. This indicates that certain care is necessary in interpreting the seismic structure of the mantle by means of flow models. The global tomographic image includes only the first few degrees of the harmonic series and, consequently, its interpretation in terms of a present-day flow field results in a predominantly whole-mantle circulation even for extreme viscosity contrasts.     

Repeated Geodetic Measurements in the West Bohemia Seismoactive Region: Period 1993 - 1996

The western part of the Bohemian Massif is characterized by repeated occurrences of intraplate earthquake swarms. To study surface deformations of this anomalous region, a network covering about 2000 square kilometres for repeated geodetic measurements was established in 1993 - 1994. The positions of the individual points of the network were carefully picked with respect to local tectonic structure and earthquake foci distribution. GPS and precise levelling measurements were performed 1-2 times a year. The GPS data were processed by Bernese GPS software. No tendency to any displacement - either horizontal or vertical - of geological blocks was derived from the geodetic data for the period 1993 - 96. Only displacements of less than 5 mm/year in average could occur in the whole region in that period; larger displacements would have been revealed by our measurements.     

Detecting lateral resistivity inhomogeneities with the Schlumberger array

A method of detecting lateral resistivity inhomogeneities with a multi-electrode cable for the Schlumberger array is presented. Using such a cable system, two dipole-dipole soundings are gathered in addition to the Schlumberger sounding at each point. Offset differences calculated from the dipole-dipole data give qualitative information about lateral resistivity inhomogeneities. Results from 1D modelling can give quantitative information about the 2D resistivity distribution since the dipole-dipole soundings are made to either side of the Schlumberger sounding point. Examples from two different locations in Norway are shown. At Reinøya, northern Norway, a dipping layer, confirmed by refraction seismic data, was identified. In a sedimentary basin with a contamination plume at Haslemoen, southern Norway, the method has revealed lateral variations in resistivity. In both cases, the Schlumberger soundings could be fitted with a 1D resistivity model.