The composition of nutrient fluxes from contrasting UK river basins

Accurate estimates of N and P loads were obtained for four contrasting UK river basins over a complete annual cycle. The fractionation of these loads into dissolved and particulate, and inorganic and organic components allowed a detailed examination of the nutrient load composition and of the factors influencing both the relative and absolute magnitude of these components. The particulate phosphorus (TPP) loads account for 26–75% of the annual total phosphorus (TP) transport and are predominantly inorganic. The inorganic (PIP) and organic (POP) fractions of the TPP loads represent 20–47% and 6–28% of the annual TP transport, respectively. In contrast, the particulate nitrogen loads (TPN) represent 8% or less of the annual total nitrogen (TN) loads and are predominately organic. For dissolved P transport, the dissolved inorganic fraction (DIP) is more important, representing 15–70% of the TP loads, whereas the dissolved organic fraction (DOP) represents only 3–9% of the TP loads. The TN loads are dominated by the dissolved component and more particularly the total oxidized fraction (TON), which is composed of nitrate and nitrite and represents 76–82% of the annual TN transport. The remaining dissolved N species, ammonium (NH₄-N) and organic N (DON) account for 0·3–1·2% and 13–16% of the annual TN transport, respectively. The TPN and TPP fluxes closely reflect the suspended sediment dynamics of the study basins, which are in turn controlled by basin size and morphology. The dissolved inorganic nutrient fluxes are influenced by point source inputs to the study basins, especially for P, although the TON flux is primarily influenced by diffuse source contributions and the hydrological connectivity between the river and its catchment area. The dissolved organic fractions are closely related to the dissolved organic carbon (DOC) dynamics, which are in turn influenced by land use and basin size. The magnitude of the NH₄-N fraction was dependent on the proximity of the monitoring station to point source discharges, because of rapid nitrification within the water column. However, during storm events, desorption from suspended sediment may be temporarily important. Both the magnitude and relative contribution of the different nutrient fractions exhibit significant seasonal variability in response to the hydrological regime, sediment mobilization, the degree of dilution of point source inputs and biological processes. © 1998 John Wiley & Sons, Ltd.     

Evaluating regional climate model estimates against site-specific observed data in the UK

This paper compares precipitation, maximum and minimum air temperature and solar radiation estimates from the Hadley Centre’s HadRM3 regional climate model (RCM), (50 × 50 km grid cells), with observed data from 15 meteorological station in the UK, for the period 1960–90. The aim was to investigate how well the HadRM3 is able to represent weather characteristics for a historical period (hindcast) for which validation data exist. The rationale was to determine if the HadRM3 data contain systematic errors and to investigate how suitable the data are for use in climate change impact studies at particular locations. Comparing modelled and observed data helps assess and quantify the uncertainty introduced to climate impact studies. The results show that the model performs very well for some locations and weather variable combinations, but poorly for others. Maximum temperature estimations are generally good, but minimum temperature is overestimated and extreme cold events are not represented well. For precipitation, the model produces too many small events leading to a serious under estimation of the number of dry days (zero precipitation), whilst also over- or underestimating the mean annual total. Estimates represent well the temporal distribution of precipitation events. The model systematically over-estimates solar radiation, but does produce good quality estimates at some locations. It is concluded that the HadRM3 data are unsuitable for detailed (i.e. daily time step simulation model based) site-specific impacts studies in their current form. However, the close similarity between modelled and observed data for the historical case raises the potential for using simple adjustment methods and applying these to future projection data.     

The seasonal cycle in coupled ocean-atmosphere general circulation models

We examine the seasonal cycle of near-surface air temperature simulated by 17 coupled ocean-atmosphere general circulation models participating in the Coupled Model Intercomparison Project (CMIP). Nine of the models use ad hoc “flux adjustment” at the ocean surface to bring model simulations close to observations of the present-day climate. We group flux-adjusted and non-flux-adjusted models separately and examine the behavior of each class. When averaged over all of the flux-adjusted model simulations, near-surface air temperature falls within 2?K of observed values over the oceans. The corresponding average over non-flux-adjusted models shows errors up to ～6?K in extensive ocean areas. Flux adjustments are not directly applied over land, and near-surface land temperature errors are substantial in the average over flux-adjusted models, which systematically underestimates (by ～5?K) temperature in areas of elevated terrain. The corresponding average over non-flux-adjusted models forms a similar error pattern (with somewhat increased amplitude) over land. We use the temperature difference between July and January to measure seasonal cycle amplitude. Zonal means of this quantity from the individual flux-adjusted models form a fairly tight cluster (all within ～30% of the mean) centered on the observed values. The non-flux-adjusted models perform nearly as well at most latitudes. In Southern Ocean mid-latitudes, however, the non-flux-adjusted models overestimate the magnitude of January-minus-July temperature differences by ～5?K due to an overestimate of summer (January) near-surface temperature. This error is common to five of the eight non-flux-adjusted models. Also, over Northern Hemisphere mid-latitude land areas, zonal mean differences between July and January temperatures simulated by the non-flux-adjusted models show a greater spread (positive and negative) about observed values than results from the flux-adjusted models. Elsewhere, differences between the two classes of models are less obvious. At no latitude is the zonal mean difference between averages over the two classes of models greater than the standard deviation over models. The ability of coupled GCMs to simulate a reasonable seasonal cycle is a necessary condition for confidence in their prediction of long-term climatic changes (such as global warming), but it is not a sufficient condition unless the seasonal cycle and long-term changes involve similar climatic processes. To test this possible connection, we compare seasonal cycle amplitude with equilibrium warming under doubled atmospheric carbon dioxide for the models in our data base. A small but positive correlation exists between these two quantities. This result is predicted by a simple conceptual model of the climate system, and it is consistent with other modeling experience, which indicates that the seasonal cycle depends only weakly on climate sensitivity.     

