Biomass Burning in Southern Africa: Individual Particle Characterization of Atmospheric Aerosols and Savanna Fire Samples

Ambient atmospheric aerosols and savanna fireparticulate emission samples from southern Africa werecharacterised in terms of particle classes and theirnumber abundance by electron probe X-ray microanalysis(EPXMA). About ten particle classes were identifiedfor each sample. The major classes werealuminosilicates and sea salts for ambient coarse(2–10 m equivalent aerodynamic diameter (EAD))samples, and K-S and S-only particles for ambient fine(<2 m EAD) samples. The K-S particles are oneof the major products of biomass burning. The EPXMAresults were found to be consistent with the resultsfrom bulk analyses on a sample by sample basis. Forsavanna fire fine samples, quantitative EPXMA revealedthat many particles had a composition of simple saltssuch as KCl. Some particles had a deviatingcomposition in the sense that more ionic species wereinvolved in sustaining the balance between cations andanions, and they were composite or mixed salts.Because of extensive processing during the atmospherictransport, the composition of the K-S particles in theambient samples was different from K₂SO₄,and such particles were enriched with S. The finepyrogenic KCl particles and the fine sea-saltparticles were much depleted in chlorine.     

Objective method for classifying air masses: an application to the analysis of Buenos Aires’ (Argentina) urban heat island intensity

Summary ?During recent years, numerous studies have examined the Buenos Aires urban climate, but the relationship between large-scale weather conditions and the Buenos Aires urban heat island (UHI) intensity has not been studied. The goal of this paper is to apply an objective synoptic climatological method to identify homogeneous air masses or weather types affecting Buenos Aires during winter, and to relate the results to the UHI intensity. A K-means clustering method was used to define six different air masses considering the 03:00, 09:00, 15:00 and 21:00 LT surface observations of dry bulb temperature, dew point, cloud cover, atmospheric pressure and wind direction and velocity at Ezeiza, the most rural meteorological station of the Buenos Aires metropolitan area (Fig. 1). Results show that the mean UHI intensity is at its maximum (2.8 °C) a few hours before sunrise when conditions are dominated by cold air masses associated with cold-core anticyclones, weak winds and low cloud cover. Inverse heat islands are found during the afternoon for all air masses indicating that surface processes are not dominant at that time. The relatively infrequent and warmest air mass is the only one that presents a mean negative urban-rural temperature difference (−0.1 °C) during the afternoon with the smallest diurnal cycle of the UHI intensity probably due to the prevailing high humidity and cloudy sky conditions. The paper provides an insight into the Buenos Aires urban–rural temperature difference under a variety of winter weather types and results could be useful to improve local daily temperature forecasts for the metropolitan area of Buenos Aires on the basis of the routine forecasts of weather types. Received October 24, 2001; revised June 12, 2002; accepted October 10, 2002     

Variability of the Caribbean Low-Level Jet and its relations to climate

A maximum of easterly zonal wind at 925 hPa in the Caribbean region is called the Caribbean Low-Level Jet (CLLJ). Observations show that the easterly CLLJ varies semi-annually, with two maxima in the summer and winter and two minima in the fall and spring. Associated with the summertime strong CLLJ are a maximum of sea level pressure (SLP), a relative minimum of rainfall (the mid-summer drought), and a minimum of tropical cyclogenesis in July in the Caribbean Sea. It is found that both the meridional gradients of sea surface temperature (SST) and SLP show a semi-annual feature, consistent with the semi-annual variation of the CLLJ. The CLLJ anomalies vary with the Caribbean SLP anomalies that are connected to the variation of the North Atlantic Subtropical High (NASH). In association with the cold (warm) Caribbean SST anomalies, the atmosphere shows the high (low) SLP anomalies near the Caribbean region that are consistent with the anomalously strong (weak) easterly CLLJ. The CLLJ is also remotely related to the SST anomalies in the Pacific and Atlantic, reflecting that these SST variations affect the NASH. During the winter, warm (cold) SST anomalies in the tropical Pacific correspond to a weak (strong) easterly CLLJ. However, this relationship is reversed during the summer. This is because the effects of ENSO on the NASH are opposite during the winter and summer. The CLLJ varies in phase with the North Atlantic Oscillation (NAO) since a strong (weak) NASH is associated with a strengthening (weakening) of both the CLLJ and the NAO. The CLLJ is positively correlated with the 925-hPa meridional wind anomalies from the ocean to the United States via the Gulf of Mexico. Thus, the CLLJ and the meridional wind carry moisture from the ocean to the central United States, usually resulting in an opposite (or dipole) rainfall pattern in the tropical North Atlantic Ocean and Atlantic warm pool versus the central United States.     

