Chemical aspects of iron oxide coagulation in water: Laboratory studies and implications for natural systems

Initial coagulation rates of colloidal hematite (-Fe₂O₃) particles (diameter less than 0.1 µm) were measured experimentally in well-defined laboratory systems at constant temperature. The relative stability ratio,W, was obtained at various ionic strengths in NaCl medium and at pH values in the range from 3 to 12. ExperimentalW values ranged from 1 to 10⁴ in various systems. The results delineate the roles ofspecific andgeneralized coagulation mechanisms for iron oxides. Among the specifically-interacting species (G _ads ⁰ >G _coul ⁰ ) studied were phosphate, monomeric organic acids of various structures, and polymeric organic acids. The critical coagulation-restabilization concentrations of specifically-interacting anions (from 10^–7 to 10^–4 molar) can be compared with the general effects of non-specific electrolyte coagulants (10^–3 to 10^–1 molar). The laboratory results are interpreted with the help of a Surface Complex Formation/Diffuse Layer Model (SCF/DLM) which describes variations of interfacial charge and potential resulting from variations of coagulating species in solution. Comparison of these laboratory experiments with observations on iron behavior in estuarine and lake waters aids in understanding iron removal mechanisms and coagulation time scales in natural systems.     

Hypersensitization of Kodak infrared plates: Results of some chemical methods and pre-exposure

Tests have been carried out on Kodak Spectroscopic Plates Type I-N, in order to find a treatment which could be easily applied to the infrared plates to be used with the Loiano 152 cm,f/8, Ritchey-Chrétien telescope. Different techniques have been tested, not only with the aim of achieving the higher speed gain, but also to obtain the better uniformity and reproducibility. Our results suggest that the advantages of preexposure techniques are underestimated in this respect. Furthermore, we find that blue and infrared preexposures (at 0.8 s) give different results, suggesting a different degree of dispersity in the latent image produced by pre-exposure in the two cases.Baths including both ammonia and Ag-compounds provide the higher speed gains, but the increment of the fog is often non-uniform and/or very high. The best results have been obtained with baths including AgNO₃ and AgCl. The rejuvenation process found by Sanduleak and the results obtained by Jenkins and Farnell on the reversibility of the gains due to silver-nitrate baths have been confirmed.     

Compton scattering of relativistic electrons in compact X-ray sources

The problem of single Compton scattering is considered and the resulting spectrum, angular distribution and polarization of scattered photons in a general case are obtained. The inverse Compton scattering (ICS) for arbitrary energies of electronsE and photons ₀ is investigated in detail. In the case of isotropically-distributed initial photons and relativistic electrons, a strong rise of the scattered spectrum near the upper edge takes place, starting from the values of the characteristic parameterb4E ₀10 (in units of mc²=1). The energy-loss rate of relativistic electrons due to ICS is calculated. It is shown that the relativistic electrons of the energiesE100 MeV, when scattering on the X-rays with ₀~10KeV, transmit the dominant part of their energy to the photons which fall after scattering into the energy range of the electrons (100 MeV).The radiation spectrum of ICS, as well as the energy-losses of relativistic electrons distributed by power-lawE ^–, are calculated. The radiation spectrum reveals the power-law behaviour with the different indices in two limits: the dependence ^–(1)/2 at ₀1 gradually changes to ^–(+1) ln (₀) law for ₀1.     

The spectra and light curves of two gamma-ray bursts

During the last half of 1977 the UCSD/MIT Hard X-Ray and Low Energy Gamma-Ray Experiment of HEAO-1 observed two of the three gamma-ray bursts detected by at least three satellites. The first of these bursts (20 October, 1977) had a fluence of (3.1±0.5)×10^–5 erg cm^–2 integrated over the energy range 0.135–2.05 MeV and over its duration of 38.7 s, placing it among the largest bursts observed. The second (10 November, 1977) had a fluence of (2.1±0.8)×10^–5 erg cm^–2 integrated over the energy range 0.125–3 MeV and over its duration of 2.8 s. The light curves of both bursts exhibit time fluctuations down to the limiting time resolution of the detectors (0.1 s). The spectrum of the 20 October, 1977 burst can be fitted with a power law (index –1.93±0.16), which is harder than other reported gamma-ray burst spectral fits. This burst was detected up to 2.05 MeV, and approximately half of its energy was emitted at photon energies above 0.5 MeV. The spectrum of the 10 November, 1977 burst is softer (index –2.4±0.7) and is similar to the spectrum of the 27 April, 1972 burst.Paper presented at the Symposium on Cosmic Gamma-Ray Bursts held at Toulouse, France, 26–29 November, 1979.     

