A comparison of observed and thermodynamically predicted phase equilibria and mineral compositions in mafic granulites

Recently published activity–composition (a–x) relations for minerals in upper amphibolite‐ and granulite facies intermediate and basic rocks have expanded our ability to interpret the petrological evolution of these important components of the lower continental crust. If such petrological modelling is to be reliable, the abundances and compositions of phases calculated at the interpreted conditions of metamorphic equilibration should resemble those in the sample under study. Here, petrological modelling was applied to six granulite facies rocks that formed in different tectonic environments and reached different peak metamorphic pressure–temperature (P–T) conditions. While phase assemblages matching those observed in each sample can generally be calculated at P–T conditions that approximate those of peak metamorphism, a consistent discrepancy was found between the calculated and observed compositions of amphibole and clinopyroxene. In amphibole, Si, Ca and A‐site K are underestimated by the model, while Al and A‐site Na are overestimated; comparatively, in clinopyroxene, Mg and Si are generally underestimated, while Fe²⁺ and Al are typically overestimated, compared to observed values. One consequence is a reversal in the Fe–Mg distribution coefficient (K_D) between amphibole and clinopyroxene compared to observations. Some of these mismatches are attributed to the incorrect partitioning of elements between the predicted amphibole and clinopyroxene compositions; however, other discrepancies are the result of the incorrect prediction of major substitution vectors in amphibole and clinopyroxene. These compositional irregularities affect mineral modal abundance estimates and in turn the position and size (in P–T space) of mineral assemblage fields, the effect becoming progressively more marked as the modal abundance of hornblende increases; hence, this study carries implications for estimating P–T conditions of high‐temperature metabasites using these new a–x relations.     

Numerical distribution of Santonian to Danian corals (Scleractinia,Octocorallia) of Southern Limburg,the Netherlands

The stratigraphical occurrence of 35 known species from the Upper Cretaceous and Danian of Southern Limburg is presented based on existing collections and newly collected material. Corals are relatively rare, except in the Meerssen Member of the Maastricht Formation. Two faunas were recognised in the Meerssen Member: a fauna dominated by Cyclolites cancellata at the base of this member – which coincides with the sequence boundary of the third-order sequence cycle TA1.1 of Haq et al. (1988) – and a fauna dominated by mushroom-shaped and encrusting colonies at the top of the transgressive systems tract of the same sequence cycle.     

VLA Measurements of Faraday Rotation through Coronal Mass Ejections

Coronal mass ejections (CMEs) are large-scale eruptions of plasma from the Sun, which play an important role in space weather. Faraday rotation is the rotation of the plane of polarization that results when a linearly polarized signal passes through a magnetized plasma such as a CME. Faraday rotation is proportional to the path integral through the plasma of the electron density and the line-of-sight component of the magnetic field. Faraday-rotation observations of a source near the Sun can provide information on the plasma structure of a CME shortly after launch. We report on simultaneous white-light and radio observations made of three CMEs in August 2012. We made sensitive Very Large Array (VLA) full-polarization observations using 1?–?2 GHz frequencies of a constellation of radio sources through the solar corona at heliocentric distances that ranged from 6?–?\(15~\mathrm{R}_{\odot}\). Two sources (0842+1835 and 0900+1832) were occulted by a single CME, and one source (0843+1547) was occulted by two CMEs. In addition to our radioastronomical observations, which represent one of the first active hunts for CME Faraday rotation since Bird et al. (Solar Phys., 98, 341, 1985) and the first active hunt using the VLA, we obtained white-light coronagraph images from the Large Angle and Spectrometric Coronagraph (LASCO) C3 instrument to determine the Thomson-scattering brightness [\(\mathrm{B}_{\mathrm{T}}\)], providing a means to independently estimate the plasma density and determine its contribution to the observed Faraday rotation. A constant-density force-free flux rope embedded in the background corona was used to model the effects of the CMEs on \(\mathrm{B}_{\mathrm{T}}\) and Faraday rotation. The plasma densities (\(6\,\mbox{--}\,22\times10^{3}~\mbox{cm}^{-3}\)) and axial magnetic-field strengths (2?–?12 mG) inferred from our models are consistent with the modeling work of Liu et al. (Astrophys. J., 665, 1439, 2007) and Jensen and Russell (Geophys. Res. Lett., 35, L02103, 2008), as well as previous CME Faraday-rotation observations by Bird et al. (1985).     

Using in‐field phosphate testing to rapidly identify middens at Piedras Negras,Guatemala

Recent studies have promoted using soil phosphate analysis to detect ancient Maya sites by delimiting areas of occupation based on decomposed organic matter. Refuse associated with human activity increases organic matter around areas of ancient human habitation. Theoretically, the highest concentration of organic matter—detectable by phosphate analysis—should be directly associated with areas of refuse disposal. Thus, the objective of this study is to investigate the potential of phosphate analysis to detect residential middens in Piedras Negras, Guatemala. This paper presents the results of a sensitive, in‐field phosphate analysis method applied as a midden prospection tool in residential areas. Phosphate concentration is correlated with artifact data obtained from a total of 37 test pits excavated in areas of varying phosphate concentration in three residential sites. A positive correlation between phosphate concentration and ceramic density indicates the potential of this method in defining and orienting excavations of residential areas. © 2001 John Wiley & Sons, Inc.     

