Paleozoic tectonics of the southern Chinese Tianshan: Insights from structural,chronological and geochemical studies of the Heiyingshan ophiolitic mélange (NW China)

In the southern Chinese Tianshan, the southernmost part of the Central Asian Orogenic Belt (CAOB), widespread ophiolitic mélanges form distinct tectonic units that are crucial for understanding the formation of the CAOB. However, the timing of tectonic events and the subduction polarity are still in controversy. In order to better understand these geological problems, a comprehensive study was conducted on the Heiyingshan ophiolitic mélange in the SW Chinese Tianshan. Detailed structural analysis reveals that the ophiolitic mélange is tectonically underlain by sheared and weakly metamorphosed pre-Middle Devonian rocks, and unconformably overlain by non-metamorphic and undeformed lower Carboniferous (Serpukhovian) to Permian strata. The igneous assemblage of the mélange comprises OIB-like alkali basalt and andesite, N-MORB-like tholeiitic basalt, sheeted diabase dikes, cumulate gabbro and peridotite. Mafic rocks display supra-subduction signatures, and some bear evidence of contamination with the continental crust, suggesting a continental marginal (back-arc) basin setting. Zircons of a gabbro were dated at 392 ± 5 Ma by the U–Pb LA-ICP-MS method. Famennian–Visean radiolarian microfossils were found in the siliceous matrix of the ophiolitic mélange. Mylonitic phyllite which displays northward-directed kinematic evidence yielded muscovite ⁴⁰Ar/³⁹Ar plateau ages of 359 ± 2 Ma and 356 ± 2 Ma.These new data, combined with previously published results, suggest that the mafic protoliths originally formed in a back-arc basin in the Chinese southern Tianshan during the late Silurian to Middle Devonian and were subsequently incorporated into the ophiolitic mélange and thrust northward during the Late Devonian to early Carboniferous. Opening of the back-arc basin was probably induced by south-dipping subduction of the Paleo-Tianshan Ocean in the early Paleozoic, and the Central Tianshan block was rifted away from the Tarim block. Closure of the back-arc basin in the early Carboniferous formed the South Tianshan Suture Zone and re-amalgamated the two blocks.     

Mineralogical evidence for a local volcanic origin of the parent material of Bermuda Quaternary paleosols

The alternation of carbonate deposits and paleosols compose the emerged part of the Bermuda archipelago. The pedological units present a complex and diversified mineralogy. Former studies demonstrated that the paleosols are not primarily a product of the unique dissolution of the surrounding carbonates, but contain a massive input of allochthonous non-carbonate detrital material. Researchers during more than the past three decades have attributed this flux of insoluble residues (IR) to Saharan dusts. We carried out systematic field and mineralogical analyses on the Quaternary paleosols from the Bermuda archipelago. Their mineralogical assemblage predominantly includes carbonates, clay minerals (kaolinite, chlorite and chlorite/vermiculite), phosphates, and aluminium and iron oxides/hydroxides. This assemblage is strikingly close to the mineralogy of the weathered volcanic substrate of Bermuda, but noticeably different from the mineralogy of Saharan dust. Moreover, we found volcanic lithoclasts in numerous paleosol profiles all over the archipelago and in all the recorded time intervals. We thus consider the volcanic seamount underlying Bermuda as the main source of non-carbonate minerals detected in the paleosols. This hypothesis further resolves the anomalous maturity of Bermudan paleosols compared to their southern counterparts in the Bahamas and Barbados.     

Continuity for Kriging with Moving Neighborhood

By definition, kriging with a moving neighborhood consists in kriging each target point from a subset of data that varies with the target. When the target moves, data that were within the neighborhood are suddenly removed from the neighborhood. There is generally no screen effect, and the weight of such data goes suddenly from a non-zero value to a value of zero. This results in a discontinuity of the kriging map. Here a method to avoid such a discontinuity is proposed. It is based on the penalization of the outermost data points of the neighborhood, and amounts to considering that these points values are spoiled with a random error having a variance that increases infinitely when they are about to leave the neighborhood. Additional details are given regarding how the method is to be carried out, and properties are described. The method is illustrated by simple examples. While it appears to be similar to continuous kriging with a smoothing kernel, it is in fact based on a much simpler formalism.     

Gallium behaviour in some contrasting lateritic profiles from Cameroon and Brazil

In the supergene environment under tropical climates, the behaviour of gallium depends on the physico-chemical conditions which control the evolution stages of the residual mantle and this element is not necessarily linked to aluminum, as was formerly believed. Ga vs. Al correlation is positive in weathering profiles from West Cameroon developed on granodiorite, basalt and trachyte, which essentially result from the leaching of alkalis, alkali-earths and silicon. However, in the upper part of the profile on trachyte, which underwent later aluminization, no significant Ga vs. Al correlation was evidenced. In lateritic and bauxitic profiles from Eastern Brazilian Amazonia developed on basalt and siliciclastic sedimentary rocks, the dissociation between gallium and aluminum is clearly expressed by a negative or lack of Ga vs. Al correlation in the bauxitic horizons, resulting mainly from intense aluminization, as well as in the ferruginous horizons. In turn, Ga vs. Fe correlation is markedly positive in both cases. Thus, when dissolution of early formed Ga-containing gibbsite and kaolinite occurs, aluminum migrates and concentrates in well differentiated zones while gallium tends to be leached out of the profile or is retained by Fe-oxyhydroxides.     

