Assessment and control of organic and other contaminants associated with the Stardust sample return from comet 81P/Wild 2

Abstract– Numerous potential sources of organic contaminants could have greatly complicated the interpretation of the organic portions of the samples returned from comet 81P/Wild 2 by the Stardust spacecraft. Measures were taken to control and assess potential organic (and other) contaminants during the design, construction, and flight of the spacecraft, and during and after recovery of the sample return capsule. Studies of controls and the returned samples suggest that many of these potential sources did not contribute any significant material to the collectors. In particular, contamination from soils at the recovery site and materials associated with the ablation of the heatshield do not appear to be significant problems. The largest source of concern is associated with the C present in the original aerogel. The relative abundance of this carbon can vary between aerogel tiles and even within individual tiles. This C was fortunately not distributed among a complex mixture of organics, but was instead largely present in a few simple forms (mostly as Si‐CH₃ groups). In most cases, the signature of returned cometary organics can be readily distinguished from contaminants through their different compositions, nonterrestrial isotopic ratios, and/or association with other cometary materials. However, some conversion of the carbon indigenous to the flight aerogel appears to have happened during particle impact, and some open issues remain regarding how this C may be processed into new forms during the hypervelocity impact collection of the comet dust.     

The effects of parent body processes on amino acids in carbonaceous chondrites

Abstract– To investigate the effect of parent body processes on the abundance, distribution, and enantiomeric composition of amino acids in carbonaceous chondrites, the water extracts from nine different powdered CI, CM, and CR carbonaceous chondrites were analyzed for amino acids by ultra performance liquid chromatography‐fluorescence detection and time‐of‐flight mass spectrometry (UPLC‐FD/ToF‐MS). Four aqueously altered type 1 carbonaceous chondrites including Orgueil (CI1), Meteorite Hills (MET) 01070 (CM1), Scott Glacier (SCO) 06043 (CM1), and Grosvenor Mountains (GRO) 95577 (CR1) were analyzed using this technique for the first time. Analyses of these meteorites revealed low levels of two‐ to five‐carbon acyclic amino alkanoic acids with concentrations ranging from approximately 1 to 2,700 parts‐per‐billion (ppb). The type 1 carbonaceous chondrites have a distinct distribution of the five‐carbon (C₅) amino acids with much higher relative abundances of the γ‐ and δ‐amino acids compared to the type 2 and type 3 carbonaceous chondrites, which are dominated by α‐amino acids. Much higher amino acid abundances were found in the CM2 chondrites Murchison, Lonewolf Nunataks (LON) 94102, and Lewis Cliffs (LEW) 90500, the CR2 Elephant Moraine (EET) 92042, and the CR3 Queen Alexandra Range (QUE) 99177. For example, α‐aminoisobutyric acid (α‐AIB) and isovaline were approximately 100 to 1000 times more abundant in the type 2 and 3 chondrites compared to the more aqueously altered type 1 chondrites. Most of the chiral amino acids identified in these meteorites were racemic, indicating an extraterrestrial abiotic origin. However, nonracemic isovaline was observed in the aqueously altered carbonaceous chondrites Murchison, Orgueil, SCO 06043, and GRO 95577 with l ‐isovaline excesses ranging from approximately 11 to 19%, whereas the most pristine, unaltered carbonaceous chondrites analyzed in this study had no detectable l ‐isovaline excesses. These results are consistent with the theory that aqueous alteration played an important role in amplification of small initial left handed isovaline excesses on the parent bodies.     

A shallow subsurface controlled release facility in Bozeman, Montana, USA, for testing near surface CO2 detection techniques and transport models

A controlled field pilot has been developed in Bozeman, Montana, USA, to study near surface CO₂ transport and detection technologies. A slotted horizontal well divided into six zones was installed in the shallow subsurface. The scale and CO₂ release rates were chosen to be relevant to developing monitoring strategies for geological carbon storage. The field site was characterized before injection, and CO₂ transport and concentrations in saturated soil and the vadose zone were modeled. Controlled releases of CO₂ from the horizontal well were performed in the summers of 2007 and 2008, and collaborators from six national labs, three universities, and the U.S. Geological Survey investigated movement of CO₂ through the soil, water, plants, and air with a wide range of near surface detection techniques. An overview of these results will be presented.     

