Mercury colonial footprint in Darién Gulf sediments,Colombia

The mercury (Hg) deposition history in the Darién Gulf is reconstructed from three sediment cores spanning up to 1,000 years. Knowledge on the contribution to global Hg budget from the Caribbean is limited. Patterns of water circulation, sediment deposition rates, cataclysmic atmospheric inputs, and post-depositional migration have been considered in Hg trapping in the seabed. The sediment delivery rates to the coastal zone over the Late Holocene have increased from 0.2 to 1 cm year^?1 owing to anthropogenic influence. This alteration took the form of geological effects, like coastal morphology change, that played a major role in Hg downcore signal preservation. Natural background Hg levels in Southern Caribbean sediments (77.0 μg kg^?1) are up to three times higher than preindustrial signals at other latitudes, because of volcanic contributions from the Pacific ring of fire. Enrichment factors rose from 0.9 to 1.5 (70.1–113.5 μg kg^?1) within profiles related to Hg usage since Spanish colonial times between the calendar years 1550 and 1811.     

Coupled inverse modelling of groundwater flow and mass transport and the worth of concentration data

This paper presents the extension of the self-calibrating method to the coupled inverse modelling of groundwater flow and mass transport. The method generates equally likely solutions to the inverse problem that display the variability as observed in the field and are not affected by a linearisation of the state equations. Conditioning to the state variables is measured by an objective function including, among others, the mismatch between the simulated and measured concentrations. Conditioning is achieved by minimising the objective function by gradient-based methods. The gradient contains the partial derivatives of the objective function with respect to: log conductivities, log storativities, prescribed heads at boundaries, retardation coefficients and mass sources. The derivatives of the objective function with respect to log conductivity are the most cumbersome and need the most CPU-time to be evaluated. For this reason, to compute this derivative only advective transport is considered. The gradient is calculated by the adjoint-state method. The method is demonstrated in a controlled, synthetic study, in which the worth of concentration data is analysed. It is shown that concentration data are essential to improve transport predictions and also help to improve aquifer characterisation and flow predictions, especially in the upstream part of the aquifer, even in the case that a considerable amount of other experimental data like conductivities and heads are available. Besides, conditioning to concentration data reduces the ensemble variances of estimated transmissivity, hydraulic head and concentration.     

Holocene-emerged notches and tectonic uplift along the Jalisco coast, Southwest Mexico

This paper presents the preliminary results from a study of Holocene-emerged shorelines, marine notches, and their tectonic implications along the Jalisco coast. The Pacific coast of Jalisco, SW Mexico, is an active tectonic margin. This coast has been the site of two of the largest earthquakes to occur in Mexico this century: the 1932 (Mw 8.2) Jalisco earthquake and the 1995 (Mw 8.0) Colima earthquake. Measurement and preliminary radiocarbon dating of emergent paleoshorelines along the Jalisco coast provide the first constraints upon the timing for tectonic uplift. Along this coastline, uplifted Holocene marine notches and wave-cut platforms occur at elevations ranging from ca. 1 to 4.5 m amsl. In situ intertidal organisms dated with radiocarbon, the first ever reported for the Jalisco area, provide preliminary results that record tectonic uplift during at least the past 1300 years BP at an average rate of about 3 mm/year. We propose a model in which coseismic subsidence produced by offshore earthquakes is rapidly recovered during the postseismic and interseismic periods. The long-term period is characterized by slow tectonic uplift of the Jalisco coast. We found no evidence of coastal interseismic and long-term subsidence along the Jalisco coast.     

Zooplankton and the oceanography of the eastern tropical Pacific: A review

We review the spatial and temporal patterns of zooplankton in the eastern tropical Pacific Ocean and relationships with oceanographic factors that affect zooplankton distribution, abundance and trophic relationships. Large-scale spatial patterns of some zooplankton groups show broad coincidence with surface water masses, circulation, and upwelling regions, in agreement with an ecological and dynamic partitioning of the pelagic ecosystem. The papers reviewed and a new compilation of zooplankton volume data at large-scale show that abundance patterns of zooplankton biomass have their highest values in the upwelling regions, including the Gulf of Tehuantepec, the Costa Rica Dome, the equatorial cold tongue, and the coast of Peru.Some of the first studies of zooplankton vertical distribution were done in this region, and a general review of the topic is presented. The possible physiological implications of vertical migration in zooplankton and the main hypotheses are described, with remarks on the importance of the oxygen minimum zone (OMZ) as a barrier to both the vertical distribution and migration of zooplankton in the region. Recent results, using multiple-net gear, show that vertical distribution is more complex than previously thought. There are some well-adapted species that do live and migrate within the OMZ.Temporal patterns are reviewed and summarized with historical data. Seasonal variations in zooplankton biomass follow productivity cycles in upwelling areas. No zooplankton time series exist to resolve ENSO effects in oceanic regions, but some El Niño events have had effects in the Peru Current ecosystem. Multidecadal periods of up to 50 years show a shift from a warm sardine regime with a low zooplankton biomass to a cool anchovy regime in the eastern Pacific with higher zooplankton biomasses. However, zooplankton volume off Peru has remained at low values since the 1972 El Niño, a trend opposite to that of anchoveta biomass since 1984.Studies of trophic relations emphasize the difference in the productivity cycle in the eastern tropical Pacific compared to temperate or polar ecosystems, with no particular peaks in the stocks of either zooplankton or phytoplankton. Productivity is more dependent on local events like coastal upwelling or water circulation, especially in the equatorial countercurrent and around the equatorial cool-tongue. Micrograzers are very important in the tropics as are predatory mesozooplankton. Up to 70% of the daily primary productivity is consumed by microzooplankton, which thus regulates the phytoplankton stocks. Micrograzers are an important link between primary producers, including bacteria, and mesozooplankton, constituting up to 80% of mesozooplankton food. Oceanography affects zooplankton trophic relationships through spatial–temporal effects on primary productivity and on the distributions of metabolic factors, food organisms, and predators. This paper is part of a comprehensive review of the oceanography of the eastern tropical Pacific.     