Jökulhlaup-related Ice Fracture and Supraglacial Water Release During the November 1996 Jökulhlaup, Skeiðarárjökull, Iceland

During the initial stages of the November 1996 jökulhlaup at Skeiðarárjökull, Iceland, floodwaters burst onto the glacier surface via a series of fractures. This supraglacial drainage led to the formation of a number of distinct ice surface depressions, one of which is investigated in detail. The morphology and structural characteristics of this feature are described, as well as the sedimentology of an associated assemblage of debris-filled fractures. This work suggests that debris-charged subglacial floodwaters travelled up to the glacier surface, where supraglacial flow occurred initially via an extensive network of fractures, orientated parallel to the glacier margin. Supraglacial discharge became progressively more focused into a series of discrete outlets, leading to the mechanical erosion of a number of depressions on the glacier surface. The associated transfer of subglacially derived floodwaters to high levels within the glacier resulted in the rapid entrainment of large volumes of sediment which may influence the patterns, processes and products of ice-marginal sedimentation in the future.     

Regional adjustment of emission strengths via four dimensional data assimilation

The Four-Dimensional Data Assimilation was performed to evaluate source emission strengths over the United States. The USEPA Models-3 system (CMAQ/MM5/SMOKE) and ridge regression are used as the forward and inverse models, respectively. The continental US is divided into six regions, and data assimilation is performed for each region in July 2001 and January 2002. In addition, two separate scaling factors are calculated for weekdays and weekends. Results show that base emissions for CO and SO₂ sources are relatively accurate. Base emissions for PEC source are overestimated 100%, but those for POA source are underestimated up to 70% when compared with the adjusted emissions. Emissions for NH₃, NO _x , and PMFINE sources are relatively accurate in July 2001, but those in January 2002 are around 100% higher than the adjusted emissions. Base VOC emissions in July 2001 are similar to the adjusted emissions but those in January 2002 are underestimated up to 70% when compared with the adjusted emissions. Though the emission adjustment itself improves the overall air quality model performance, a better improvement is expected with the modification of speciation profiles and temporal allocations in the Models-3 system, as well.     

Fluctuations in US Freezing Rain Days

Freezing rain occurrences during a 50-year period, 1949/1950–1998/1999, derived from carefully examined records of 161 first-order stations distributed across the United States, were assessed for temporal fluctuations and trends. Classification of station fluctuations based on five 10-year periods revealed five unique distribution types in areas east of the Rockies. One of these five distributions, for stations located in the western Great Plains, experienced its greatest 10-year value at the end of the 50-year period. The other four regional distributions experienced their highest 10-year value in either of the first two 10-year periods. Nationally, the 10-year period when the greatest number of stations experienced their maximum value was 1949/1950–1958/1959, while the period when the greatest number of stations experienced their minimum value fell near the end of the 50-year record (1979/1980–1988/1989). The 50-year linear trends defined one region, the western Great Plains, with increasing values, while three areas of decreasing trend were identified; the Great Lakes, the eastern Ohio River valley, and southern New England. These analyses also indicate the need to examine and consider such time–space changes in the frequency of climate variables at various spatial scales when assessing weather risks and developing climate change scenarios.     

Bright water: hydrosols, water conservation and climate change

Because air?Cwater and water?Cair interfaces are equally refractive, cloud droplets and microbubbles dispersed in bodies of water reflect sunlight in much the same way. The lifetime of sunlight-reflecting microbubbles, and hence the scale on which they may be applied, depends on Stokes Law and the influence of ambient or added surfactants. Small bubbles backscatter light more efficiently than large ones, opening the possibility of using highly dilute micron-radius hydrosols to substantially brighten surface waters. Such microbubbles can noticeably increase water surface reflectivity, even at volume fractions of parts per million and such loadings can be created at an energy cost as low as J m^???2 to initiate and mW m^???2 to sustain. Increasing water albedo in this way can reduce solar energy absorption by as much as 100 W m^???2, potentially reducing equilibrium temperatures of standing water bodies by several Kelvins. While aerosols injected into the stratosphere tend to alter climate globally, hydrosols can be used to modulate surface albedo, locally and reversibly, without risk of degrading the ozone layer or altering the color of the sky. The low energy cost of microbubbles suggests a new approach to solar radiation management in water conservation and geoengineering: Don??t dim the Sun; Brighten the water.