Virtual geology special issue: developing training,teaching and research skillsets for geoscientists

Current physical science students and researchers are becoming ever more diverse in their learning needs and styles, in their ways of learning and indeed their scientific backgrounds in the subjects that they study. Current schools, colleges and Higher Education students are increasingly ‘digital natives’, connected 24/7 through mobile devices, generally goal‐orientated and responding well to digitally‐based activities and tasks. Whilst the structured nature of classrooms, traditional lectures and laboratory practicals obviously still dominate geoscience teaching, and core outdoor field trips and independent mapping/research are of paramount importance, more innovative complementary learning, teaching and research technologies are being developed by a wide variety of computer software developers, practitioners and educationalists.     

Circuits of capital and industrial restructuring: adjustment in the australian clothing industry

Patterns and processes of industrial restructuring in the Australian clothing industry are examined, utilising a ‘circuits of capital’ approach in which the interrelationships between labour markets, labour processes and product markets are emphasised. Changes in product markets (where import competition is intensifying under the trade liberalisation policies of the Hawke government and where an increasingly concentrated retail sector has accrued enormous bargaining power in its dealings with clothing manufacturers) and changes in labour markets (where competition for the industry's traditional inner urban labour supply has intensified considerably) are argued to have provided the driving force behind the process of clothing industry adjustment. This process of adjustment has been characterised by: (i) increased use of outworking, which enables clothing manufacturers to reduce production costs and provides a means for new sources of home‐based labour within the urban labour market to be tapped; and (ii) the evolution of a spatial division of labour, as some of the labour‐intensive components of the industry have been relocated to non‐urban sites where a stable and plentiful labour supply is available. In contrast to experiences in Europe and the United States, there is little evidence in Australia at the present time of significant technical change nor of specialisation in the high quality/high fashion niche of the garment market.     

Seismic response of a bridge–soil–foundation system under the combined effect of vertical and horizontal ground motions

Different levels of model sophistication have recently emerged to support seismic risk assessment of bridges, but mostly at the expense of neglecting the influence of vertical ground motions (VGMs). In this paper, the influence of VGMs on bridge seismic response is presented and the results are compared with the case of horizontal‐only excitations. An advanced finite element model that accounts for VGMs is first developed. Then, to investigate the effect of soil–structure interaction (SSI) including liquefaction potential, the same bridge with soil‐foundation and fixed boundary conditions is also analyzed. Results show that the inclusion of the VGMs has a significant influence on the seismic response, especially for the axial force in columns, normal force of bearings, and the vertical deck bending moments. However, VGMs do not have as much influence on the seismic demand of the pile cap displacements or pile maximum axial forces. Also, the significant fluctuation of the column axial force can reduce its shear and flexural capacity, and a heightened reversal of flexural effects may induce damage in the deck. In addition, relative to the fixed base case, SSI effects tend to reduce response quantities for certain ground motions while increasing demands for others. This phenomenon is explained as a function of the frequency content of the ground motions, the shift in natural vertical periods, and the VGM spectral accelerations at higher modes. Moreover, the mechanisms of liquefaction are isolated relative to SSI effects in nonliquefiable soils, revealing the influence of liquefaction on bridge response under VGMs. Copyright © 2012 John Wiley & Sons, Ltd.     

Teaching Orientalism in Introductory Human Geography

This article explores efforts to bring postcolonial theory into the undergraduate human geography classroom. Through a case study of teaching Edward Said's Orientalism in introductory human geography, we discuss the relevance of postcolonial theory to critical pedagogy in geography. We lay out how instructors can teach Orientalism in introductory courses, what happens when they do so, and where efforts to use postcolonial theory to help students analyze the “colonial present” can be improved. We suggest that postcolonial theory is particularly well suited pedagogically to show students the mechanisms and uneven power relations producing and sustaining past and present geographies of difference.     

Reference hydrologic networks II. Using reference hydrologic networks to assess climate-driven changes in streamflow

Abstract

Reference hydrologic networks (RHNs) can play an important role in monitoring for changes in the hydrological regime related to climate variation and change. Currently, the literature concerning hydrological response to climate variations is complex and confounded by the combinations of many methods of analysis, wide variations in hydrology, and the inclusion of data series that include changes in land use, storage regulation and water use in addition to those of climate. Three case studies that illustrate a variety of approaches to the analysis of data from RHNs are presented and used, together with a summary of studies from the literature, to develop approaches for the investigation of changes in the hydrological regime at a continental or global scale, particularly for international comparison. We present recommendations for an analysis framework and the next steps to advance such an initiative. There is a particular focus on the desirability of establishing standardized procedures and methodologies for both the creation of new national RHNs and the systematic analysis of data derived from a collection of RHNs.

