Investigating the variations in carbon and nitrogen isotopes in carbonaceous chondrites

The carbonaceous chondrites contain significant amounts of carbon- and nitrogen-bearing components, the most abundant of which is organic matter. Stepped combustion data of whole rock and HF/HCl residues of carbonaceous chondrites reveal that the organic material can be subdivided operationally into three components: (1) free organic matter (FOM), which is readily extractable from whole-rock meteorites and is enriched in ¹³C and ¹⁵N; (2) labile organic matter (LOM), which has a macromolecular structure but is liberated by hydrous pyrolysis; LOM is the parent structure for some FOM and is also enriched in ¹³C and ¹⁵N; and (3) refractory organic matter (ROM), which is also macromolecular but is virtually unaffected by hydrous pyrolysis and is relatively depleted in ¹³C and ¹⁵N. The macromolecular entities (LOM and ROM) are by far the most abundant organic components present, and as such, the relative abundances of the ¹³C- and ¹⁵N-enriched LOM and the ¹³C- and ¹⁵N-depleted ROM will have a major influence on the overall isotopic composition of the whole-rock meteorite. Laboratory experiments designed to simulate the effects of parent body aqueous alteration indicate that this form of processing removes LOM from the macromolecular material, allowing ROM to exert a stronger influence on the overall isotopic compositions. Hence, aqueous alteration of macromolecular materials on the meteorite parent body may have a significant control on the stable isotopic compositions of whole-rock carbonaceous chondrites. The enstatite chondrites are also carbon rich but have been subjected to high levels of thermal metamorphism on their parent body. Stepped combustion data of HF/HCl residues of enstatite chondrites indicate, that if they and carbonaceous chondrites inherited a common organic progenitor, metamorphism under reducing conditions appears to incorporate and preserve some of the ¹³C enrichments in LOM during graphitisation. However, when metamorphism is at its most extreme, the ¹⁵N enrichments in LOM are lost.     

New insights into the heterogeneity of the Tagish Lake meteorite: Soluble organic compositions of variously altered specimens

The Tagish Lake carbonaceous chondrite exhibits a unique compositional heterogeneity that may be attributed to varying degrees of aqueous alteration within the parent body asteroid. Previous analyses of soluble organic compounds from four Tagish Lake meteorite specimens (TL5b, TL11h, TL11i, TL11v) identified distinct distributions and isotopic compositions that appeared to be linked to their degree of parent body processing (Herd et al. 2011; Glavin et al. 2012; Hilts et al. 2014). In the present study, we build upon these initial observations and evaluate the molecular distribution of amino acids, aldehydes and ketones, monocarboxylic acids, and aliphatic and aromatic hydrocarbons, including compound‐specific δ¹³C compositions, for three additional Tagish Lake specimens: TL1, TL4, and TL10a. TL1 contains relatively high abundances of soluble organics and appears to be a moderately altered specimen, similar to the previously analyzed TL5b and TL11h lithologies. In contrast, specimens TL4 and TL10a both contain relatively low abundances of all of the soluble organic compound classes measured, similar to TL11i and TL11v. The organic‐depleted composition of TL4 appears to have resulted from a relatively low degree of parent body aqueous alteration. In the case of TL10a, some unusual properties (e.g., the lack of detection of intrinsic monocarboxylic acids and aliphatic and aromatic hydrocarbons) suggest that it has experienced extensive alteration and/or a distinct organic‐depleted alteration history. Collectively, these varying compositions provide valuable new insights into the relationships between asteroidal aqueous alteration and the synthesis and preservation of soluble organic compounds.     

