Phase equilibria involving humite minerals in impure dolomitic limestones

The natural occurrence of critical assemblages among the phases clinohumite, chondrodite, norbergite, tremolite, forsterite, brucite, periclase, diopside, calcite and dolomite, together with experimental and thermochemical data, permits the calculation of phase equilibria governing the stability of the humite group minerals in impure dolomitic limestones. The phase relations are described by 29 divariant (OH-F) continuous reactions, and 11 univariant discontinuous reactions. The equilibrium conditions for these reactions have been calculated and plotted in isobaricT-X(OH-F) andT- phase diagrams. Continuous reactions govern the compositions of (OH-F) solid solutions and the consequent movement of three-phase triangles on the chemographic diagram. Discontinuous reactions result in the appearance or disappearance of a distinct phase assemblage. The pure OH-humite minerals are metastable relative to forsterite+brucite. With increasing fluorine content, clinohumite, followed in turn by chondrodite and norbergite, becomes stable. The stability fields for the individual humite minerals expand to more CO₂-rich fluid compositions with increasing fluorine content and decreasing total pressure. At 1,000 bars, clinohumite can contain a maximum of 58 mole percent fluorine before reacting discontinuously to form chondrodite (X _F=0.61) and forsterite. The stability field for clinohumite+calcite is restricted to fluids with <0.40. At temperatures less than 700°C, the minimum fluorine mole fractions required to stabilize chondrodite and norbergite are 0.31 and 0.62 respectively. At the same conditions, chondrodite can contain a maximum of approximately 85 mole % F. The calculated phase equilibrium boundaries, the range of stable humite compositions and the compositions of coexisting (OH-F) phases are in good overall agreement with natural assemblages. Owing to steepdT/d slopes for several of the humite continuous reactions, the F/(F+OH) ratio of a given humite mineral is a useful indicator of the CO₂/H₂O ratio of the fluid phase.     

Effects of size and temperature on mud crab,Panopeus herbstii,predation on hard clams,Mercenaria mercenaria

Predation byPanopeus herbstii onMercenaria mercenaria was significantly affected by temperature, and the size of predators and prey items. LargerP. herbstii opened more clams and preyed more successfully on larger clams than did smaller crabs. Increase in seed clam size and decrease in water temperature significantly reduced predation. Clam size appeared to be more important than crab satiation in reducing predation rate. Planting larger seed clams in cooler months should help to improve clam survival by reducing the impact ofP. herbstii in culture operations.     

Evaluation of the CORDEX-Africa multi-RCM hindcast: systematic model errors

Monthly-mean precipitation, mean (T_AVG), maximum (T_MAX) and minimum (T_MIN) surface air temperatures, and cloudiness from the CORDEX-Africa regional climate model (RCM) hindcast experiment are evaluated for model skill and systematic biases. All RCMs simulate basic climatological features of these variables reasonably, but systematic biases also occur across these models. All RCMs show higher fidelity in simulating precipitation for the west part of Africa than for the east part, and for the tropics than for northern Sahara. Interannual variation in the wet season rainfall is better simulated for the western Sahel than for the Ethiopian Highlands. RCM skill is higher for T_AVG and T_MAX than for T_MIN, and regionally, for the subtropics than for the tropics. RCM skill in simulating cloudiness is generally lower than for precipitation or temperatures. For all variables, multi-model ensemble (ENS) generally outperforms individual models included in ENS. An overarching conclusion in this study is that some model biases vary systematically for regions, variables, and metrics, posing difficulties in defining a single representative index to measure model fidelity, especially for constructing ENS. This is an important concern in climate change impact assessment studies because most assessment models are run for specific regions/sectors with forcing data derived from model outputs. Thus, model evaluation and ENS construction must be performed separately for regions, variables, and metrics as required by specific analysis and/or assessments. Evaluations using multiple reference datasets reveal that cross-examination, quality control, and uncertainty estimates of reference data are crucial in model evaluations.     

Dynamic response of flexible rockfall barriers under different loading geometries

Flexible steel barriers are commonly constructed on steep hillsides to mitigate rockfall. The evaluation of the dynamic response of proprietary flexible barriers is conventionally performed using full-scale field tests by dropping a weight onto the barriers in accordance with the European test standard ETAG 27. The weight typically has a spherical or polyhedral shape and cannot reproduce more complex rockfall scenarios encountered in the field. A rigid slab may load a barrier over a larger area and its effect has not been investigated. In this study, a calibrated three-dimensional finite-element model was developed to study the performance of vertically and horizontally orientated rockfall barriers under concentrated areal impact loads. A new bilinear force-displacement model was incorporated into the model to simulate the behavior of the energy-dissipating devices on the barriers. The effect of different weight geometries was studied by considering impacts by a rigid single spherical boulder and a rigid slab. Results reveal that areal loading induced by a rigid slab increases the loading on the barrier foundation by up to 40 % in both horizontally and vertically positioned barriers when compared to a concentrated load scenario with a single boulder. This indicates that barriers tested under the current test standard does not give the worst-case scenario in terms of foundation loads, and barrier designers should take into account the possible effect of increased foundation loads by reinforcing the barrier posts and/or increasing their spacing.     

