How do early successional patterns in man-made wetlands differ between cold temperate and Mediterranean regions?

The early stages of succession in newly created wetlands should be impacted by the region in which the wetland is located, since climate may have filtered the dominant biological strategies of the taxa leading this process and may condition their dynamics. We studied the early successional patterns of macroinvertebrates within man made ponds, located in cold temperate (Scandinavian Peninsula) and Mediterranean regions (Iberian Peninsula), during the first three years following their creation. We predicted (1) non random subsets of the regional species pool (deterministic assembly) guiding the successional process in cold temperate wetlands, and random (stochastic) assembly in the Mediterranean region; (2) higher successional rates in Mediterranean ponds than in the cold temperate ponds, with contrary episodes of highest and lowest change throughout the year; and (3) a significant difference in the composition of biological traits between regions, due to the dominance of traits adapted to hydrological variability in the Mediterranean region. Hypotheses on community structure (1) and the composition of dominant biological traits (3) were mostly supported – deterministic assembly mechanisms in the cold temperate ponds and stochastic assembly in the Mediterranean ponds; and a dominance of different biological traits between regions, explained by the need to overcome hydrological disturbances in the Mediterranean ponds. The dynamics of succession (2) were explained by climatic factors in the cold temperate region but not in the Mediterranean ponds. We suggest that the intrinsic hydrological variability of Mediterranean lentic systems may be a major factor driving community changes in man-made wetlands in this region. In order to generalize the observed patterns, we performed a meta-analysis of the temporal trends of taxonomic distinctness parameters of other successional studies across a latitudinal gradient in Europe, which supported the differences we had observed between latitudinal extremes.     

Effects of wave-wave and wave-mean flow interactions on the evolution of a baroclinic wave

Abstract

The weakly nonlinear evolution of a free baroclinic wave in the presence of slightly supercritical, vertically sheared zonal flow and a forced stationary wave field that consists of a single zonal scale and an arbitrary number of meridional harmonics is examined within the context of the conventional two-layer model. The presence of the (planetary-scale) stationary wave introduces zonal variations in the supercriticality and is shown to alter the growth rate and asymptotic equilibrium of the (synoptic-scale) baroclinic wave via two distinct mechanisms: The first is due to the direct interaction of the stationary wave with the shorter synoptic wave (wave-wave mechanism), and the second is due to the interaction of the synoptic wave with that portion of the mean field that is corrected by the zonally rectified stationary wave fluxes (wave-mean mechanism). These mechanisms can oppose or augment each other depending on the amplitude and spatial structure of the stationary wave field. If the stationary wave field is confined primarily to the upper (lower) layer and consists of only the gravest cross-stream mode, conditions are favorable (unfavorable) for nonzero equilibrium of the free wave.

In addition to the time dependent heat flux generated by baroclinic growth of the free wave, its interaction with a stationary wave field consisting of two or more meridional harmonics generates time dependent heat fluxes that vary with period of the free wave. However, if the stationary wave field contains several meridional harmonics of sufficiently large amplitude, the free baroclinic wave is destroyed.     

Biogeochemical processes controlling methane in gassy coastal sediments—Part 2: groundwater flow control of acoustic turbidity in Eckernförde Bay Sediments