Surface Synoptic Circulation and Daily Precipitation in Catalonia

Summary Catalonian daily precipitation patterns were obtained by means of S-mode Principal Component Analysis (PCA) applied to subsets built up according to synoptic surface airflow. Daily data from November to April 1990–1994 from 45 raingauge sites in Catalonia without missing data were used. Eight circulation classes for days in this period were considered. A Precipitation Activity Index (PAI) was calculated for each station and class, leading to the determination of the highest activity regions for each subset. In addition, we determined which circulation type produced most precipitation at each station of the network. Separate PCAs were performed for each of the eight classes considered and the first four Varimax rotated solutions were interpreted for each circulation type. The physical meaning of the rest of the factors were omitted as they were associated with local behaviour. Finally, some concluding remarks on the cyclogenic properties of the Western Mediterranean Basin and the diversity of the extracted patterns are presented and supported by the authors experience in forecasting in Catalonia. Received February, 11, 1997 Revised May 23, 1997     

Arctic Climate Changes Based on Historical Simulations (1900‒2013) with the CAMS-CSM

The Chinese Academy of Meteorological Sciences Climate System Model (CAMS-CSM) is a newly developed global climate model that will participate in the Coupled Model Intercomparison Project phase 6. Based on historical simulations (1900?2013), we evaluate the model performance in simulating the observed characteristics of the Arctic climate system, which includes air temperature, precipitation, the Arctic Oscillation (AO), ocean temperature/salinity, the Atlantic meridional overturning circulation (AMOC), snow cover, and sea ice. The model?data comparisons indicate that the CAMS-CSM reproduces spatial patterns of climatological mean air temperature over the Arctic (60°?90°N) and a rapid warming trend from 1979 to 2013. However, the warming trend is overestimated south of the Arctic Circle, implying a subdued Arctic amplification. The distribution of climatological precipitation in the Arctic is broadly captured in the model, whereas it shows limited skills in depicting the overall increasing trend. The AO can be reproduced by the CAMS-CSM in terms of reasonable patterns and variability. Regarding the ocean simulation, the model underestimates the AMOC and zonally averaged ocean temperatures and salinity above a depth of 500 m, and it fails to reproduce the observed increasing trend in the upper ocean heat content in the Arctic. The large-scale distribution of the snow cover extent (SCE) in the Northern Hemisphere and the overall decreasing trend in the spring SCE are captured by the CAMS-CSM, while the biased magnitudes exist. Due to the underestimation of the AMOC and the poor quantification of air–sea interaction, the CAMS-CSM overestimates regional sea ice and underestimates the observed decreasing trend in Arctic sea–ice area in September. Overall, the CAMS-CSM reproduces a climatological distribution of the Arctic climate system and general trends from 1979 to 2013 compared with the observations, but it shows limited skills in modeling local trends and interannual variability.     

UV attenuation in the cloudy atmosphere

Ultraviolet (UV) energy absorption plays a very important role in the Earth–atmosphere system. Based on observational data for Beijing, we suggest that some atmospheric constituents utilize or transfer UV energy in chemical and photochemical (C&P) reactions, in addition to those which absorb UV energy directly. These constituents are primarily volatile organic compounds (VOCs) emitted from both vegetative and anthropogenic sources. The total UV energy loss in the cloudy atmosphere for Beijing in 1990 was 78.9 Wm⁻². This attenuation was caused by ozone (48.3 Wm⁻²), other compounds in the atmosphere (26.6 Wm⁻²) and a scattering factor (4.0 Wm⁻²). Our results for a cloudy atmosphere in the Beijing area show that the absorption due to these other compounds occurs largely through the mediation of water vapor. This fraction of energy loss has not been fully accounted for in previous models. Observations and previous models results suggest that 1) a cloudy atmosphere absorbs 25∼30 Wm⁻² more solar shortwave radiation than models predict; and 2) aerosols can significantly decrease the downward mean UV-visible radiation and the absorbed solar radiation at the surface by up to 28 and 23 Wm⁻², respectively. Thus, quantitative study of UV and visible absorption by atmospheric constituents involved in homogeneous and heterogeneous C&P reactions is important for atmospheric models.     