Head–tail Galaxies: beacons of high-density regions in clusters

Using radio data at 1.4 GHz from the Australia Telescope Compact Array (ATCA), we identify five head–tail (HT) galaxies in the central region of the Horologium–Reticulum Supercluster (HRS). Physical parameters of the HT galaxies were determined along with substructure in the HRS to probe the relationship between environment and radio properties. Using a density enhancement technique applied to 582 spectroscopic measurements in the  2°× 2°  region about A3125/A3128, we find all five HT galaxies reside in regions of extremely high density (>100 galaxies Mpc⁻³). In fact, the environments surrounding HT galaxies are statistically denser than those environments surrounding non-HT galaxies and among the densest environments in a cluster. Additionally, the HT galaxies are found in regions of enhanced X-ray emission and we show that the enhanced density continues out to substructure groups of 10 members. We propose that it is the high densities that allow ram pressure to bend the HT galaxies as opposed to previously proposed mechanisms relying on exceptionally high peculiar velocities.     

Noble gases and nitrogen in Martian meteorites Dar al Gani 476, Sayh al Uhaymir 005 and Lewis Cliff 88516: EFA and extra neon

Meteorite “finds” from the terrestrial hot deserts have become a major contributor to the inventory of Martian meteorites. In order to understand their nitrogen and noble gas components, we have carried out stepped heating experiments on samples from two Martian meteorites collected from hot deserts. We measured interior and surface bulk samples, glassy and non-glassy portions of Dar al Gani 476 and Sayh al Uhaymir 005. We have also analyzed noble gases released from the Antarctic shergottite Lewis Cliff 88516 by crushing and stepped heating. For the hot desert meteorites significant terrestrial Ar, Kr, Xe contamination is observed, with an elementally fractionated air (EFA) component dominating the low temperature releases. The extremely low Ar/Kr/Xe ratios of EFA may be the result of multiple episodes of trapping/loss during terrestrial alteration involving aqueous fluids. We suggest fractionation processes similar to those in hot deserts to have acted on Mars, with acidic weathering on the latter possibly even more effective in producing elementally fractionated components. Addition from fission xenon is apparent in DaG 476 and SaU 005. The Ar-Kr-Xe patterns for LEW 88516 show trends as typically observed in shergottites - including evidence for a crush-released component similar to that observed in EETA 79001. A trapped Ne component most prominent in the surface sample of DaG 476 may represent air contamination. It is accompanied by little trapped Ar (²⁰Ne/³⁶Ar > 50) and literature data suggest its presence also in some Antarctic finds. Data for LEW 88516 and literature data, on the other hand, suggest the presence of two trapped Ne components of Martian origin characterized by different ²⁰Ne/²²Ne, possibly related to the atmosphere and the interior. Caution is recommended in interpreting nitrogen and noble gas isotopic signatures of Martian meteorites from hot deserts in terms of extraterrestrial sources and processes. Nevertheless our results provide hope that vice-versa, via noble gases and nitrogen in meteorites and other relevant samples from terrestrial deserts, Martian secondary processes can be studied.     

Recombinant workfare, across the Americas: Transnationalizing “fast” social policy

The paper presents a genealogy of the Bloomberg administration’s Opportunity NYC program, launched in 2007 as part of New York City’s explicitly experimental anti-poverty strategy. Opportunity NYC was modeled on “conditional cash transfer” programs, currently operating in more than thirty countries across the Global South, drawing direct inspiration from Mexico’s widely touted Oportunidades program. This striking case of South-North policy emulation calls attention to some distinctive features of what is characterized here as a transnationalizing “fast-policy” regime, based on technocratic forms of program evaluation and development, dense expert networks, and orchestrated communities of practice, within which a range of policy intermediaries—particularly those connected with multilateral agencies—are assuming significant new roles. What appears to be a pragmatic form of policy learning in fact operates in the context of narrow ideological parameters, within which there is a concerted technocratic “push” toward favored solutions.     

Simulating low flows over a heterogeneous landscape in southeastern Poland

This paper presents a scheme describing low flow formation processes in areas with different environmental conditions, including the impact of the selection and explanatory power of predictors for a probabilistic model based on the Logit model. The research was carried out using 29 daily streamflow gauges located in the Lublin region of southeastern Poland for the hydrological period 1976–2018. Analysis resulted in two distinct low flow schemes. In the lowland rivers, low flows occur during the warm season and are related to evaporation exceeding precipitation. In the upland rivers, hydrogeological factors related to water levels in the local Cretaceous aquifers determine the occurrence of low flows. This differentiation affects the quality of the predictive models. For lowland rivers, models based on the climatic water balance with a monthly shift have a better fit, while these models used for upland rivers are characterized by an approximately 10% decrease in accuracy. For upland rivers, the combined C_tH_t models without shifts produce the best model fit. The generalized precision of the Logit models is around 80%–90%.     