OSO-8 observations of CaII H and K,MgII h and k,Lα and Lβ above a sunspot

Observations with the French (L.P.S.P.) experiment on board OSO-8 of a sunspot and nearby plage region are described. The behaviour of the emission cores of the Ca II H and K and Mg II h and k resonance lines is very similar and the correspondence in intensity between the four lines persists in all observed features. In contrast, the Lyman lines show little correlation with the other lines. Their emission regions appear broader in the spectroheliograms than the underlying sunspot structure and must not necessarily possess a counterpart in lower layers. From the central intensity of L above the umbra an electron density of 4.3 × 10¹⁰ cm^-3 n _e ^* 2.3 × 10¹¹ cm^-3 at 20 000 K is estimated.Mitteilungen aus dem Kiepenheuer-Institut Nr. 186.Stockholm Observatorium, S-13300 Saltsjöbaden, Sweden.Laboratoire de Physique Stellaire et Planétaire, CNRS, P.O. Box 10, F-91370 Verrières-le-Buisson, France.     

The inter-relationship of hard X-ray and EUV bursts during solar flares

A comparison is made between the flux-versus-time profile in the EUV band and the thick target electron flux profile as inferred from hard X-rays for a number of moderately large solar flares. This complements Kane and Donnelly's (1971) study of small flares. The hard X-ray data are from ESRO TD-1A and the EUV inferred from SFD observations.Use of a ₂ minimising method shows that the best overall fit between the profile fine structures obtains for synchronism to 5 s which is within the timing accuracy. This suggests that neither conduction nor convection is fast enough as the primary mechanism of energy transport into the EUV flare and rather favours heating by the electrons themselves or by some MHD wave process much faster than acoustic waves.The electron power deposited, for a thick target model, is however far greater than the EUV luminosity for any reasonable assumptions about the area and depth over which EUV is emitted. This means that either most of the power deposited is conducted away to the optical flare or that only a fraction 1–10% of the X-ray emitting electrons are injected downwards. Recent work on H flare heating strongly favours the latter alternative - i.e. that electrons are mostly confined in the corona.     

Fair weather and storm sand transport on the Long Island, New York, inner shelf

Both spring-summer and fall-winter sand transport have been observed on the Long Island, New York, inner shelf at water depths of 20-22 m using a radio-isotope sand tracer system. The extent of dispersal of the tagged, fine sand was measured at 3 week intervals in two 70 day experiments. In the late spring and early summer, movement was primarily diffusive in nature, extending 100 m around the line of tracer injection, while late fall-winter patterns had strong advective features, including an ellipsoidal outline extending approximately 1500 m westward of the injection points after the passage of several storms with strong northeasterly winds. Near-bottom current observations made with Savonius rotor sensors identify the event responsible for the bulk of the transport over the 135 day observation period as a storm flow of 2 days duration. Tracer and current observations together suggest that westward winter storm flow along the Long Island shelf is the major mechanism of sand transport at these depths on a yearly time scale. A least-squares fit of several of the observed winter patterns with a plume model yields average sediment mass flux lower bounds of 3.2 × 10^?3 gm/cm/sec and 1.7 × 10^?1 gm/cm/sec for ‘typical’ and extreme winter storm activity.     

Direct imaging of extra-solar planets with stationary occultations viewed by a space telescope

The feasibility of detecting planets outside the solar system through imaging at optical wavelengths by a telescope in space is considered. The “black” limb of the moon can be used as an occulting edge to greatly reduce the background light from the planet's star. With this technique and if certain other technical requirements can be realized, a hypothetical Jupiter-Sun system could be detected at a distance of 10 pc. For this system, a signal-to-noise ratio of 9 could be achieved in less than 20 min with a 2.4-m telescope in space. For diffraction limited optics, the required integration time is inversely proportional to the fifth power of the telescope aperture. An orbit for the telescope is described that could achieve a stationary lunar occultation of any star that would last nearly two hours, providing six times more integration time than required by the hypothetical Jupiter-Sun example.