Reconstructing Phreatic Palaeogroundwater Levels in a Geoarchaeological Context: A Case Study in Flanders,Belgium

The complex debate on prehistoric settlement decisions is no longer tackled from a purely archaeological perspective but from a more landscape‐oriented manner combined with archaeological evidence. Therefore, reconstruction of several components of the former landscape is needed. Here, we focus on the reconstruction of the groundwater table based on modeling. The depth of the phreatic aquifer influences, for example, soil formation processes and vegetation type. Furthermore, it directly influences settlement by the wetness of a site. Palaeogroundwater modeling of the phreatic aquifer was carried out to produce a series of full‐coverage maps of the mean water table depth between 12.7 ka and the middle of the 20th century (1953) in Flanders, Belgium. The research focuses on the reconstruction of the input data and boundary conditions of the model and the model calibration. The model was calibrated for the 1924–1953 time period using drainage class maps. Archaeological site data and podzol occurrence data act as proxies for local drainage conditions over periods in the past. They also served as a control on the simulated phreatic palaeogroundwater levels. Model quality testing on an independent validation data set showed that the model predicts phreatic water table levels at the time of soil mapping well (mean error of 1.8 cm; root mean square error of 65.6 cm). Simulated hydrological conditions were in agreement with the occurrence of archaeological sites of Mesolithic to Roman age at 96% of the validation locations, and also with the occurrence of well‐drained podzols at 97% of the validation locations.     

Biogéographie des ammonites jurassiques et reconstitution palinspastique de la Téthys

Résumé

— La distribution géographique des ammonites jurassiques est régie par deux causes fondamentales : l’écologie et l’histoire évolutive (événements vicariants). L’analyse conjointe de ces deux facteurs permet de reconnaître : d’une part des taxons dont la distribution est essentiellement contrôlée par des contraintes écologiques (Phylloce-ratinae et Lytoceratinae, liés à des environnements océaniques profonds; Clydoniceratidae et Proplanulitinae liés à des plates-formes assez superficielles); d’autre part des taxons dont l’histoire évolutive est associée à des événements vicariants (Ammonitina liasiques euro-boréales et Cardioceratidae-Kosmoceratidae boréaux du Jurassique moyen).

Les exemples développés ici permettent d’analyser en terme de paléobiogéographie la position de l’Europe centro-méridionale (Bulgarie, Hongrie, Roumanie) incluse au Jurassique dans la bordure nord-téthy-sienne. Il est montré que Phylloceratinae et Lytoceratinae sont très abondants dans les régions supposées profondes à cette époque (sphéno-chasme des monts d’Apuseni, sillon Dobrogeo-Caucasien), alors qu’elles sont très rares sur la plate-forme moësienne. La même remarque est valable pour les plates-formes moyennes-orientales de la marge sud (Israël, Arabie Saoudite).

Lorsque l’on tente d’établir des reconstructions palinspastiques basées sur la paléobiogéographie, on constate que les taxons qui ont une histoire évolutive originale fournissent de meilleures informations paléogéographiques que les formes ubiquistes ou celles à préférences écologiques accusées. Les données brutes de répartition des faunes d’ammonites ne sont donc pas des arguments absolus pour corroborer les reconstructions. Les analyses fauniques, conduites avec une approche qualitative et quantitative, doivent tenir compte de données extra-biologiques telles que la distribution des faciès et des unités structurales; enfin, le niveau d’intervention — local, régional, global — conditionne fortement les possibilités d’interprétation des résultats.     

Mesozoic paleostress evolution in the Saharian platform (southern Tunisia)

Abstract

A detailed analysis of brittle deformations in the Saharian platform of southern Tunisia is based on studies of fault-slip data sets and joint sets. It allows reconstruction of the Mesozoic paleostress evolution. During the Permo-Triassic, N-S extensions occurred with high late Permian subsidence rates. During the Norian, strike-slip movements reactivated former normal faults. During the Jurassic and the Cretaceous a succession of extensional events was characterized by : (1) a N-S extension which dominated from late Triassic to early Aptian. We relate this extension to the Africa-Eurasia divergence; (2) a ENE-WSW extension during the Cenomanian. We relate this extension to the opening of «he African basins ; (3) a NE-SW Senonian extension that continued during the Cenozoic in the Jeffara and in the Gabes Gulf, during the further evolution of the northern African margin. The various compressional trends recorded in the platform are attributed to Cenozoic events.     