Wetland soil moisture complicates the use of Sporormiella to trace past herbivore populations

Spores of the dung‐fungi Sporormiella provide a proxy for assessing past changes in herbivore abundance, and for temporally linking these with shifts in vegetation communities (pollen) and fire frequency (charcoal). Although the proxy is now widely used, potential influences of local environmental conditions are poorly understood. Here we assess the reliability of Sporormiella as a proxy of herbivores by presenting five new spore records from the South Island of New Zealand; a land where the herbivore extinction/introduction chronology is well established, and where extinctions occurred independently of major climate change. We show that Sporormiella spores from relatively dry soils provide a good proxy for herbivore extinctions and introductions. However, spore abundances from saturated soil sites appear to fluctuate in close correlation with changes in local hydrology (represented by wetland herb pollen, testate amoebae and moisture sensitive mosses). Our results suggest Sporormiella records derived from wetlands require cautious interpretation, and that proxies for hydrological conditions should also be considered when interpreting such records. Copyright © 2011 John Wiley & Sons, Ltd.     

Assessing stand water use in four coastal wetland forests using sapflow techniques: annual estimates,errors and associated uncertainties

Forests comprise approximately 37% of the terrestrial land surface and influence global water cycling. However, very little attention has been directed towards understanding environmental impacts on stand water use (S) or in identifying rates of S from specific forested wetlands. Here, we use sapflow techniques to address two separate but linked objectives: (1) determine S in four, hydrologically distinctive South Carolina (USA) wetland forests from 2009–2010 and (2) describe potential error, uncertainty and stand‐level variation associated with these assessments. Sapflow measurements were made from a number of tree species for approximately 2–8 months over 2 years to initiate the model, which was applied to canopy trees (DBH > 10–20 cm). We determined that S in three healthy forested wetlands varied from 1.97–3.97 mm day^?1 or 355–687 mm year^?1 when scaled. In contrast, saltwater intrusion impacted individual tree physiology and size class distributions on a fourth site, which decreased S to 0.61–1.13 mm day^?1 or 110–196 mm year^?1. The primary sources of error in estimations using sapflow probes would relate to calibration of probes and standardization relative to no flow periods and accounting for accurate sapflow attenuation with radial depth into the sapwood by species and site. Such inherent variation in water use among wetland forest stands makes small differences in S (<200 mm year^?1) difficult to detect statistically through modelling, even though small differences may be important to local water cycling. These data also represent some of the first assessments of S from temperate, coastal forested wetlands along the Atlantic coast of the USA. Copyright © 2014 John Wiley & Sons, Ltd.     

Hydrology on high: Assessing the effect of ski resort expansion and changing climate at the Mount Mansfield paired-catchment study in Vermont,USA

A paired-catchment study began in 2000 to assess the hydrologic effects of high-elevation development on Mt. Mansfield, Vermont's highest summit (1340 m). West Branch Little River drains 12.08 km² and encompasses a large ski resort. Adjacent Ranch Brook drains 9.83 km² of minimally disturbed second-growth forest. The two catchments have similar elevation, aspect, surficial and bedrock geology, and vegetation. The resort was well established before this study, but it underwent a major expansion during the period 2004–2008. The expansion included new ski lifts and trails, a large hotel, roads and second home development, a 435 000-m³ snowmaking storage pond and a nine-hole golf course, increasing the extent of cleared/open land from 17% to 24%. Runoff from the developed West Branch Little River catchment was 21% greater than Ranch Brook over the duration of the study, but varied widely each year from 10% to 42%. This high variability occurs both on the interannual and individual storm scales, and is consistent with expectations from future climate projections. Hydrologic variability is on the rise, as shown by an increase in stream flashiness in both catchments over the 20 years of our study. Resort expansion, which provided for stormwater management, had no discernible effect on the overall runoff difference nor the flow distribution at the scale of the catchments, but sedimentation, water quality impacts and localized erosion cannot be ruled out. Forest clearing, impervious and hardened surfaces, and skier-compacted and machine-made snow may all cause enhanced runoff. However, the greater runoff at West Branch, which occurs primarily during snowmelt and summer, may arise partly from greater precipitation capture in the complex mountain topography. Development pressure on the mountain landscape continues to mount, but managers may also need to consider the confounding effects of a changing climate.