Iron(VI) Seems an Unlikely Explanation for Viking Labeled Release Results

Tsapin et al. (2000, Icarus147, 68-78) propose the strong oxidant ferrate(VI) to explain the Viking Labeled Release Mars life detection results. However, their data do not support that theory. Further, sensitive IR searches for oxidants on Mars found none, and Viking produced physical evidence against an oxidizing surface. Finally, Tsapin et al. (2000, Icarus147, 68-78) report no precautions to prevent microbial contamination from confounding their results.     

Fish Remains from Homestead Cave and Lake Levels of the Past 13,000 Years in the Bonneville Basin

A late Quaternary ichthyofauna from Homestead Cave, Utah, provides a new source of information on lake history in the Bonneville basin. The fish, represented by 11 freshwater species, were accumulated between 11,200 and 1000 ¹⁴C yr B.P. by scavenging owls. The ⁸⁷Sr/⁸⁶Sr ratio of Lake Bonneville varied with its elevation; ⁸⁷Sr/⁸⁶Sr values of fish from the lowest stratum of the cave suggest they grew in a lake near the terminal Pleistocene Gilbert shoreline. In the lowest deposits, a decrease in fish size and an increase in species tolerant of higher salinities or temperatures suggest multiple die-offs associated with declining lake levels. An initial, catastrophic, post-Provo die-off occurred at 11,300–11,200 ¹⁴C yr B.P. and was followed by at least one rebound or recolonization of fish populations, but fish were gone from Lake Bonneville sometime before 10,400 ¹⁴C yr B.P. This evidence is inconsistent with previous inferences of a near desiccation of Lake Bonneville between 13,000 and 12,000 ¹⁴C yr B.P. Peaks in Gila atraria frequencies in the upper strata suggest the Great Salt Lake had highstands at 3400 and 1000 ¹⁴C yr B.P.     

Hydrodynamics of coalbed methane reservoirs in the Black Warrior Basin: Key to understanding reservoir performance and environmental issues

The Black Warrior Basin of the southeastern United States hosts one of the world’s most prolific and long-lived coalbed methane plays, and the wealth of experience in this basin provides insight into the relationships among basin hydrology, production performance, and environmental issues. Along the southeast margin of the basin, meteoric recharge of reservoir coal beds exposed in an upturned fold limb exerts a strong control on water chemistry, reservoir pressure, and production performance. Fresh-water plumes containing Na–HCO₃ waters with low TDS content extend from the structurally upturned basin margin into the interior of the basin. Northwest of the plumes, coal beds contain Na–Cl waters with moderate to high-TDS content. Carbon isotope data from produced gas and mineral cements suggest that the fresh-water plumes have been the site of significant bacterial activity and that the coalbed methane reservoirs contain a mixture of thermogenic and late-stage biogenic gases.     

A general mixing equation with applications to Icelandic basalts

The mixing equation applied by Vollmer [1] to Pb and Sr isotope ratios is shown to be a general equation applicable to consideration of element and isotope ratios. The mixing equation is hyperbolic and has the form:Ax + Bxy + Cy + D = 0where the coefficients are dependent on the type of plot considered: i.e. ratio-ratio, ratio-element, or element-element. Careful use of this equation permits testing whether mixing is a viable process, places constraints on end member compositions, allows distinction between mixing of sources and mixing of magmas, and should allow distinction between recent mixing and long-term evolution of sources.The available chemical data for postglacial basalts from Iceland and along the Reykjanes Ridge are not consistent with either mixing of magmas or simple mixing of an enriched ocean island source with a depleted ocean ridge source. If the available analyses for basalts are representative of the source regions, the data are consistent with at least two models neither of which can be properly tested with the available data.(1) There are two separate mixing trends: one beneath Iceland with the alkali basalt source and a depleted Iceland source as end members; the second along the Reykjanes Ridge with a heterogeneous ocean ridge basalt source and a source similar to that for intermediate basalts on Iceland as end members. The depleted Iceland source and the depleted ocean ridge source are not the same.(2) The chemistry of the basalts is not determined by mixing. Instead the basalts are derived from a multiplicity of sources with a similar history which have been isolated for hundreds of millions of years.     

A microprobe study of metalliferous sediment components

Smectite aggregates, Fe-Mn micronodules, and fish debris from the coarse fraction of a metalliferous sediment sample from the Bauer Basin have been analyzed by microprobe. Both X-ray diffraction and bulk chemical analyses reveal that the smectite, an iron-rich and aluminum-poor nontronite, is the dominant phase. A linear programming solution to a series of mass balance equations indicates that the bulk sample is 70% smectite, 4% todorokite, 13% microlaminated material, and 1% fish debris. Two episodes of micronodule development are indicated by the presence of overgrowths of microlaminated iron-rich material over a homogeneous dense todorokite core. The two micronodule compositions can be explained by reaction of hydrothermally produced amorphous Fe-Mn oxyhydroxides with biogenous opal to form the calculated phase composition. The rare earth elements in the bulk sample can be explained by a similar diagenetic process which distributes rare earth elements of a seawater origin between cerium-enriched micronodules and cerium-depleted fish debris.     