To understand the origin of the methane distributions in sediments of Eckernförde Bay, three sites were sampled in May 1994 for determination of methane, sulfate and chloride concentrations in the sediment porewaters. In much of the Bay, bubbles of biogenic methane gas within the sediments lead to widespread ‘acoustic turbidity’ seen in acoustic surveys, masking the sedimentary structure below the gassy horizon. Acoustic windows, where the gas does not appear to be present, occur in several locations in the Bay, often surrounded by acoustically turbid sediments. Pockmarks, shallow depressions in the sediment, are also found in Bay sediments and may show acoustic turbidity at even shallower depths below the interface than surrounding sediments. One site of each type was sampled in this study. The site probably representative of much of the bay below 20 m water depth, revealed methane saturated conditions by about 75 cm depth below the interface, confirming inferences from acoustic scattering data that free gas was present in the sediment. Above this, the methane concentration profile was concave-upward, indicative of methane oxidation in the overlying, sulfate-reducing sediments. These porewaters showed a slightly decreasing chlorinity with depth. At an acoustic window site, methane concentrations rose to a maximum at about 125 cm depth, but did not reach saturation. Below this depth they decreased in a concave-down pattern. Chloride concentrations decreased markedly with depth, indicative of vertical freshwater flow from below. The third site was a pockmark exhibiting very shallow acoustic turbidity at about 25 cm depth. Here methane concentrations rose to exceed saturation within 25 cm depth below the interface and the porewaters became almost fresh by 1.5 m depth, indicative of a stronger flow of freshwater from below. These groundwater flows have competing effects on the methane inventory. They help exclude sulfate from the sediment, allowing the earlier/shallower onset of methanogenesis, but they also aid loss of methane through advection. A diagenetic model that couples the biogeochemistry of sulfate and methane is used to explain the presence or absence of methane gas in these sediments in relation to the flow rate of fresh groundwater from below. Model results indicate that acoustic windows within otherwise acoustically turbid sediments of the bay are likely due to relatively higher rates of vertical advection of fresh groundwater. The gassy pockmark, however, with an even higher vertical advection rate, seems to require the input of additional reactive organic carbon to explain its vertical methane distribution.     

Seasonal and event-controlled export of organic matter from the shelf towards the Gulf of Lions continental slope

To investigate the role of coastal canyons in the transfer of organic matter from the shelf to the slope and basin, we deployed sediment trap/current meter pairs at the head of five canyons in the Gulf of Lions (GoL) between November 2003 and May 2004. Analysis of organic carbon, biogenic silica, Corg isotopic composition, Corg/total nitrogen, chloropigments, and amino acids clearly shows the seasonal influence and effect of extreme meteorological events on the composition of collected particles. The sampling period was divided into three “scenarios”. The first corresponded to a large easterly storm and flood of the Rhone river during stratified water column conditions; the composition of material collected during this event was influenced by increased transfer of riverine and coastal particulate matter, with a lower Corg content. During the second “fall-winter” scenario, northern and northwestern winds blowing over the shelf caused cooling and homogenization of the shelf water column; particles collected at this time reflected the homogeneous source of particulate matter transported through canyons; particles sitting in the vicinity of canyon heads are most likely swept downslope by the general south-westward circulation. Organic tracers indicate a degraded origin for organic matter transported during this period. A third “spring” scenario corresponded to northern winds alternating with eastward windstorms that triggered and/or enhanced the cascading of dense waters accumulated on the bottom of the shelf due to previous cooling. These conditions occurred in conjunction with increased phytoplankton productivity in shelf surface waters. Organic matter advected mainly by dense shelf water cascading was fresher due to the transport of newly produced particles and a variable terrestrial fraction; this fraction depended on the proportion of resuspended material accumulated during previous high discharge periods that was involved in each transport pulse. The tight link shown between meteorological conditions and organic matter transport is important for continental margin geochemical studies as future changes in climatic conditions may lead to dramatic changes in carbon sequestration capability and in the ecosystems of deep margin environments.     

Using MODFLOW code to approach transient hydraulic head with a sharp‐interface solution

Saltwater intrusion problems have been usually tackled through analytical models because of its simplicity, easy implementation and low computational cost. Most of these models are based on the sharp‐interface approximation and the Ghyben–Herzberg relation, which neglects mixing of fresh water and seawater and implicitly assumes that salt water remains static. This paper provides insight into the validity of a sharp‐interface approximation defined from a steady state solution when applied to transient seawater intrusion problems. The validation tests have been performed on a 3D unconfined synthetic aquifer, which include spatial and temporal distribution of recharge and pumping wells. Using a change of variable, the governing equation of the steady state sharp‐interface problem can be written with the same structure of the steady confined groundwater flow equation as a function of a single potential variable (?). We propose to approach also the transient problem solving a single potential equation (using also the ? variable) with the same structure of the confined groundwater flow equation. It will allow solving the problem by using the classical MODFLOW code. We have used the parameter estimation model PEST to calibrate the parameters of the transient sharp‐interface equation. We show how after the calibration process, the sharp‐interface approach may provide accurate enough results when applied to transient problems and improve the steady state results, thus avoiding the need of implementing a density‐dependent model and reducing the computational cost. This has been proved by comparing results with those obtained using the finite difference numerical code SEAWAT for solving the coupled partial differential equations of flow and density‐dependent transport. The comparison was performed in terms of piezometric heads, seawater penetration, transition zone width and critical pumping rates. Copyright © 2014 John Wiley & Sons, Ltd.     