Editor Z.W. Kundzewicz; Associate editor K. Hamed

Citation Burn, D. H., et al., 2012 Whitfield, P.H. 2012. Reference hydrologic networks, I. The status of national reference hydrologic networks for detecting trends and future directions. Hydrological Sciences Journal, 57(8) this issue[Taylor & Francis Online] , [Google Scholar]. Reference hydrologic networks II. Using reference hydrologic networks to assess climate-driven changes in streamflow. Hydrological Sciences Journal, 57 (8), 1580–1593.     

A propensity for n‐ω‐amino acids in thermally altered Antarctic meteorites

Abstract– Asteroids and their fragments have impacted the Earth for the last 4.5 Gyr. Carbonaceous meteorites are known to contain a wealth of indigenous organic molecules, including amino acids, which suggests that these meteorites could have been an important source of prebiotic organic material during the origins of life on Earth and possibly elsewhere. We report the detection of extraterrestrial amino acids in thermally altered type 3 CV and CO carbonaceous chondrites and ureilites recovered from Antarctica. The amino acid concentrations of the thirteen Antarctic meteorites ranged from 300 to 3200 parts‐per‐billion (ppb), generally much less abundant than in amino acid‐rich CI, CM, and CR carbonaceous chondrites that experienced much lower temperature aqueous alteration on their parent bodies. In contrast to low‐temperature aqueously altered meteorites that show complete structural diversity in amino acids formed predominantly by Strecker–cyanohydrin synthesis, the thermally altered meteorites studied here are dominated by small, straight‐chain, amine terminal (n‐ω‐amino) amino acids that are not consistent with Strecker formation. The carbon isotopic ratios of two extraterrestrial n‐ω‐amino acids measured in one of the CV chondrites (δ¹³C approximately ?25‰) are consistent with ¹³C‐depletions observed previously in hydrocarbons produced by Fischer‐Tropsch type reactions. The predominance of n‐ω‐amino acid isomers in thermally altered meteorites hints at cosmochemical mechanisms for the preferential formation and preservation of a small subset of the possible amino acids.     

Unusual nonterrestrial l‐proteinogenic amino acid excesses in the Tagish Lake meteorite

Abstract– The distribution and isotopic and enantiomeric compositions of amino acids found in three distinct fragments of the Tagish Lake C2‐type carbonaceous chondrite were investigated via liquid chromatography with fluorescence detection and time‐of‐flight mass spectrometry and gas chromatography isotope ratio mass spectrometry. Large l ‐enantiomeric excesses (l _ee ～ 43–59%) of the α‐hydrogen aspartic and glutamic amino acids were measured in Tagish Lake, whereas alanine, another α‐hydrogen protein amino acid, was found to be nearly racemic (d ≈ l ) using both techniques. Carbon isotope measurements of d ‐ and l ‐aspartic acid and d ‐ and l ‐alanine in Tagish Lake fall well outside of the terrestrial range and indicate that the measured aspartic acid enantioenrichment is indigenous to the meteorite. Alternate explanations for the l ‐excesses of aspartic acid such as interference from other compounds present in the sample, analytical biases, or terrestrial amino acid contamination were investigated and rejected. These results can be explained by differences in the solid–solution phase behavior of aspartic acid, which can form conglomerate enantiopure solids during crystallization, and alanine, which can only form racemic crystals. Amplification of a small initial l ‐enantiomer excess during aqueous alteration on the meteorite parent body could have led to the large l ‐enrichments observed for aspartic acid and other conglomerate amino acids in Tagish Lake. The detection of nonterrestrial l ‐proteinogenic amino acid excesses in the Tagish Lake meteorite provides support for the hypothesis that significant enantiomeric enrichments for some amino acids could form by abiotic processes prior to the emergence of life.     

Compound‐specific carbon,nitrogen, and hydrogen isotopic ratios for amino acids in CM and CR chondrites and their use in evaluating potential formation pathways

Abstract– Stable hydrogen, carbon, and nitrogen isotopic ratios (δD, δ¹³C, and δ¹⁵N) of organic compounds can reveal information about their origin and formation pathways. Several formation mechanisms and environments have been postulated for the amino acids detected in carbonaceous chondrites. As each proposed mechanism utilizes different precursor molecules, the isotopic signatures of the resulting amino acids may indicate the most likely of these pathways. We have applied gas chromatography with mass spectrometry and combustion isotope ratio mass spectrometry to measure the compound‐specific C, N, and H stable isotopic ratios of amino acids from seven CM and CR carbonaceous chondrites: CM1/2 Allan Hills (ALH) 83100, CM2 Murchison, CM2 Lewis Cliff (LEW) 90500, CM2 Lonewolf Nunataks (LON) 94101, CR2 Graves Nunataks (GRA) 95229, CR2 Elephant Moraine (EET) 92042, and CR3 Queen Alexandra Range (QUE) 99177. We compare the isotopic compositions of amino acids in these meteorites with predictions of expected isotopic enrichments from potential formation pathways. We observe trends of decreasing δ¹³C and increasing δD with increasing carbon number in the α‐H, α‐NH₂ amino acids that correspond to predictions made for formation via Strecker‐cyanohydrin synthesis. We also observe light δ¹³C signatures for β‐alanine, which may indicate either formation via Michael addition or via a pathway that forms primarily small, straight‐chain, amine‐terminal amino acids (n‐ω‐amino acids). Higher deuterium enrichments are observed in α‐methyl amino acids, indicating formation of these amino acids or their precursors in cold interstellar or nebular environments. Finally, individual amino acids are more enriched in deuterium in CR chondrites than in CM chondrites, reflecting different parent‐body chemistry.     

