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161.
162.
Late summer hypoxia (<3 ppm oxygen) in western Long Island Sound (WLIS) is a persistent environmental and management issue whose controlling processes are poorly understood. Measured rates of sediment and water-column oxygen consumption in the bottom water suggest that a condition of no oxygen should be attained on the time scale of 13–30 d. Observations, however, indicate the onset of hypoxia is of the order 150 d. Therefore, horizontal and/or vertical transport of oxygen into the area of hypoxia must play an important role. Hypoxia decreases benthic activity and the sediment flux of222Rn. The resulting horizontal gradient in bottom water222Rn was measured and used to estimate the effective horizontal transport rate (>5–50 m2 s?1), which is considerably slower than previous estimates. Scale analysis of the hypoxia process indicates that horizontal transport rates alone can explain the slow progression of hypoxia in XLIS but that vertical processes may also be capable of delaying the onset of hypoxia especially under conditions of weak stratification or weak intermediate layer oxygen consumption. This scale analysis indicates a delicately balanced process that is sensitive to both climatologically-driven variability in the rates of horizontal and vertical transport as well as the biologically-driven rates of oxygen consumption. An improved ability to predict and/or control hypoxia must be based on a better understanding of temporal and spacial variations in circulation, mixing, and stratification as well as the biological processes in the water column and the sediments. 相似文献
163.
Robert W. Nesbitt Takafumi Hirata Ian B. Butler James A. Milton 《Geostandards and Geoanalytical Research》1997,21(2):231-243
This study reports a series of applications of UV laser ablation ICP-MS in the geological sciences. The advantages and disadvantages of the PQ "S" option and the use of nitrogen in the carrier gas are discussed. A general problem common to all ablation techniques is the calibration technique and experiments involving synthetic calibration samples are covered. Zircon geochemistry and geochronology by LA-ICP-MS are discussed and data are presented for REE, Hf and U for a standard zircon (91500) as well as a series of zircons from Zimbabwe. The potential of using Ce and Eu anomalies in petrologic studies is illustrated by zircons from a fractionated gabbroic-granite in the Urals. The potential of the LA-ICP-MS method to utilise standard X-ray fluorescence glass discs is demonstrated as a useful semi-quantitative tool in determining REE patterns. LA-ICP-MS is a powerful tool in the analysis of the platinum group elements (and Re) and some examples are given in the successful application of the technique to partitioning in iron meteorites. 相似文献
164.
Sharon S. Crowley Peter D. Warwick Leslie F. Ruppert James Pontolillo 《International Journal of Coal Geology》1997,34(3-4)
The origin and distribution of twelve potentially Hazardous Air Pollutants (HAPs; As, Be, Cd, Cr, Co, Hg, Mn, Ni, Pb, Sb, Se, and U) identified in the 1990 Clean Air Act Amendments were examined in relation to the maceral composition of the A1 bed (Paleocene, Calvert Bluff Formation, Wilcox Group) of the Calvert mine in east-central Texas. The 3.2 m-thick A1 bed was divided into nine incremental channel samples (7 lignite samples and 2 shaley coal samples) on the basis of megascopic characteristics. Results indicate that As, Cd, Cr, Ni, Pb, Sb, and U are strongly correlated with ash yield and are enriched in the shaley coal samples. We infer that these elements are associated with inorganic constituents in the coal bed and may be derived from a penecontemporaneous stream channel located several kilometers southeast of the mining block. Of the HAPs elements studied, Mn and Hg are the most poorly correlated to ash yield. We infer an organic association for Mn; Hg may be associated with pyrite. The rest of the trace elements (Be, Co, and Se) are weakly correlated with ash yield. Further analytical work is necessary to determine the mode of occurrence for these elements. Overall, concentrations of the HAPs elements are generally similar to or less than those reported in previous studies of lignites of the Wilcox Group, east-central region, Texas. Petrographic analysis indicates the following ranges in composition for the seven lignite samples: liptinites (5–8%), huminites (88–95%), and inertinites (trace amounts to 7%). Samples from the middle portion of the A1 bed contain abundant crypto-eugelinite compared to the rest of the samples; this relationship suggests that the degradation of plant material was an important process during the development of the peat mire. With the exception of Hg and Mn, relatively low levels of the HAPs elements studied are found in the samples containing abundant crypto-eugelinite. We infer that the peat-forming environment for this portion of the coal bed was very wet with minimal detrital input. Relatively high concentrations of crypto-humotelinite were found in samples from the top and base of the coal bed. The presence of abundant crypto-humotefinite in this part of the coal bed suggests the accumulation of wood-rich peat under conditions conducive to a high degree of tissue preservation in the peat mire. Although several of the trace elements (Be, Co, Ni, and Sb) exhibit enrichment in these samples, they are not necessarily chemically associated with humotelinite. We infer that these elements, with the exception of Be, are possibly associated with deposition of the roof and floor rock of the coal bed; however, further analytical work would be necessary to confirm this hypothesis. Beryllium may have an organic origin. 相似文献
165.