Formation events of shoreline sand waves on a gravel beach

Kilometric-scale shoreline sand waves (KSSW) have been observed in the north-east flank of the Dungeness Cuspate Foreland (southeastern coast of the UK). They consist of two bumps separated by embayments with a 350–450-m spacing. We have analysed 36 shoreline surveys of 2-km length using the Discrete Fourier Transformation (DFT), from 2005 to 2016, and seven topographic surveys encompassing the intertidal zone, from 2010 to 2016. The data set shows two clear formation events. In order to test the role of high-angle waves on the KSSW formation, the 10-year wave series is propagated from the wave buoy located at 43 m depth up to a location in front of the undulations at 4 m depth using the SWAN wave model. The dominating SW waves arrive with a very high incidence angle (～ 80°) while the NE waves arrive almost shore normal. The ratio R, which measures the degree of dominance of high-angle waves with respect to low-angle waves, correlates well with the shoreline DFT magnitude values of the observed wavelength undulations. In particular, the highest R values coincide with the formation events. Finally, a linear stability model based on the one-line approximation is applied to the Dungeness profile and the 10-year propagated wave series. It predicts accurately the formation moments, with positive growth rates in the correct order of magnitude for wavelengths similar to the observed ones. All these results confirm that the shoreline undulations in Dungeness are self-organized and that the underlying formation mechanism is the high-angle wave instability. The two detected formation events provide a unique opportunity to validate the existing morphodynamic models that include such instability.     

Three-dimensional tomographic inversion of the seismic velocity structure of the crust and upper mantle of northwestern Nicaragua

Journal of Seismology - A three-dimensional tomographic image of the seismic velocity structure in the crust and upper mantle of northwestern Nicaragua was performed using the back-projection...     

High-resolution seismic stratigraphy of the late Neogene of the central sector of the Colombian Pacific continental shelf: A seismic expression of an active continental margin

The sedimentary prism of the central Pacific continental shelf of Colombia was affected by regional folding and faulting, and probably later mud diapirism, from the Late Miocene to the Holocene. Interpretation of high-resolution seismic lines (2 s/dt) revealed that the prism consists of 13 high-resolution seismic units, that can be separated into 5 seismic groups.Deposition of the prism and the associated stacking pattern, are probably the response to variable uplift and subsidence in a fore-arc basin that underwent important tectonic events by the end of the Miocene. Throughout the Pliocene, the continental shelf sedimentation was affected by the growing of a dome structure probable due to mud diapirism. This fact caused peripheral faults both normal and reverse that controlled the distribution of some of the seismic units. During the Late Pleistocene (Wisconsin stage?) a eustatic sea level fall caused the shoreline to advance about 50 km westward of its present position. Because of this eustatic sea level change, a strong fluvial dissection took place and is interpreted as the probable extension of the San Juan River to the south of the present day river mouth. Within this framework it is believed that the Malaga and Buenaventura Bays were the passageways of branches of the old drainage system of the San Juan River. The inner branch circulated through the present Buenaventura Bay and runs southward leaving the mark of an apparent valley identified in the seismic information in the eastern sector of the study area. This old fluvial valley and its filling material located in the present day inner continental shelf front of Buenaventura are postulated as important targets to find placer minerals such as gold and platinum.     

From desert to Mediterranean rangelands: will increasing drought and inter-annual rainfall variability affect herbaceous annual primary productivity?

Climate change is predicted to alter the rainfall regime in the Eastern Mediterranean Basin: total annual rainfall will decrease, while seasonal and inter-annual variation in rainfall will increase. Such changes in the rainfall regime could potentially lead to large-scale changes in aboveground net primary productivity (ANPP) in the region. We conducted a data-driven evaluation of herbaceous ANPP along an entire regional rainfall gradient, from desert (90 mm MAR [Mean Annual Rainfall]) to Mesic-Mediterranean (780 mm MAR) ecosystems, using the largest database ever collated for herbaceous ANPP in Israel, with the aim of predicting consequences of climate change for rangeland productivity. This research revealed that herbaceous ANPP increases with increasing rainfall along the gradient, but strong dependence on rainfall was only apparent within dry sites. Rain Use Efficiency peaks at mid-gradient in Mediterranean sites without woody vegetation (560 and 610 mm MAR). Inter-annual coefficients of variation in rainfall and herbaceous ANPP decrease along the rainfall gradient up to ca. 500 mm MAR. Climate change is more likely to affect herbaceous ANPP of rangelands in the arid end of the rainfall gradient, requiring adaptation of rangeland management, while ANPP of rangelands in more mesic ecosystems is less responsive to variation in rainfall. We conclude that herbaceous ANPP in most Mediterranean rangelands is less vulnerable to climate change than generally predicted.