On diagenesis,dolomitisation and mineralisation in the Irish Zn-Pb orefield

Marine calcite cementation and lithification of Carboniferous carbonate sediments hosting Zn-Pb mineralisation in the Irish orefield occurred at or near the seafloor. A relatively early, fine-grained, grey replacive dolomite, preferentially developed in micrite, is widely developed in the Waulsortian Limestone Formation, the main host to mineralisation, and is pervasive in the southeastern Midlands in proximity to the Leinster Massif. This dolomite formed after the first four main stages of calcite cementation but probably also developed within tens of metres of the seafloor as evidenced by incorporation of clasts of dolomite in intraformational sedimentary breccias. Later, coarse-grained white dolomite preferentially replaced coarser components of the Waulsortian Limestone and infilled residual vuggy porosity. Whilst some of this coarse dolomite may be related to the fine replacive dolomite event, a common spatial association with fault zones, coupled with primary fluid inclusion data, suggest that a significant proportion of this phase precipitated during the onset of fault-controlled subsidence and widespread hydrothermal circulation within the Irish Midlands area. Fluids up to ~250 °C and 10–15 wt% NaCl equivalent, sourced from a Lower Palaeozoic basement-equilibrated fluid reservoir, infiltrated the carbonate sequence via faults and fractures. The more localised development of dolomite-cemented breccias (white matrix breccias) that are frequently associated spatially with mineralisation was a consequence of the increased focusing of these hydrothermal fluids. Ore formation was broadly synchronous with development of the white dolomite breccias but only happened where mixing occurred between the hydrothermal ore-fluids and localised, near-surface reservoirs of low-temperature, H₂S-rich brine. In the Waulsortian, this process led to the precipitation of a distinctive black dolomite that forms a broad halo to massive sulphides. Although ore-stage sulphides postdate significant diagenesis of the host rocks, and often display "epigenetic" textures, the fact that much of the cementation occurred soon after carbonate deposition means that mineralisation does not have to have formed after significant burial. In fact, the occurrence of clasts of hydrothermal dolomite and sulphides in intraformational debris-flow breccias is only consistent with mineralising processes occurring in the near-seafloor environment, relatively soon after host-rock deposition. The regional development of a distinctive pink dolomite associated with faults and fractures was a post-ore event, and is considered to mark a regional brine migration linked to the onset of the Variscan orogeny. The development of this new tectonic and flow regime may have been responsible for the cessation of economic mineralisation in Ireland.Editorial handling: J. Menuge     

Patterns of variability in ichthyoplankton occurrence and abundance in Biscayne Bay,Florida

Within-day variability in ichthyoplankton and microzooplankton abundances was examined at a single station in Biscayne Bay using replicate tows of 61-cm bongo nets and Niskin bottles to determine if patchiness occurred on the 10–1000 m scale and on the minutes to hours time scale. Fish eggs and larvae often were patchy but copepod nauplii, the predominant food of larvae, usually were randomly distributed at the scales examined and over the 3.15 m-depth water column. Mean patchiness index values were of similar magnitude for fish eggs and larvae but fish eggs were patchy more often than were larvae. Individual taxa of larvae had extremely high patchiness index values on some dates. Variability in fish egg catches often reflected increasing or decreasing abundance trends during the 2.5h sampling period while fish larvae catches often appeared to be clumped within the repetitive series of tows. There was no tendency for patchiness to be correlated among taxa on collection dates nor was it correlated with abundances or wind speeds. Patchiness indices of bay anchovy Anchoa mitchilli eggs and larvae were not significantly correlated, indicating little concordance in tendency to be aggregated, suggesting that distributions were influenced by biological processes related to spawning of adults and behaviour of larvae, in addition to physical processes. Although ichthyoplankton patchiness often did exist at the 10–1000 m scale, on many days ichthyoplankton was uniformly or randomly distributed. Copepod nauplii were abundant ($\text{x}\text{=90.41}{}^{\mathrm{?1}}$), randomly distributed on most dates, and apparently readily available as fish larvae food in Biscayne Bay.