Estimation of Surface-Layer Scaling Parameters in the Unstable Boundary Layer: Implications for Orographic Flow Speed-Up

A method is proposed for estimating the surface-layer depth \((z_s)\) and the friction velocity \((u_*)\) as a function of stability (here quantified by the Obukhov length, L) over the complete range of unstable flow regimes. This method extends that developed previously for stable conditions by Argaín et al. (Boundary-Layer Meteorol 130:15–28, 2009), but uses a qualitatively different approach. The method is specifically used to calculate the fractional speed-up \((\varDelta S)\) in flow over a ridge, although it is suitable for more general boundary-layer applications. The behaviour of \(z_s \left( L\right) \) and \(u_*\left( L\right) \) as a function of L is indirectly assessed via calculation of \(\varDelta S\left( L\right) \) using the linear model of Hunt et al. (Q J R Meteorol Soc 29:16–26, 1988) and its comparison with the field measurements reported in Coppin et al. (Boundary-Layer Meteorol 69:173–199, 1994) and with numerical simulations carried out using a non-linear numerical model, FLEX. The behaviour of \(\varDelta S\) estimated from the linear model is clearly improved when \(u_*\) is calculated using the method proposed here, confirming the importance of accounting for the dependences of \(z_s\left( L \right) \) and \(u_*\left( L \right) \) on L to better represent processes in the unstable boundary layer.     

A GCM Simulation of Heat Waves, Dry Spells, and Their Relationships to Circulation

Heat waves and dry spells are analyzed (i) at eightstations in south Moravia (Czech Republic), (ii) inthe control ECHAM3 GCM run at the gridpoint closest tothe study area, and (iii) in the ECHAM3 GCM run fordoubled CO₂ concentrations (scenario A) at thesame gridpoint (heat waves only). The GCM outputs arevalidated both against individual station data andareally representative values. In the control run, theheat waves are too long, appear later in the year,peak at higher temperatures and their numbers areunder- (over-) estimated in June and July (in August).The simulated dry spells are too long, and the annualcycle of their occurrence is distorted.Mid-tropospheric circulation, and heat waves and dryspells are linked much less tightly in the controlclimate than in the observed. Since mid-troposphericcirculation is simulated fairly successfully, wesuggest the hypothesis that either the air-masstransformation and local processes are too strong inthe model or the simulated advection is too weak. Inthe scenario A climate, the heat waves become a commonphenomenon: warming of 4.5 °C in summer(difference between scenario A and control climates)induces a five-fold increase in the frequency oftropical days and an immense enhancement of extremityof heat waves. The results of the study underline theneed for (i) a proper validation of the GCM outputbefore a climate impact study is conducted and (ii)translation of large-scale information from GCMs intolocal scales using downscaling and stochasticmodelling techniques in order to reduce GCMs' biases.     

Characteristics of carbonyl compounds in ambient air of Shanghai,China

The levels of carbonyl compounds in Shanghai ambient air were measured in five periods from January 2007 to October 2007 (covering winter, high-air-pollution days, spring, summer and autumn). A total of 114 samples were collected and eighteen carbonyls were identified. Formaldehyde, acetaldehyde and acetone were the most abundant carbonyls and their mean concentrations of 19.40 ± 12.00, 15.92 ± 12.07 and 11.86 ± 7.04 μg m⁻³ respectively, in the daytime for five sampling periods. Formaldehyde and acetaldehyde showed similar diurnal profiles with peak mixing ratios in the morning and early afternoon during the daytime. Their mean concentrations were highest in summer and lowest in winter. Acetone showed reversed seasonal variation. The high molecular weight (HMW, ≥C5) carbonyls also showed obvious diurnal variations with higher concentrations in the daytime in summer and autumn, while they were all not detected in winter. Formaldehyde and acetaldehyde played an important role in removing OH radicals in the atmosphere, but the contribution of acetone was below 1%. The carbonyls levels in high-air-pollution days were reported. More carbonyl species with higher concentrations were found in high-air-pollution days than in spring. These carbonyls were transported with other pollutants from north and northwest in March 27 to April 2, 2007 and then mixed with local sources. Comparing with Beijing and Guangzhou, the concentrations of formaldehyde and acetaldehyde in Shanghai were the highest, which indicated that the air pollution in Shanghai was even worse than expected.     

Interdecadal change in the connection between Hadley circulation and winter temperature in East Asia

Based on NCEP/NCAR reanalysis data, the interdecadal variability of Hadley circulation （HC） and its association with East Asian temperature in winter are investigated. Results indicate that the Northern Hemisphere winter HC underwent apparent change in the 1970s, with transition occurring around 1976/77. Along with interdecadal variability of HC, its linkage to surface air temperature （SAT） in East Asia also varied decadally, from weak relations to strong relations. Such a change may be related to the interaction between HC and the atmospheric circulation system over the Philippines, which is associated with the East Asian winter monsoon （EAWM）. Before the 1970s, the connection between HC and the anticyclonic circulation around the Philippines was insignificant, but after the late 1970s their linkage entered a strong regime. The intensification of this connection may therefore be responsible for the strong relations between HC and East Asian winter temperatures after the late 1970s.