Combined thermodynamic and rare earth element modelling of garnet growth during subduction: Examples from ultrahigh-pressure eclogite of the Western Gneiss Region, Norway

Major and trace element zonation patterns were determined in ultrahigh-pressure eclogite garnets from the Western Gneiss Region (Norway). All investigated garnets show multiple growth zones and preserve complex growth zonation patterns with respect to both major and rare earth elements (REE). Due to chemical differences of the host rocks two types of major element compositional zonation patterns occur: (1) abrupt, step-like compositional changes corresponding with the growth zones and (2) compositionally homogeneous interiors, independent of growth zones, followed by abrupt chemical changes towards the rims. Despite differences in major element zonation, the REE patterns are almost identical in all garnets and can be divided into four distinct zones with characteristic patterns.In order to interpret the major and trace element distribution and zoning patterns in terms of the subduction history of the rocks, we combined thermodynamic forward models for appropriate bulk rock compositions to yield molar proportions and major element compositions of stable phases along the inferred pressure-temperature path with a mass balance distribution of REEs among the calculated stable phases during high pressure metamorphism. Our thermodynamic forward models reproduce the complex major element zonation patterns and growth zones in the natural garnets, with garnet growth predicted during four different reaction stages: (1) chlorite breakdown, (2) epidote breakdown, (3) amphibole breakdown and (4) reduction in molar clinopyroxene at ultrahigh-pressure conditions.Mass-balance of the rare earth element distribution among the modelled stable phases yielded characteristic zonation patterns in garnet that closely resemble those in the natural samples. Garnet growth and trace element incorporation occurred in near thermodynamic equilibrium with matrix phases during subduction. The rare earth element patterns in garnet exhibit distinct enrichment zones that fingerprint the minerals involved in the garnet-forming reactions as well as local peaks that can be explained by fractionation effects and changes in the mineral assemblage.     

Local and remote response of the North Sea dynamics to morphodynamic changes in the Wadden Sea

The response of the tidal system in the southern North Sea to morphodynamic changes was investigated in a modelling study using fine resolution bathymetric observations available for 1982–2011. The Semi-implicit Cross-scale Hydroscience Integrated System Model (SCHISM) was set up for the different sets of bathymetries. One set of bathymetry was compiled from a large number of bathymetric measurements over many years, while the other two reflected bathymetry state in the area of Wadden Sea during 2000 and 2011, respectively. The temporal and spatial evolution of bathymetry was dominated by migration of tidal channels. The M4 tide showed larger sensitivity to bathymetric change in the Wadden Sea than the M2 tide, whereas the structure of the latter remained rather robust. The largest change of the tidal wave due to the differences in bathymetries was located off the North Frisian Wadden Sea. Traces of changes were also found far away from the regions of their origin because the tidal waves in the North Sea propagate the local disturbances basin-wide. This illustrated an efficient physical mechanism of teleconnectivity, i.e. effecting the local responses to the larger-scale or remote change of ocean bottom caused by erosion and deposition. The tidal distortion resulting from the relatively small bathymetric changes was substantial, particularly in the coastal zone. This is a manifestation of the nonlinear tidal transformation in shallow oceans and is crucial for the sediment transport and the morphodynamic feedback, because of the altered tidal asymmetry.     

Patterns of surface downwearing on shore platforms in eastern Canada

Downwearing rates were measured on shore platforms at about 200 transverse micro‐erosion meter (TMEM) stations, over periods ranging from 2 to 6 years. There were seven study areas in eastern Canada. The platforms were surveyed and a Schmidt Rock Test Hammer was used to measure rock hardness. More than 1200 rock samples from three of the study areas were also subjected each day, over a 3 year period, to two tidal cycles of immersion and exposure, which simulated the central intertidal zone. A further 840 samples were subjected to longer periods of exposure and immersion, over a 1 year period, which represented different elevations within the upper and lower intertidal zone, respectively. These experiments suggested that tidally generated weathering and debris removal is an effective erosional mechanism, particularly at the elevation of the lowest high tides. In the field, mean rates of downwearing for each study area ranged from 0·24 mm yr^?1 to more than 1·5 mm yr^?1. Rates tended to increase with elevation in the field, with maxima in the upper intertidal zone. This trend in the field cannot be attributed entirely to the tidally induced weathering processes that were simulated in the laboratory, and must reflect, in part, the effect of waves, frost, ice, and other mechanisms. It is concluded that there are no strong spatial downwearing patterns on shore platforms, and that downwearing rates in the intertidal zone are the result of a number of erosional mechanisms with different elevation‐efficacy characteristics. Furthermore, even if only one or two mechanisms were dominant in an area, any resulting relationship between downwearing rates and elevation would be obscured or eliminated by the effect of variations in the chemical and physical characteristics of the rocks. Copyright © 2010 John Wiley & Sons, Ltd.     

