Kinetics of hepatic phase I and II biotransformation reactions in eight finfish species

Hepatic microsomes and cytosols of channel catfish (Ictalurus punctatus), rainbow trout (Oncorhynchus mykiss), Atlantic salmon (Salmo salar), red tilapia (Oreochromis sp.), largemouth bass (Micropterus salmoides), striped bass (Morone saxatilis), hybrid striped bass (M. saxatilis × M. crysops), and bluegill (Lepomis macrochuris) (n = 8) were used to study the kinetics of phase I (ECOD, EROD, PROD, BROD) and phase II (UDP-glucuronosyltransferase (UDPGT)-, sulfotransferase (ST)- and glutathione-s-transferase (GST)-mediated) reactions. The best catalytic efficiency for ECOD and GST activities was performed by channel catfish, Atlantic salmon, rainbow trout and tilapia. The highest EROD catalytic efficiency was for Atlantic salmon. None of the species had either PROD or BROD activities. Rainbow trout had very similar UDPGT catalytic efficiency to tilapia, channel catfish, Atlantic salmon, largemouth bass and bluegill. Sulfotransferase conjugation had no significant differences among the species. In summary, tilapia, channel catfish, Atlantic salmon and rainbow trout had the best biotransforming capabilities; striped bass, hybrid striped bass and bluegill were low metabolizers and largemouth bass shared some capabilities with both groups.     

Geochemical constraints on the stability of zeolites and C-S-H in the high pH reaction of bentonite

Cement-bentonite interactions will occur in deep geological repositories for high level radioactive waste. We performed laboratory experiments in order to constrain some previous geochemical and mineralogical uncertainties in the formation of secondary minerals in the high pH reaction of FEBEX bentonite at moderate temperatures.The reactivity of a Mg-homoionic FEBEX bentonite was studied at 25, 60 and 90 °C in batch reactors using two solutions representative of short and long time evolution stages of cement degradation. These solutions were periodically renewed in order to maintain a constant pH regime for a period of almost 2 years.Chabazite and merlinoite were observed to be the main zeolites that formed at 60 °C, while merlinoite was the dominant zeolite formed at 90 °C with the hyperalkaline (K-Na-OH) solution. The alkaline experiments (Ca-OH solution) showed minor reactivity and negligible mineralogical alteration, but the overall results suggest that the reaction tends to equilibrium conditions between C-S-H and montmorillonite at high temperature and metastable conditions at low temperature. The montmorillonite dissolution rates were calculated for all experiments, showing good agreement with previous calculations.     

Drivers of peatland water table dynamics in the central Andes,Bolivia and Peru

Cushion plant dominated peatlands are key ecosystems in tropical alpine regions of the Andes in South America. The cushion plants have formed peat bodies over thousands of years that fill many valley bottoms, and the forage produced by the plants is critical for native and nonnative domesticated mammals. The sources and flow paths of water supporting these peatlands remain largely unknown. Some studies have suggested that glacier meltwater streams support some peatlands, and that the ongoing loss of glaciers and their meltwaters could lead to the loss or diminishment of peatlands. We analysed the hydrologic regime of 10 peatlands in four mountain regions of Bolivia and Peru using groundwater monitoring. Groundwater levels in peatlands were relatively stable and within 20 cm of the ground surface during the rainy season, and many sites had water tables 40–90 cm below the ground surface in the dry season. Topographic and groundwater elevations in the peatlands demonstrated that the water source of all 10 peatlands was hillslope groundwater flowing from lateral moraines, talus, colluvium, or bedrock aquifers into the peatlands. There was little to no input from streams, whether derived from glacier melt or other sources, and glacier melt could not have recharged the hillslope aquifers supporting peatlands. We measured the stable water isotopes in water samples taken during different seasons, distributed throughout the catchments, and the values are consistent with this interpretation. Our findings indicate that peatlands in the study region are recharged by hillslope groundwater discharge rather than stream water and may not be as vulnerable to glacial decline as other studies have indicated. However, both glaciers and peatlands are susceptible to changing thermal and precipitation regimes that could affect the persistence of peatlands.     

Puerto Lápice eucrite fall: Strewn field,physical description,probable fireball trajectory,and orbit

Abstract— The fall of the Puerto Lápice eucrite occurred on May 10, 2007, at 17 h 57 m 30 ± 30 s UTC. Its daylight fireball was witnessed by hundreds of people from Spain, and produced a meteorite fall associated with a large strewn field of fragments. There were no direct pictures of the fireball, but several pictures of the fireball's train were taken from different locations in Spain. Additional theodolite calibrations of visual records were made in order to find the most probable fireball trajectory based on the available data. The shape of the meteorite strewn field was considered as well. Although the orbit of the Puerto Lápice meteoroid could not be computed due to the absence of velocity data, we assumed a likely range of geocentric velocities and computed a range of possible orbits. All solutions show that the body was in an Apollo‐type orbit, with low inclination and perihelion distance just below 1 astronomical unit (AU). This is the first case that an orbit can be discussed for an HED meteorite fall.     

