A METHOD OF EXTRACTION AND ANALYSIS OF POSSIBLE COSMIC PARTICLES FROM MANGANESE NODULES

A method is described for extracting magnetic micron-size particles from manganese nodules, and for studying the selected particles by light microscopy, scanning electron microscopy, electron microprobe and X-ray diffraction.     

Mesoarchean sanukitoid rocks of the Rio Maria Granite-Greenstone Terrane,Amazonian craton,Brazil

The Archean sanukitoid Rio Maria Granodiorite yielded zircon ages of ～2.87 Ga and is exposed in large domains of the Rio Maria Granite-Greenstone Terrane, southeastern Amazonian craton. It is intrusive in the greenstone belts of the Andorinhas Supergroup, in the Arco Verde Tonalite and Caracol Tonalitic Complex (older TTGs). Archean potassic leucogranites, younger TTGs and the Paleoproterozoic granites of Jamon Suite are intrusive in the Rio Maria Granodiorite.The more abundant rocks of the Rio Maria Granodiorite have granodioritic composition and display medium to coarse even-grained textures. These rocks show generally a gray color with greenish shades due to strongly saussuritized plagioclase, and weak WNW-ESE striking foliation. The significant geochemical contrasts between the occurrences of Rio Maria Granodiorite in different areas suggest that this unit corresponds in fact to a granodioritic suite of rocks derived from similar but distinct magmas. Mingling processes involving the Rio Maria Granodiorite and similar mafic to intermediate magmas are able to explain the constant occurrence of mafic enclaves in the granodiorite.The associated intermediate rocks occur mainly near Bannach, where mostly quartz diorite and quartz monzodiorite are exposed. The dominant rocks are mesocratic, dark-green rocks, with fine to coarse even-grained texture. The Rio Maria Granodiorite and associated intermediate rocks show similar textural and mineralogical aspects. They follow the calc-alkaline series trend in some diagrams. However, they have high-Mg#, Cr, and Ni conjugate with high contents of large ion lithophile elements (LILEs), typical of sanukitoids series. The patterns of rare earth elements of different rocks are similar, with pronounced enrichment in light rare earth elements (LREEs) and strong to moderate fractionation of heavy rare earth elements (HREEs).Field aspects and petrographic and geochemical characteristics denote that the granodiorites and intermediate rocks have sanukitoid affinity. However, geochemical data suggest that the intermediate rocks and the granodiorites are not related by a fractional crystallization process. It is concluded that the intermediate rocks derived from similar sources to the granodiorites, but probably result from a higher degree of melting, being both cogenetic, but not comagmatic rocks.Mineralogical aspects associated with experimental evidence suggest that the Rio Maria Granodiorite magma was relatively water-enriched (>4 wt.%), explaining the presence of hornblende at the liquidus and the absence of clinopyroxene and orthopyroxene in the studied rocks. The occurrence of well-preserved magmatic epidote crystals, admitting that the Rio Maria Granodiorite was emplaced at shallow crustal levels, points to a rapid ascent of the Rio Maria Granodiorite magma.     

Les récoltes peuvent‐elles faire office de grêlimètres?

Résumé

Cet article étudie la possibilité d^‘employer les récoltes comme grêlimètres. Après avoir discuté les caractéristiques essentielles d'un grêlimètre idéal, l'auteur discute le dommage aux récoltes comme mesure de l'énergie cinétique de la chute de grêle et les facteurs indépendants de la chute de grêle qui, cependant, contribuent fortement aux dommages. Une solution aux problèmes présentés par ces facteurs est suggérée.     

Topographic eddies in temporally varying oceanic flows

Abstract

In this paper we examine the behaviour of oceanic unsteady flow impinging on isolated topography by means of numerical simulation. The ocean model is quasigeostrophic and forced by an oscillatory mean flow. The fluid domain is of the channel type and open-boundary numerical conditions are used to represent downstream and upstream flow.

In certain cases, vortex shedding, either cyclonic or anticyclonic, is observed in the lee of obstacles. Such shedding can be explained as the consequence of both an enhanced process of vorticity dissipation over the topography which locally affects the balance of potential vorticity on the advective timescale, and a periodic dominance of advective effects which sweep the fluid particles trapped on the seamount. For refined resolution and smallest viscosity the model will predict flows in which the shed eddies are coherent structures with closed streamlines.

The model suggests a mechanism by which topographically generated eddies may be swept away from a seamount in the ocean.     

Three‐dimensional non‐geostrophic disturbances in a baroclinic zonal flow

Abstract

A study is made to determine the stability properties of a baroclinic zonal current on which small amplitude three‐dimensional non‐geostrophic disturbances are superimposed. The flow is assumed to be bounded to the north and south by rigid vertical walls and the Rossby number Ro is taken to be small compared to unity. It is then shown that if the perturbation quantities are expanded in power series in Ro the leading or zero order terms in the series correspond to the quasi‐geostrophic solution obtained by Eady (1949) and that the higher order terms represent the “non‐geostrophic” effects neglected by the latter.

It is shown that to the second order in Ro the non‐geostrophic effects decrease the growth rates of those disturbances which are found to be unstable according to Eady's analysis but do not alter their speed of propagation. The results indicate, on the other hand, that to the same order of approximation the stable waves travel at a speed which is different from that given by Eady's solution. The modification of the perturbation wave structure by the non‐geostrophic effects is also investigated. It is found in particular that to the first order in Ro the latter produce a northward tilt with height in the ridge (or trough) lines of the meridional and vertical particle velocity fields away from the lateral boundaries.     