The intensification of the East Asian winter monsoon contributed to the disappearance of Cedrus (Pinaceae) in southwestern China

Climate change during the Quaternary played an important role in the distribution of extant plants. Herein, cone scales of Cedrus (Pinaceae) were uncovered from the Upper Pliocene Sanying Formation, Longmen Village, Yongping County of Yunnan Province in southwestern China. Detailed comparisons show that these fossils all belong to the genus Cedrus (Pinaceae), and a new species is proposed, Cedrus angusta sp. nov. This find expands the known distribution of Cedrus during the Late Pliocene to Yunnan, where the genus no longer exists in natural forests. Based on the analysis of reconstructed Neogene climate data, we suggest that the intensification of the East Asian winter monsoon during the Quaternary may have dramatically increased seasonality and given rise to a much drier winter in Yunnan. Combined with information on Cedrus fossil records and its seed physiology, we conclude that the intensification of a drier climate after the Late Pliocene may have prevented the survival of Cedrus seedlings, leading to the eventual disappearance of Cedrus in western Yunnan. This study indicates that the topography in southwestern China acted as a vital refuge for many plants during the Quaternary, but that other species gradually disappeared due to the intensification of the monsoonal climate.     

Armouring of well cement in H2S–CO2 saturated brine by calcite coating – Experiments and numerical modelling

The active acid gas (H₂S–CO₂ mixture) injection operations in North America provide practical experience for the operators in charge of industrial scale CO₂ geological storage sites. Potential leakage via wells and their environmental impacts make well construction durability an issue for efficiency/safety of gas geological storage. In such operations, the well cement is in contact with reservoir brines and the injected gas, meaning that gas–water–solid chemical reactions may change the physical properties of the cement and its ability to confine the gas downhole. The cement-forming Calcium silicate hydrates carbonation (by CO₂) and ferrite sulfidation (by H₂S) reactions are expected. The main objective of this study is to determine their consequences on cement mineralogy and transfer ability. Fifteen and 60 days duration batch experiments were performed in which well cement bars were immersed in brine itself caped by a H₂S–CO₂ phase at 500 bar–120 °C. Scanning electron microscopy including observations/analyses and elemental mapping, mineralogical mapping by micro-Raman spectroscopy, X-ray diffraction and water porosimetry were used to characterize the aged cement. Speciation by micro-Raman spectroscopy of brine trapped within synthetic fluid inclusions were also performed. The expected calcium silicate hydrates carbonation and ferrite sulfidation reactions were evidenced. Furthermore, armouring of the cement through the fast creation of a non-porous calcite coating, global porosity decrease of the cement (clogging) and mineral assemblage conservation were demonstrated. The low W/R ratio of the experimental system (allowing the cement to buffer the interstitial and external solution pH at basic values) and mixed species diffusion and chemical reactions are proposed to explain these features. This interpretation is confirmed by reactive transport modelling performed with the HYTEC code. The observed cement armouring, clogging and mineral assemblage conservation suggest that the tested cement has improved transfer properties in the experimental conditions. This work suggests that in both acid gas and CO₂ geological storage, clogging of cement or at least mineral assemblage conservation and slowing of carbonation progress could occur in near-well zones where slight water flow occurs e.g. in the vicinity of caprock shales.     

The Paleoenvironment and Lithic Taphonomy of Shi’Bat Dihya 1, a Middle Paleolithic Site in Wadi Surdud,Yemen

The Shi'bat Dihya 1 site in western Yemen, dated by optically stimulated luminescence to 55 ka, provides insight into the Middle Paleolithic peopling of the Arabian Peninsula. The archaeological layer is interstratified within thick, sandy silt floodplain deposits filling a piedmont basin. Luminescence dates, lack of soil development, and gypsum precipitation indicate a high accretion rate of the floodplain during Marine Isotope Stage 3, in connection with a (semi)‐arid environment. Rapid overbank sedimentation was likely a result of the remobilization of loess material deposited on the Yemeni Great Escarpment at the periphery of the adjacent Tihama coastal sand desert or of other sources. Fabric and size analyses of the lithic artifacts, together with spatial projections, indicate site modifications by floods. Primary modifications include (1) selective accumulation of medium‐sized lithic pieces as a result of hydraulic sorting, (2) bimodal orientation of artifacts, and (3) ripple‐like arrangement of lithics and bone/tooth fragments. The overrepresentation of teeth may also be a consequence of sorting. Although floods have distorted the original site patterning, long‐distance transport of artifacts by water can be excluded, as indicated by relatively high refitting rate, close proximity of artifacts derived from the same block of raw material, and lack of abrasion of the pieces. Therefore, the site is considered “geologically” in situ because its remobilization by water occurred shortly after human abandonment. This study also stresses that the effective preservation of a site cannot be assessed without careful taphonomic study, even in a potentially favorable depositional context such as silty alluvium.