Factors controlling the noble gas abundance patterns of deep-sea basalts

A number of processes may modify the noble gas composition of silicate liquids so that the composition of noble gases observed in glassy margins of deep-sea basalts is not that of the upper mantle. Differential solubility enhances the light noble gases relative to the heavier gases; however, we demonstrate that the observed abundance pattern cannot be attributed to solubility of noble gases with atmospheric proportions. Partial melting and fractional crystallization increase the noble gas content of all species relative to mantle concentrations, but do not fractionate their relative abundances. Noble gases may be lost from an ascending magma in various ways, the most important, however, may be exclusion of gas from crystals forming at the time of solidification, which is shown to result in marked loss of gas from the basalt. Small amounts of low-temperature alteration of solidified basalt can produce dramatic changes in the noble gas abundance pattern, since the adsorption coefficients for the different noble gas favor uptake of heavy species relative to the light species. Atmospheric contamination can account for observed variations in the ⁴⁰Ar/³⁶Ar ratio of oceanic basalts. The degree of crystallinity of glassy margins of deep-sea basalts may control the helium abundance of these samples; however, the uniform ³He/⁴He values reported apparently reflect a relatively constant proportion of radiogenic and primordial helium in the mantle.     

Modelling of major elements in mantle-melt systems using trace element approaches

Major elements can be modelled in ways similar to the quantitative petrogenetic modelling used for trace elements. In contrast to modelling with trace elements, however, modelling with major elements is constrained by the stoichiometry of the solid phases. Within these constraints, the same equations for partial melting and crystallization which have been used to such advantage for trace elements may be used for major elements.Calculated MgO and FeO abundances in a mantle-melt system are used as an example of the modelling technique. Such modelling yields limited fields of permissible melts and residues for a given parent composition, but does not give the paths of melting. It does allow the temperature and extent of melting which gave rise to a melt to be determined from the MgO and FeO abundances of the melt or residual solid. Applying the results of the modelling to igneous rocks and ultramafic nodules leads to the following conclusions, which are subject to the uncertainties in the available distribution coefficients. Least differentiated basalt glasses from the ocean floor are derived from parent melts with less than 15.5 weight % MgO and 8.2 wt. % FeO. Komatiites may be derived by less than 60% melting of a pyrolite source leaving a residue of olivine and pyroxene. Many nodules from the subcontinental mantle appear to be residues of large fractions of melting (>30%) at high temperature and pressure, whereas ultramafic nodules from oceanic basalts appear to be residues of smaller fractions of melting (<30%) at lower temperatures and pressures.     

Metal accumulation rates in the Southeast Pacific and the origin of metalliferous sediments

Metal accumulation rates over the East Pacific Rise and Bauer Deep rule out normal authigenic precipitation of iron and manganese as the major mechanism of enrichment to the metalliferous sediments. A hydrothermal source located along the East Pacific Rise is compatible with the transition metal and aluminum accumulation rates. For the Bauer Deep the accumulation rate data suggest either that metal-bearing phases are being transported from the rise to the protected basins of the deep or that a second hydrothermal source exists within the Bauer Deep. A major portion of the minor elements being deposited in the Bauer Deep could result from authigenic precipitation, thus accounting for their distinctive chemical composition.     

Particulate dispersion from sources within a forest

Particulate dispersion from sources within a 10- to 13-m tall pine forest was studied experimentally at Brookhaven National Laboratory using stained ragweed pollen and other tracers ranging from 14 to 58 m in size. Forty-seven continuous point source releases lasting from 22 to 55 min were made at heights from 1.75 to 14.0 m from locations having a long fetch through the forest. In most experiments, differently colored ragweed pollen were emitted simultaneously from three locations. In other tests, several particle types were released from a single point. The sampling network consisted of 119 rotoslide samplers at heights from 0.5 to 21.0 m at 57 positions within and at the edge of the forest. Deposition to the ground was sampled by greased microscope slides at each position. Meteorological measurements were taken in and near the forest.Data were classified by particle characteristics, source height and meteorological parameters. Concentration patterns were illustrated on scale diagrams of the sampling grid. Changes in centerline and crosswind integrated concentrations, plume width and height, mass flux, deposition and deposition velocity were studied as a function of distance, particle size and wind speed. Results were compared to those obtained from similar releases over open terrain.In the forest, vertical predominates over lateral dispersion and considerable interchange occurs through the canopy. Flow is channelled somewhat by vegetation density differences but is generally in the direction of the mean wind above the forest. No systematic turning of the wind with height was observed. Most particles are lost to the foliage rather than to the ground and large particles are lost more rapidly than smaller ones. Rate of change in mass flux is similar to that over open terrain and is greater with light than with stronger wind speeds.This research was carried out under the auspices of the New York State Museum and Science Service and the U.S. Atomic Energy Commission (now Energy Research and Development Administration) and was partially supported by Research Grant No. R-800677 from the Division of Meteorology, U.S. Environmental Protection Agency.     

Cyclic triaxial tests on frozen sand

Strain-controlled cyclic triaxial tests were performed on a one-size silica (Ottawa) sand artificially frozen into 71.1-mm-diameter cylindrical samples. Ice-saturated samples with three different sand contents were tested under the following conditions: axial strains ranging from 3 × 10⁻³ to 3 X 10⁻²%, confining pressures from zero to 1.378 MPa, frequencies of 0.05–5.0 cps and temperatures from −1 to −10 °C.

Test equipment included (1) an MTS electrohydraulic closed-loop testing system which applies the load to the sample, (2) a triaxial cell completely immersed in a low-temperature coolant for temperature control, (3) a refrigeration unit for control of the coolant temperature and constant coolant circulation and (4) measuring devices including an LVDT and load cell, together with recording devices such as a digital multimeter, an oscilloscope, a strip-chart recorder and a minicomputer.

Test results indicate that the dynamic Young's modulus increases with increasing frequency, confining pressure and sand content, but decreases with increasing strain and temperature. The damping ratio decreases with increasing frequency, sand content and lower temperatures. The influence of confining pressures and axial strain on the damping ratio are less explicit for the ranges considered. The experimental results are compared with data from other sources.