Parameter Estimation for Groundwater Models under Uncertain Irrigation Data

The success of modeling groundwater is strongly influenced by the accuracy of the model parameters that are used to characterize the subsurface system. However, the presence of uncertainty and possibly bias in groundwater model source/sink terms may lead to biased estimates of model parameters and model predictions when the standard regression‐based inverse modeling techniques are used. This study first quantifies the levels of bias in groundwater model parameters and predictions due to the presence of errors in irrigation data. Then, a new inverse modeling technique called input uncertainty weighted least‐squares (IUWLS) is presented for unbiased estimation of the parameters when pumping and other source/sink data are uncertain. The approach uses the concept of generalized least‐squares method with the weight of the objective function depending on the level of pumping uncertainty and iteratively adjusted during the parameter optimization process. We have conducted both analytical and numerical experiments, using irrigation pumping data from the Republican River Basin in Nebraska, to evaluate the performance of ordinary least‐squares (OLS) and IUWLS calibration methods under different levels of uncertainty of irrigation data and calibration conditions. The result from the OLS method shows the presence of statistically significant (p < 0.05) bias in estimated parameters and model predictions that persist despite calibrating the models to different calibration data and sample sizes. However, by directly accounting for the irrigation pumping uncertainties during the calibration procedures, the proposed IUWLS is able to minimize the bias effectively without adding significant computational burden to the calibration processes.     

Geochemische Untersuchungen an einem Vorkommen von Fasersteinsalz

Zusammenfassung Am Beispiel des Fasersteinsalzes wird untersucht, ob die Verteilung des im NaCl eingebauten Broms Rückschlüsse auf den Wachstumsvorgang und die Herkunft der für das Wachstum benötigten Lösungen zuläßt. NachSchmidt undMügge erfolgt das Wachstum der Fasern an ihrer Basis. Wenn dieser Vorgang stimmt, sollte der Br-Gehalt in den älteren Teilen des Fasersteinsalzes (in der Mitte der Kluft gelegen) niedriger sein als in den zuletzt gebildeten Partien der Kluftfüllung (an der Kluftwand gelegen). Tatsächlich konnte an dem natürlichen Fasersteinsalz festgestellt werden, daß der Br-Gehalt im Steinsalz von der Mitte der Kluft zum Rand zunimmt. Auch die Lösungszufuhr kann nach diesem Befund nur in Form von Porenlösungen aus dem Nebengestein erfolgt sein. Aus dem Br-Gehalt des Fasersteinsalzes wurde die Br-Konzentration in den Porenlösungen mit 3,5 · 10^–1 Gew.- % berechnet.

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Summary The distribution of bromine replacing chlorine in fibrous halite of the potash salt mine Marie Louise (Elsaß, France) was determined in order to examine the crystallisation process of this halite. The contents of bromine increase in the cleavage filling of the fibrous halite from the central part to the contact with the marl. The cause of this distribution is the growth of the fibre perpendicular to its base during the opening of the cleavage. The fibrous halite crystallizes from pore solutions originating in the marl rock. The calculation showed that the bromine content in the solution was about 0.35 wt.- %.

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Herrn Prof. Dr. Dr. h. c.C. W. Correns zum 70. Geburtstag gewidmet.     