Mercurian impact ejecta: Meteorites and mantle

Abstract— We have examined the fate of impact ejecta liberated from the surface of Mercury due to impacts by comets or asteroids, in order to study 1) meteorite transfer to Earth, and 2) reaccumulation of an expelled mantle in giant‐impact scenarios seeking to explain Mercury's large core. In the context of meteorite transfer during the last 30 Myr, we note that Mercury's impact ejecta leave the planet's surface much faster (on average) than other planets in the solar system because it is the only planet where impact speeds routinely range from 5 to 20 times the planet's escape speed; this causes impact ejecta to leave its surface moving many times faster than needed to escape its gravitational pull. Thus, a large fraction of Mercurian ejecta may reach heliocentric orbit with speeds sufficiently high for Earth‐crossing orbits to exist immediately after impact, resulting in larger fractions of the ejecta reaching Earth as meteorites. We calculate the delivery rate to Earth on a time scale of 30 Myr (typical of stony meteorites from the asteroid belt) and show that several percent of the high‐speed ejecta reach Earth (a factor of 2–3 less than typical launches from Mars); this is one to two orders of magnitude more efficient than previous estimates. Similar quantities of material reach Venus. These calculations also yield measurements of the re‐accretion time scale of material ejected from Mercury in a putative giant impact (assuming gravity is dominant). For Mercurian ejecta escaping the gravitational reach of the planet with excess speeds equal to Mercury's escape speed, about one third of ejecta reaccretes in as little as 2 Myr. Thus collisional stripping of a silicate proto‐Mercurian mantle can only work effectively if the liberated mantle material remains in small enough particles that radiation forces can drag them into the Sun on time scale of a few million years, or Mercury would simply re‐accrete the material.     

Middle Eocene deformation–sedimentation in the Luracatao Valley: Tracking the beginning of the foreland basin of northwestern Argentina

The Andean foreland basin overlaps the Cretaceous-Paleogene Salta rift basin in northwestern Argentina. Knowledge of the relationship between rift and foreland basins is key to understanding the initial stages of foreland basin development related to Andean shortening. We present a new stratigraphic scheme for the Luracatao Valley, revealing that the Quebrada de los Colorados Formation (Payogastilla Group) lies over the Santa Bárbara Subgroup (Salta Group) through an erosional unconformity that turns into an angular unconformity close to folds and faults recorded in the Santa Bárbara Subgroup. The base of the Quebrada de los Colorados Formation shows growth strata along the west frontal limb of an anticline with Santa Bárbara units in its core. The finding of a mammalian fossil at the base of the Quebrada de los Colorados Formation allows us to assign a Middle-Upper Eocene age to the sedimentation; therefore, the time elapsed between the deposition of the final postrift strata and the beginning of Andean sedimentation was brief and constrained to the Lower-Middle Eocene. This data indicates that the Eocene deformation phase described in other portions of the Puna-Cordillera Oriental transition (e.g., the northern Calchaquí Valley and Aguilar range) is also present in the Luracatao Valley, offering new tools for interpreting the ages and distributions of the initial episodes of sedimentation and deformation related to the Andean shortening. Thus, the Luracatao Valley provides new evidence for tracking the distribution of the Paleogene deformation in northwestern Argentina.     

A Blocking Markov Chain Monte Carlo Method for Inverse Stochastic Hydrogeological Modeling

An adequate representation of the detailed spatial variation of subsurface parameters for underground flow and mass transport simulation entails heterogeneous models. Uncertainty characterization generally calls for a Monte Carlo analysis of many equally likely realizations that honor both direct information (e.g., conductivity data) and information about the state of the system (e.g., piezometric head or concentration data). Thus, the problems faced is how to generate multiple realizations conditioned to parameter data, and inverse-conditioned to dependent state data. We propose using Markov chain Monte Carlo approach (MCMC) with block updating and combined with upscaling to achieve this purpose. Our proposal presents an alternative block updating scheme that permits the application of MCMC to inverse stochastic simulation of heterogeneous fields and incorporates upscaling in a multi-grid approach to speed up the generation of the realizations. The main advantage of MCMC, compared to other methods capable of generating inverse-conditioned realizations (such as the self-calibrating or the pilot point methods), is that it does not require the solution of a complex optimization inverse problem, although it requires the solution of the direct problem many times.