Characteristics of asbestiform and non-asbestiform calcic amphiboles

In terms of morphology there are four major types of calcic amphibole; massive, prismatic, finely acicular and asbestos. Representatives of each of these types have been examined by optical microscopy, X-ray diffraction, scanning and transmission electron microscopy, and electron probe microanalysis. Massive specimens (nephrite) consist of randomly oriented clusters of fine, roughly lath-shaped, sub-microscopic crystals; within each cluster the lath lengths (z) are approximately aligned but neighbouring laths are rotated with respect to one another. Finely acicular specimens (“byssolites”) have well-formed crystals bounded mainly by {110} (100) and (010) faces and characteristically have striations parallel to their lengths. Asbestiform varieties range from finer (flexible) to coarser (more brittle) specimens and many specimens contain a mixture of fine and coarse fibrils. The fibrils in a bundle are aligned parallel to z but are in a range of azimuthal orientations. It is inferred that they are formed by multiple independent nucleation and growth parallel to z rather than through parting or cleavage on {110} planes. (100) defect or twin planes, or on (010) planar defects.

The {110} cleavage in amphiboles is well reported but (100) features are rarely mentioned in the literature. Our observations reveal the importance of (100) as a cleavage or parting as well as the tendency in nephrites, byssolites and asbestos towards a lath-like (parallel to z) morphology with flattening on (100). In the latter varieties therefore, the y-direction is that of second fastest crystal growth, after z.

When subjected to moderate grinding, the comminution of asbestos fibres proceeds more by separation of fibrils and less by fracturing to shorter lengths as compared with prismatic and byssolite specimens. Prolonged grinding does, however, shorten lengths of even the least brittle asbestos.

Transmission electron microscopy revealed extensive sub-grain boundaries and dislocation networks (suggesting a deformation history) in all prismatic and nephrite specimens. Fine multiple (100) twinning was observed in asbestos but not in other varieties. Although chain-width defects [on (010)], with visibility enhanced by beam damage, were most abundant in nephrites and fibrous tremolites, there appears to be no completely consistent relationship between such features and morphological type.

Electron probe analyses showed that specimens that contain more than a very small amount of aluminium do not have asbestiform habit. Asbestos specimens also have lower contents of Mn, Na and K and have formulae closer to the ideal Ca₂(Mg,Fe)₅Si₈O₂₂(OH)₂. Small departures from this in asbestos involve Na in the A site compensated by Na for Ca rather than Al for Si whereas the reverse is true in byssolites. Chemical substitutions in prismatic specimens are much less constrained.

The characteristics of the four morphological sub-groups correlate reasonably well with what is known of their geological environments.     

Contact metamorphism of impure dolomitic limestone in the Boulder Aureole,Montana

Progressive metamorphism of impure dolomitic limestone in the 1.5 to 2.5 km wide contact aureole surrounding the northernmost portion of the boulder batholith has resulted in a consistent sequence of uniformly distributed zones of low-variance mineral parageneses separated by abrupt and distinctive isograds. In silica-undersaturated, aluminous marbles, the following mineral assemblages occur, in order of increasing grade: calcite-dolomite-calcic amphibole-chlorite, calcite-dolomite-calcic amphibole-chlorite-spinel, calcite-dolomite-calcic amphibole-chlorite-olivine-spinel, calcite-dolomite-chlorite-olivine-spinel, calcite-dolomite-olivine-spinel. The spatial distribution of parageneses and the occurrence of low-variance parageneses indicate buffering of the pore fluid composition by the local mineral assemblages. The observed sequence of mineral reactions and the spacing of isograds is in good agreement with experimental and calculated equilibria in terms of P-T-X _{CO 2}and temperatures of equilibration inferred from calcite-dolomite geothermometry, which range from 435 to 607 °C across the aureole.Microprobe analyses of coexisting minerals indicate attainment of exchange equilibrium. Calcic amphibole and chlorite coexisting with calcite and dolomite become progressively more aluminous with increasing grade; calcic amphibole changes rapidly from Al-poor tremolite to pargasite, while Al^IV in Cte increases from 2.0 to 2.3 atoms per 8 tetrahedral sites. Observed low-variance assemblages fix the activities of calcic amphibole and chlorite end-member components as a function of P and T, and hence the systematic compositional variation in these phases is not an independent variable, but is controlled by the local mineral assemblage.