Seismic fragilities of single-column highway bridges with rocking column-footing

Rocking isolation has been increasingly studied as a promising design concept to limit the earthquake damage of civil structures. Despite the difficulties and uncertainties of predicting the rocking response under individual earthquake excitations (due to negative rotational stiffness and complex impact energy loss), in a statistical sense, the seismic performance of rocking structures has been shown to be generally consistent with the experimental outcomes. To this end, this study assesses, in a probabilistic manner, the effectiveness of using rocking isolation as a retrofit strategy for single-column concrete box-girder highway bridges in California. Under earthquake excitation, the rocking bridge could experience multi-class responses (eg, full contacted or uplifting foundation) and multi-mode damage (eg, overturning, uplift impact, and column nonlinearity). A multi-step machine learning framework is developed to estimate the damage probability associated with each damage scenario. The framework consists of the dimensionally consistent generalized linear model for regression of seismic demand, the logistic regression for classification of distinct response classes, and the stepwise regression for feature selection of significant ground motion and structural parameters. Fragility curves are derived to predict the response class probabilities of rocking uplift and overturning, and the conditional damage probabilities such as column vibrational damage and rocking uplift impact damage. The fragility estimates of rocking bridges are compared with those for as-built bridges, indicating that rocking isolation is capable of reducing column damage potential. Additionally, there exists an optimal slenderness angle range that enables the studied bridges to experience much lower overturning tendencies and significantly reduced column damage probabilities at the same time.     

Development of push moraines in deeply frozen sediment adjacent to a cold-based glacier in the McMurdo Dry Valleys,Antarctica

Previous studies of push moraines have concluded that structural architecture is controlled by a combination of stress exerted by flowing ice and the rheology of the deforming sediment. However, the relationship between deformation processes and the thermal/hydrologic conditions within the sediment remains ambiguous. Using a combination of surface mapping, logging exposures and ground penetrating radar we examine the relationships between surface morphology, material properties and development of deformation structures in deeply frozen sediment that has been deformed by Joyce Glacier, a cold-based glacier in the McMurdo Dry Valleys. The structural architecture of the push moraines is characterized by a combination of brittle and ductile deformation structures that have produced a structurally complex pattern of thrust faults, low angle listric thrusts and recumbent folds that extend 400 m beyond the glacier margin. Deformation is ductile where the ice concentration exceeds c. 65% volume and predominantly brittle where the ice concentration is less than c. 65%. The change in rheology reflects transition in behaviour from the material having a predominantly frictional character when the ice is limited to pore spaces to a non-frictional character in which strength is primarily determined by the cohesive strength of the ice. This work shows that glaciotectonic deformation can occur in deeply frozen permafrost where there is no liquid pore water. We conclude that the presence of liquid porewater is not a necessary condition for the development of glaciotectonic deformation or for the formation of push moraines. © 2019 John Wiley & Sons, Ltd.     

In situ analysis of platinum group elements in equilibrated ordinary chondrite kamacite and taenite

Platinum group element (PGE) concentrations have been determined in situ in ordinary chondrite kamacite and taenite grains via laser ablation inductively coupled plasma mass spectrometry (LA‐ICP‐MS). Results demonstrate that PGE concentrations in ordinary chondrite metal (kamacite and taenite) are similar among the three ordinary chondrite groups, in contrast to previous bulk metal studies in which PGE concentrations vary in the order H < L < LL. PGE concentrations are higher in taenite than kamacite, consistent with preferential PGE partitioning into taenite. PGE concentrations vary between and within metal grains, although average concentrations in kamacite broadly agree with results from bulk studies. The variability of PGE concentrations in metal decreases with increasing petrologic type; however, variability is still evident in most type six ordinary chondrites, suggesting that equilibration of PGEs does not occur between metal grains, but rather within individual metal grains via self‐diffusion during metamorphism. The constant average PGE concentrations within metal grains across different ordinary chondrite groups are consistent with the formation of metal via nebular condensation prior to the accretion of ordinary chondrite parent bodies. Post‐condensation effects, including heating during chondrule‐formation events, may have affected some element ratios, but have not significantly affected average metal PGE concentrations.     

