Structural Spatial Interaction*

This paper identifies a concept of structural spatial interaction. Although it is defined differently from its counterpart of structural unemployment in economics, it attempts to define a similar idea. In economics, the focus is on equilibrium in the supply and demand of labor. In this paper structural interaction is that which minimizes aggregate distance travelled, subject to constraints on origins and destinations. The structural interaction model produces an equilibrium, therefore, in the supply and demand of movers, while identifying a spatially efficient trip distribution. It is portrayed as a type of relaxed interaction model and is illustrated using an example of structural migration with Canadian interprovincial migration data.     

Formation of humic-like substances by fungi epiphytic onSpartina alterniflora

In laboratory experiments, two fungi that commonly colonize leaves of Spartina aZterniJEoru(L oisel.) were studied to determine if they contribute to the formation of humic substances, which have been isolated earlier from salt marsh estuaries. In incubations of up to one year in duration, Phaeosphaeria spartinicola and Phaeosphaeria halima did not form dark pigments when grown in an artificial, full-nutrient medium. However, if the nutrient solution was enriched with a water extract of S. alterniJEoro, appreciable amounts of dark brown substances were produced. Elemental (C, H, N, 0) and spectral (ultraviolet, visible, and Fourier Transform Infrared) analyses of these dark brown substances show them to be similar to salt marsh humic substances.     

Characterizing the dispersive state of convective boundary layers for applied dispersion modeling

Estimates from semiempirical models that characterize surface heat flux, mixing depth, and profiles of temperature, wind, and turbulence are compared with observations from atmospheric field studies conducted in Colorado, Illinois, Indiana, and Minnesota. Sodar observations are compared with tower measurements at the Colorado site, for wind and turbulence profiles. The median surface heat flux, as calculated using surface-layer flux-profile relationships and an energy budget model, was consistently overestimated by 20 to 80%. Several mixing-depth models were evaluated: (1) integration of the hourly surface heat flux and friction velocity, (2) solving for the time rate of change of profiles of virtual potential temperature, and (3) an interpolation scheme used by the U.S. Environmental Protection Agency in regulatory dispersion models. For the late afternoon, 80 to 90% of the estimates from the first and third models were within 40% of the observed values. For the morning hours after sunrise, all were less accurate. Temperature estimates from surface-layer flux-profile relationships compared well with observations within the mixed layer, but were too low for the inversion layer aloft. Wind profiles were derived using surface-layer flux-profile relationships, a windprofile power-law based on Pasquill stability category, and sodar measurements. The sodar measurements were superior to both types of model estimates. Turbulence profiles were derived from sodar measurements and from semiempirical similarity relationships based on mixing depth and Obukhov length. The scatter in the comparisons with the sodar observations is twice that seen in the comparisons with empirical profile relationships. Overall, it appears that uncertainty of as low as 20 to 30% in the characterization of the diffusion meteorology is the exception rather than the rule.On assignment from the National Oceanic and Atmospheric Administration, U. S. Department of Commerce.Disclaimer: Although the research described in this article has been supported by the United States Environmental Protection Agency, it has not been subjected to Agency review and therefore does not necessarily reflect the views of the Agency and no official endorsement should be inferred. Mention of trade names or commercial products does not constitute endorsement or recommendation for use.     

Factors Affecting Efficient Aquifer Restoration at In Situ Uranium Mine Sites

In situ mining of uranium typically requires the injection of a reactive leaching solution (lixiviant) such as sodium carbonate/bicarbonate, ammonium carbonate/bicarbonate, or sulfuric acid, and an oxidant such as hydrogen peroxide or oxygen into an ore-bearing, confined aquifer. It also requires the environmental restoration of the source aquifer. The stratigraphy of sandstone uranium deposits typically consists of interbedded layers of poorly consolidated sands and clays and gravels deposited in fluvial or coastal environments. The parameters that influence the migration of lixiviant during mining and restoration in these environments include induced hydraulic gradients, hydrodynamic dispersion, heterogeneity, anisotropy, physicochemical reactions, leakage into and/or through confining layers, and convergence of flow lines due to partial well penetration.
The effectiveness of the various methods of aquifer restoration is sit -specific and is dependent upon the site hydrogeology and hydrogeochemistry, and the chemistry of the lixiviant. Each method of aquifer restoration has advantages and disadvantages. Selection of the most effective and economically feasible method requires detailed knowledge of the site-specific hydrogeologic conditions.     

Modeling the Potential Effect of Additives on Enhancing the Solubility of Aromatic Solutes Contained in Gasoline

The potential effect of two common gasoline additives, ethanol and methyl tertiary-butyl ether (MTBE), on enhancing the solubility of the aromatic solutes benzene, toluene, ethylbenzene, and o-, m-, and p-xylene, was examined using a computer model, ARSOL. Aqueous solute systems containing cosolvents ethanol and MTBE at 0, 0.1, 1, and 4.3 percent were modeled for both ethanol and MTBE systems. Five- and 10-percent ethanol systems were also modeled. Little solubility enhancement was predicted by modeling at cosolvent levels less than 1 percent. At cosolvent levels greater than 1 percent, predicted solute solubility increased curvilinearly with an increase in percent cosolvent; a 10 percent cosolvent system increased aromatic hydrocarbon solubility by approximately 100 percent. According to the model predictions, MTBE enhanced solute solubility more than ethanol, with enhancement by MTBE being approximately 10 percent greater than enhancement by ethanol at 4.3 percent cosolvent. Other concerns regarding gasoline additives are the observed reduction in partitioning of solutes to soils and sediments and the contamination of water supplies due to the high water solubility of the additives.     

An example of slip instability resulting from displacement-varying strength

A rock cylinder, containing a clay-filled sawcut making an angle of 30° to the sample axis, was deformed at constant confining and pore pressures and constant remote shortening rate. The sawcut surfaces contained a series of regularly spaced ridges and grooves oriented perpendicular to the direction of shear. The interaction of these grooved surfaces resulted in a sliding strength which varied periodically with displacement. By varying the effective machine stiffness through the use of an electronic feedback circuit, a range of stable and unstable slip behavior was achieved. In this way, we examined fault slip behavior which was dominated by displacement-dependent strength.     

The characterization of axenic culture systems suitable for plant propagation and experimental studies of the submersed aquatic angiospermPotamogeton pectinatus (Sago Pondweed)

Clonal lines of the submersed aquatic angiospermPotamogeton pectinatus were grown in three culture systems. The first, which used sucrose as a carbon source in a liquid medium, supported vigorous vegetative growth and can be used to propagate large numbers of plants in axenic conditions. In this culture system, plants were responsive to increasings photosynthetically active radiation (PAR) photon flux density (PFD) and were photosynthetically competent. However, their growth was heterotrophic and root development was poor. When these plants were transferred to a second nonaxenic culture system, which used 16-1 buckets containing artificial sediments and tap water, growth was autotrophic and plants were morphologically identical to field-harvestedP. pectinatus. The last culture system which consisted of a sand substrate and inorganic nutrient bathing solution aerated with 135 ml min^?1 ambient air enhanced to 3.0% CO₂ was axenic and supported autotrophic growth by plants that were also morphologically normal.