James Derrick Sidaway 《Area》1997,29(1):72-80
Summary A brief investigation of certain missing links in the narration of the history of geography focuses on the need to consider the contribution of non-western geographical and scientific knowledges to the making of 'European discovery' and therefore to the development of a putatively western geographical tradition. 相似文献
166.
James Taylor 《Area》1997,29(2):160-171
Summary This paper discusses the relationship between advertising and 'race', using as its foundation the replication of a study conducted in the US which used content analysis to examine the representation of Black characters in television advertisements. The replication facilitates a comparison of the British and American cases, revealing significant differences in the frequency and perceived importance of such representations. It can also help draw out the specificities of the UK situation. The paper attempts to convey the complexity of the interplay between advertising and racialisation, and emphasises that while such quantitative, textual studies offer a useful basis for further research, they are limited by their failure to address the motivations of producers and how advertisements are read by different groups in different places. 相似文献
167.
Tectonic implications of S-wave anisotropy beneath SE Brazil 总被引:1,自引:0,他引:1
168.
169.
Distribution and morphology of sinkholes triggered by flooding following Tropical Storm Alberto at Albany, Georgia, USA 总被引:1,自引:0,他引:1
Flooding of the Flint River in July 1994 triggered the collapse of at least 312 sinkholes in the karstic Dougherty Plain at Albany, Georgia. We examined the distribution and morphology of these new sinkholes to evaluate the mode of formation, to characterize early stages of the evolution of sinkhole form, and to estimate the lowering of the surface associated with the development of new sinkholes.Eighty-eight percent of sinkholes occur inside the limits of flooding, especially in areas of sandy overburden, and they often follow joint-controlled linear trends. Sinkhole dimensions are log-normally distributed with median values of circumference = 5.7 m, length = 1.8 m, width = 1.6 m, and depth = 0.7 m; asymmetry (L:W) = 1.2. Cross-sectional forms range from narrow cylinders to large bowls, with many sinkholes having undercut sides.Flooding triggered the formation of sinkholes by saturating and liquefying overburden, which caused soil arches to collapse and flow into cavities in bedrock. The prevalence of sinkholes near the periphery of flooding suggests that drainage and loss of buoyant support as flood waters subsided may also have contributed to failure. A volume ratio index is used to quantify the three dimensional geometric form of sinkholes. Initially, small cylindrical shafts open over a bedrock joint, followed by progressive slumping that leads to widening and increases in volume to a final bowl form. Estimates of the aggregate volume of overburden transported underground in flooded areas range from 7,990 to 11,130 m3. Averaged over flooded areas, this accounts for 0.26 to 0.37 mm/km2 lowering of the surface. Based on a 500 year recurrence interval for the flood event, values for lowering of the surface range from 0.52 to 0.74 mm per 1,000 years. These values are an order of magnitude less than estimates of carbonate dissolution and suggest that transport of overburden underground is limited by triggering events. 相似文献
170.