Metop-GRAS in-orbit instrument performance

The GRAS instrument on the Metop-A satellite provides more than 600 radio occultation measurement profiles per day. The instrument is characterized by its wide antenna coverage, high signal-to-noise ratio and an ultra-stable clock reference. The conventional dual-frequency tracking of GPS signals is under dynamic atmosphere conditions complemented by open loop tracking with sampling of the signal at a 1 kHz rate, providing an unprecedented view of the signal spectral environment. This paper presents the instrument performance as derived from analysis of in-orbit measurement data. We show that the noise figure is low enough to enable mapping of external radio noise variations over the earth’s surface. An error propagation model is presented to relate instrument characteristics to bending angle performance. This model is also used to illustrate the relation between filter bandwidth, resolution and measurement noise. The Doppler model, guiding open loop measurements, is found to be accurate to better than 20 Hz with a possibility for improvement to 10 Hz. The high performance at low altitudes enables the presence of surface reflections at the −20-dB level to be identified in more than 50% of the occultations. The potential performance improvements for next generation receivers are discussed.     

Adoption of flood-related preventive behaviours by people having different risks and histories of flooding

Natural Hazards - The increase in the frequency of floods, which is a projected consequence of climate change, can have wide-ranging health and economic impacts. To cope with these floods and to...     

Estimating mean residence time of karst groundwater in mountainous catchments of Western Himalaya,India

The mean residence time (MRT) of karst groundwater in three mountainous catchments of the Western Himalaya was estimated using multiple approaches: the tritium method, the sine wave model and tracer tests. Water samples were collected from precipitation, glacier melt, streams and karst springs for δ²H and tritium analysis during 2012 and 2013. High tritium values were observed in winter precipitation and low values in summer precipitation. The variation of tritium in karst springs was similar to that of the streams, whereas glacier melt showed lower tritium values. The MRT of cold karst springs was shorter than that of warm karst springs. The tracer breakthrough curves (TBC) retrieved for different springs suggested a short travel time for groundwater and possibly conduit flow. Deterioration of water quality and variation in flux magnitude are the two main practical consequences of the short travel time of karst groundwater in the region.

EDITOR D. Koutsoyiannis

ASSOCIATE EDITOR K. Heal     

Concurrent Treatment of 1,4‐Dioxane and Chlorinated Aliphatics in a Groundwater Recirculation System Via Aerobic Cometabolism

This research demonstrates that groundwater contaminated by a relatively dilute but persistent concentration of 1,4‐dioxane (1,4‐D), approximately 60 μg/L, and chlorinated aliphatic co‐contaminants (1.4 to 10 μg/L) can be efficiently and reliably treated by in situ aerobic cometabolic biodegradation (ACB). A field trial lasting 265 days was conducted at Operable Unit D at the former McClellan Air Force Base and involved establishing an in situ ACB reactor through amending recirculated groundwater with propane and oxygen. The stimulated indigenous microbial population was able to consistently degrade 1,4‐D to below 3 μg/L while the co‐contaminants trichloroethene (TCE) and 1,2‐dichloroethane (1,2‐DCA) were decreased to below 1 μg/L and 0.18 μg/L, respectively. A stable treatment efficiency of more than 95% removal for 1,4‐D and 1,2‐DCA and of more than 90% removal for TCE was achieved. High treatment efficiencies for 1,4‐D and all co‐contaminants were sustained even without propane and oxygen addition for a 2‐week period.     

Impacts of a Rural Subdivision on Groundwater Quality: Results of Long-Term Monitoring

A rural subdivision in south central Wisconsin was instrumented with monitoring wells and lysimeters before, during, and after its construction to examine the impacts of the unsewered subdivision on groundwater quality and quantity. Prior to construction, the 78-acre (32 ha) site was farmland. Sixteen homes were constructed beginning in 2003. Initial monitoring from 2002 to 2005 showed that groundwater beneath the site had been impacted by previous agricultural use, with nitrate-N values as high as 30 mg/L and some detections of the herbicide atrazine. Our 12-year study shows that the transition from agricultural to residential land use has changed groundwater quality in both negative and positive ways. Although groundwater elevations showed typical seasonal fluctuations each year, there were no measurable changes in groundwater levels or general flow directions during the 12-year study period. Chloride values increased in many wells, possibly as a result of road salting or water softener discharge. Nitrate concentrations varied spatially and temporally over the study period, with some initial concentrations substantially above the drinking water standard. In some wells, nitrate and atrazine levels have declined substantially since agriculture ceased. However, atrazine was still present at trace concentrations throughout the site in 2014. Wastewater tracers show there are small but detectable impacts from septic effluent on groundwater quality. Particle traces based on a groundwater flow model are consistent with the hypothesis that septic leachate has impacted groundwater quality.