Surface properties, solubility and dissolution kinetics of bamboo phytoliths

Although phytoliths, constituted mainly by micrometric opal, exhibit an important control on silicon cycle in superficial continental environments, their thermodynamic properties and reactivity in aqueous solution are still poorly known. In this work, we determined the solubility and dissolution rates of bamboo phytoliths collected in the Réunion Island and characterized their surface properties via electrophoretic measurements and potentiometric titrations in a wide range of pH. The solubility product of “soil” phytoliths ( at 25 °C) is equal to that of vitreous silica and is 17 times higher than that of quartz. Similarly, the enthalpy of phytoliths dissolution reaction is close to that of amorphous silica but is significantly lower than the enthalpy of quartz dissolution. Electrophoretic measurements yield isoelectric point pH_IEP = 1.2 ± 0.1 and 2.5 ± 0.2 for “soil” (native) and “heated” (450 °C heating to remove organic matter) phytoliths, respectively. Surface acid-base titrations allowed generation of a 2-pK surface complexation model. Phytoliths dissolution rates, measured in mixed-flow reactors at far from equilibrium conditions at 2 ? pH ? 12, were found to be intermediate between those of quartz and vitreous silica. The dissolution rate dependence on pH was modeled within the concept of surface coordination theory using the equation:

     

Ni-Co sulphide segregation in the Mamb pyroxenite intrusion, Cameroon

The amphibole metapyroxenite intrusion from Mamb (Cameroon) consists of enstatite, diopside-augite, edenite, and traces of plagioclase, biotite and rutile. It contains notable amounts of sulphides (pyrrhotite, pentlandite, chalcopyrite, pyrite and Co-rich violarite). The sulphide phase segregated during magma crystallization as immiscible droplets (≤ 1 mm) included in growing ferromagnesian minerals or aggregated in the silicate crystal mush to form an interstitial phase. However, observed sulphide assemblages are likely to result from low-T (≤ 300 °C) re-equilibration of high-T monosulphide solid solutions, more particularly during the Pan-African metamorphic event. The Mamb amphibole pyroxenite intrusion is tentatively considered as a potential source for Ni and Co mineralization.     

Fluxes of high- versus low-temperature water-rock interactions in aerial volcanic areas: Example from the Kamchatka Peninsula, Russia

Volcanic areas play a key role in the input of elements into the ocean and in the regulation of the geological carbon cycle. The aim of this study is to investigate the budget of silicate weathering in an active volcanic area. We compared the fluxes of the two major weathering regimes occurring at low temperature in soils and at high temperature in the active volcanic arc of Kamchatka, respectively. The volcanic activity, by inducing geothermal circulation and releasing gases to the surface, produces extreme conditions in which intense water-rock interactions occur and may have a strong impact on the weathering budgets. Our results show that the chemical composition of the Kamchatka river water is controlled by surface low-temperature weathering, atmospheric input and, in some limited cases, strongly imprinted by high-temperature water-rock reactions. We have determined the contribution of each source and calculated the rates of CO₂ consumption and chemical weathering resulting from low and high-temperature water/rock interactions. The weathering rates (between 7 and 13.7 t/km²/yr for cations only) and atmospheric CO₂ consumption rates (∼0.33-0.46 × 10⁶ mol/km²/yr for Kamchatka River) due to rock weathering in soils (low-temperature) are entirely consistent with the previously published global weathering laws relating weathering rates of basalts with runoff and temperature. In the Kamchatka River, CO₂ consumption derived from hydrothermal activity represents about 11% of the total HCO₃ flux exported by the river. The high-temperature weathering process explains 25% of the total cationic weathering rate in the Kamchatka River. Although in the rivers non-affected by hydrothermal activity, the main weathering agent is carbonic acid (reflected in the abundance of in rivers), in the region most impacted by hydrothermalism, the protons responsible for minerals dissolution are provided not only by carbonic acid, but also by sulphuric and hydrochloric acid. A clear increase of weathering rates in rivers impacted by sulphuric acid can be observed. In the Kamchatka River, 19% of cations are released by hydrothermal acids or the oxidative weathering of sulphur minerals.Our results emphasise the important impact of both low and high-temperature weathering of volcanic rocks on global weathering fluxes to the ocean. Our results also show that besides carbonic acid derived from atmospheric CO₂, hydrochloric acid and especially sulphuric acid are important weathering agents. Clearly, sulphuric acid, with hydrothermal activity, are key parameters that cause first-order increases of the chemical weathering rates in volcanic areas. In these areas, accurate determination of weathering budgets in volcanic area will require to better quantify sulphuric acid impact.     

Averaging on the motion of a fast revolving body. Application to the stability study of a planetary system

Exploring the global dynamics of a planetary system involves computing integrations for an entire subset of its parameter space. This becomes time-consuming in presence of a planet close to the central star, and in practice this planet will be very often omitted. We derive for this problem an averaged Hamiltonian and the associated equations of motion that allow us to include the average interaction of the fast planet. We demonstrate the application of these equations in the case of the μ Arae system where the ratio of the two fastest periods exceeds 30. In this case, the effect of the inner planet is limited because the planet’s mass is one order of magnitude below the other planetary masses. When the inner planet is massive, considering its averaged interaction with the rest of the system becomes even more crucial.