Size fractionation and optical properties of colloids in an organic-rich estuary (Thurso, UK)

The optical characteristics of a black water river estuary from the north coast of Scotland were examined in the filtered (0.4 µm), ultrafiltered (5 kDa) and colloid-enriched fractions of estuarine samples. The samples were collected over the full salinity range during a period when the pH was relatively constant (8.2–8.5) throughout the estuary, allowing the influence of salinity on estuarine colloidal processes to be distinguished. The properties examined in the bulk, the low molecular weight (LMW) and the colloidal fraction (HMW) were UV–visible absorption, 3-D fluorescence excitation–emission matrix (EEM) spectrum, inorganic and organic carbon, mean size (by dynamic light scattering), and size distribution by flow field-flow fractionation analysis (FlFFF). The combined results of these analyses support the view that river-borne, humic-rich colloids underwent two types of transformation upon mixing with the seawater end member. The first one resulted in an apparent increase in the abundance of LMW constituents and may be explained by coiling of the individual humic macromolecules. The second one resulted in an increase in the mean size measured in both the lower and higher colloidal size ranges, and may be explained by aggregation of colloids to form entities that were still mostly colloidal i.e., smaller than 0.4 µm. The LMW contribution to the bulk optical properties increased with increasing salinity. Very similar findings were obtained from simulated mixing experiments using a Nordic Reference NOM extract as a source of freshwater colloids. This indicates that changes in the molecular architecture and molar mass of river-borne colloids—not changes in their chemical nature—were responsible for the observed variations in the spectral characteristics of CDOM in this estuary.     

A thousand year speleothem proxy record of North Atlantic climate from Scotland

Luminescent organic matter in stalagmites may form annual bands, allowing growth rate to be precisely determined. Stalagmite growth rate is controlled by precipitation, so annual bands can be used to derive long precipitation records. A continuously banded stalagmite from a cave in NW Scotland was used to provide a 1100?year high-resolution record of precipitation. The location of the cave means that precipitation is closely linked to the North Atlantic Oscillation, for which a record is also derived. This suggests that changes in the North Atlantic Oscillation state was an important control on European climate over the past millennium.     

Incorporating geographies of health into public policy debates: The GeoHealth Laboratory

Abstract:  The restricted influence of geographers in the policy arena has been the source of some angst. This paper reports on a new initiative at the University of Canterbury, which aims to strengthen geography's contribution to health policy debates in New Zealand. The GeoHealth Laboratory is a joint initiative between the Department of Geography and Public Health Intelligence group at the Ministry of Health that seeks to provide a pathway for the integration of health geography research into policy development. This new facility aligns the expertise in health geography, GIS and other spatial analytical methods with policy-relevant research priorities. An overview of the strategic aims of the GeoHealth Laboratory is provided along with some examples of recent research activities that are contributing to understandings of the health landscape in New Zealand. It is argued that such partnerships provide important opportunities for geographers to engage with policy-relevant issues.     

地铁隧道施工引起地层位移规律的探讨

目前对城市隧道开挖所引起的地表以下地层的位移规律的认识还很不充分，长期以来只有定性地认识。英国学者Mair等人（1993年）根据在黏土中的有限实测资料，基于预测地表位移的Peck公式，考虑了沉降槽宽度随深度变化，从而提出了地表以下的位移计算公式。他们的研究成果被广泛引用，但是由于其仅适用于黏性土，且假定地表处沉降槽宽度参数为0.5，因此在应用上受到很大的限制。在Mair公式的基础上，着重讨论了沉降槽宽度参数随地层深度的变化趋势，并提出了修正计算公式，不仅可以考虑地表沉降槽宽度参数与0.5相差较大的情况，还适用于砂类土地层，因此比Mair公式具有更广泛的适用性。     

Clay mineral‐organic matter relationships in the early solar system

Abstract— As the solar system formed, it inherited and perpetuated a rich organic chemistry, the molecular products of which are preserved in ancient extraterrestrial objects such as carbonaceous chondrites. These organic‐rich meteorites provide a valuable and tangible record of the chemical steps taken towards the origin of life in the early solar system. Chondritic organic matter is present in the inorganic meteorite matrix which, in the CM and CI chondrites, contains evidence of alteration by liquid water on the parent asteroid. An unanswered and fundamental question is to what extent did the organic matter and inorganic products of aqueous alteration interact or display interdependence? We have used an organic labelling technique to reveal that the meteoritic organic matter is strongly associated with clay minerals. This association suggests that clay minerals may have had an important trapping and possibly catalytic role in chemical evolution in the early solar system prior to the origin of life on the early Earth.