Debris entrainment by basal freeze‐on and thrusting during the 1995–1998 surge of Kuannersuit Glacier on Disko Island,west Greenland

Kuannersuit Glacier, a valley glacier on Disko Island in west Greenland, experienced a major surge from 1995 to 1998 where the glacier advanced 10·5 km and produced a ～65 m thick stacked sequence of debris‐rich basal ice and meteoric glacier ice. The aim of this study is to describe the tectonic evolution of large englacial thrusts and the processes of basal ice formation using a multiproxy approach including structural glaciology, stable isotope composition (δ¹⁸O and δD), sedimentology and ground‐penetrating radar. We argue that the major debris layers that can be traced in the terminal zone represent englacial thrusts that were formed early during the surge. Thrust overthrow was at least 200–300 m and this lead to a 30 m thick repetition of basal ice at the ice margin. It is assumed that the englacial thrusting was initiated at the transition between warm ice from the interior and the cold snout. The basal debris‐rich ice was mainly formed after the thrusting phase. Two sub‐facies of stratified basal ice have been identified; a lower massive ice facies (S_M) composed of frozen diamict enriched with heavy stable isotopes overlain by laminated ice facies (S_L) consisting of millimetre thick lamina of alternating debris‐poor and debris‐rich ice. We interpret the stratified basal ice as a continuum formed mainly by freeze‐on processes and localized regelation. First laminated basal ice is formed and as meltwater is depleted more sediment is entrained and finally the glacier freezes to the base and massive diamict is frozen‐on. The increased ability to entrain sediments may partly be associated with higher basal freezing rates enhanced by loss of frictional heat from cessation of fast flow and conductive cooling through a thin heavily crevassed ice during the final phase of the glacier surge. The dispersed basal ice facies (D) was mainly formed by secondary processes where fine‐grained sediment is mobilized in the vein system of ice. Our results have important implications for understanding the significance of basal ice formation and englacial thrusting beneath fast‐flowing glaciers and it provides new information about the development of landforms during a glacier surge. Copyright © 2010 John Wiley & Sons, Ltd.     

The solubility of platinum and gold in NaCl brines at 1.5 kbar, 600 to 800°C: A laser ablation ICP-MS pilot study of synthetic fluid inclusions

The concentration and distribution of Pt and Au in a fluid-melt system has been investigated by reacting the metals with S-free, single-phase aqueous brines (20, 50, 70 wt% eq. NaCl) ± peraluminous melt at a confining pressure of 1.5 kbar and temperatures of 600 to 800 °C, trapping the fluid in synthetic fluid inclusions (quartz-hosted) and vesicles (silicate melt-hosted), and quantifying the metal content of the trapped fluid and glass by laser ablation ICP-MS. HCl concentration was buffered using the assemblage albite-andalusite-quartz and fO₂ was buffered using the assemblage Ni-NiO. Over the range of experimental conditions, measured concentrations of Pt and Au in the brines (, ) are on on the order of 1-10³ ppm. Concentrations of Pt and Au in the melt (, ) are ∼35-100 ppb and ∼400-1200 ppb, respectively. Nernst partition coefficients (, ) are on the order of 10²-10³ and vary as a function of (non-Henry’s Law behavior). Trapped fluids show a significant range of metal concentrations within populations of inclusions from single experiments (∼ 1 log unit variability for Au; ∼2-3 log unit variability for Pt). Variability in metal concentration within single inclusion groups is attributed to premature brine entrapment (prior to metal-fluid-melt equilibrium being reached); this allows us to make only minimum estimates of metal solubility using metal concentrations from primary inclusions. The data show two trends: (i) maximum and average values of and in inclusions decrease ∼2 orders of magnitude as fluid salinity () increases from ∼4 to 40 molal (20 to 70 wt % eq. NaCl) at a constant temperature; (ii) maximum and average values of increase approximately 1 order of magnitude for every 100°C increase temperature at a fixed . The observed behavior may be described by the general expression:

     

Environmental isotope study on hydrodynamics of Lake Naini,Uttar Pradesh,India

Environmental isotopes (δ¹⁸O, δD and ³H) were used to understand the hydrodynamics of Lake Naini in the State of Uttar Pradesh, India. The data was correlated with the in situ physico‐chemical parameters, namely temperature, electrical conductivity and dissolved oxygen. The analysis of the data shows that Lake Naini is a warm monomictic lake [i.e. in a year, the lake is stratified during the summer months (March/April to October/November) and well mixed during the remaining months]. The presence of a centrally submerged ridge inhibits the mixing of deeper waters of the lake's two sub‐basins, and they exhibit differential behaviour. The rates of change of isotopic composition of hypolimnion and epilimnion waters of the lake indicate that the water retention time of the lake is very short, and the two have independent inflow components. A few groundwater inflow points to the lake are inferred along the existing fractures, fault planes and dykes. In addition to poor vertical mixing of the lake due to the temperature‐induced seasonal stratification, the lake also shows poor horizontal mixing at certain locations of the lake. The lake–groundwater system appears to be a flow‐through type. Also, a tritium and water‐balance model was developed to estimate the water retention time of well‐mixed and hydrologically steady state lakes. The model assumes a piston flow of groundwater contributing to the lake. The developed model was verified for (a) Finger Lakes, New York; (b) Lake Neusiedlersee, Austria; and (c) Blue Lake, Australia based on literature data. The predicted water retention times of the lakes were close to those reported or calculated from the hydrological parameters given in the references. On application of this model to Lake Naini, a water retention time of ～2 years and age of groundwater contributing to the lake ～14 years is obtained. Copyright © 2001 John Wiley & Sons, Ltd.     

The spatial organization of services in new land settlement: experiences and trends

Conclusion Despite its uniqueness, the vitality inherent in the rural structure of Israel is of particular interest to other developing regions with a predominant rural-agricultural population. Latin American countries, for example, are investing considerable resources in the development of new lands through construction of penetration roads and other infrastructure. Several countries have created regional development authorities; some have policies designed to attract private investments into virgin areas.¹³⁾ The general emphasis tends increasingly toward state-initiated and planned settlement, often in conjuction with agrarian reform programs — an approach dictated both by economic efficiency and welfare criteria.Past experience has shown that the rural population has to be organized in viable communities in order to become amenable to economic and cultural integration. Communities must likewise be spatially organized in an optimal way that will make it possible to provide them with amenities and so direct their production for the purpose of achieving economic status. At the same time, maximum flexibility must be preserved to fit varying developmental stages, since physical plans once carried into effect are extremely difficult to modify.In order to reduce the social and economic pull of existing urban centers it may be advisable to develop new settlement areas as self-sufficient enclaves, independent to some extent from the facilities existing in the region. The settlements would share the national infrastructure of communications and public services, but would gear their production to regional as well as extra-regional demand, bypassing the traditional local market place. Then, as the new communities consolidate as social and economic entities, the options for collaboration or competition with existing central places can be laid open on a more equitable basis.Admittedly such sheltered development may affect the role of the local intermediary and lessen the commercial activities of the urban sector, but it would also stimulate the development of an independent framework of handling, marketing, and an increasing degree of processing the settlements' produce. These complementary activities would help to retain part of the added value of the production and generate new sources of employment for successive village generations. The delay in the growth for the region's total output may well be worthwhile for achieving that social and economic transformation which in turn may lead to a more balance and sustained development of the entire region.¹⁴⁾