The distribution of titanium on the lunar surface

Titanium concentrations have been derived from measurements with the lunar-orbiting gamma-ray experiment on Apollo 15 and 16 by analyzing a spectral interval in which the titanium signal is relatively enhanced. Landing site soil values provide the reference for a regression curve from which Ti concentrations in 137 regions of adequate counting statistics are calculated. Among the mare regions overflown, the southern portion of Mare Tranquillitatis contains the highest Ti concentration (4.4%), Mare Serenitatis, Mare Fecunditatis, and Mare Smythii have intermediate values corresponding to low-Ti basalts, and Mare Crisium is conspicuously low in Ti (0.9%). Regional values in the western maria range from 1.1% to 4.1%, somewhat higher in the north than in the south, with the highest values seen south and west of Aristarchus. The Aristarchus Plateau appears chemically distinct from the surrounding mare. The younger western basalts mapped by the experiment do not appear to be identical to the Apollo 11 and Apollo 17 high-Ti basalts. Low-Ti basalts predominate in the observed mare regions. Highland Ti concentrations range from undetectable to 1.5% with several exceptions; accuracy is limited by the relatively large uncertainty. Highland results suggest a north-south asymmetry which is not consistent with previously reported results for Fe and Th. Comparisons with telescopic spectral reflectance studies of the maria do not show complete agreement and suggest that effects due to Fe may not have been fully removed from the reflectance data.     

The climatic response of the Arctic Ocean to Soviet river diversions

A numerical model is constructed to evaluate the effect of river diversions on the circulation of the Arctic Ocean, including the climatically important response in the extent of sea ice. The ocean model solves the primitive equations of motion in finite-difference form for the irregular geometry of the Arctic Ocean and Greenland/Norwegian Sea, using 110 km horizontal grid spacing and up to 13 unevenly spaced levels in the vertical. Annual mean atmospheric conditions and river discharges are specified from observations. The presence of sea ice is diagnosed on the basis of model ocean temperature; and the effects of sea ice on the surface fluxes of momentum, heat, and salt are included in a simplified way. Lateral exchanges at the southernmost boundary are held near observed values but respond to circulation changes in the Greenland/Norwegian Sea. Three equilibrium solutions are obtained by eighty-year integrations from simple initial conditions: the first with inflow from all rivers, the second with one-third of the inflow diverted from four major rivers (the Ob, Yenesei, Dvina, and Pechora), and the third with total diversion from those rivers. The middle case corresponds to maximal diversions which are either planned or envisioned by the Soviet Union over the next fifty years, whereas the final extreme case is run in the event that model sensitivity is low relative to that of nature.The control integration gives a good simulation of known water masses and currents. In the Central Arctic, for example, the model correctly predicts a strong shallow halocline, a relatively warm intermediate layer of Atlantic origin, and a temperature jump across the deep Lomonosov Ridge. The overall pattern of surface salinity and the margin of the pack ice are also properly simulated.When runoff into the marginal Kara and Barents Seas is diverted, either in part or in full, almost no effect on the halocline results in the Central Arctic. In particular, deep convection does not develop in the Eurasian Basin, the possibility of which was suggested by Aagaard and Coachman (1975). The vertical stability within the two marginal seas is considerably decreased by the total diversion of four rivers, but not to the point of convective overturning. The surface currents in this area change to confine the water with increased salinity to the shelf region. At deeper levels, an increased salinity tongue spreads into the deep basins of the ice-free Greenland/Norwegian Sea, where existing deep convection is slightly enhanced. As a result, there is some additional heat loss from the Atlantic layer before it enters the Central Arctic. The ice extent remains nearly the same as before within the Kara and Barents Seas. In fact, since modified bottom currents over the continental shelf bring in less heat from the Greenland Sea, an increased thickness of sea ice may result there, in spite of reduced vertical stability. These model responses are generally in agreement with those suggested by Micklin (1981) and by Soviet investigations of the effect of river diversions. These annualmean results should be regarded as tentative, pending confirmation by studies which include the seasonal cycles of runoff and atmospheric forcing.The National Center for Atmospheric Research is sponsored by the National Science Foundation.     

Scaling Variances of Scalars in a Convective Boundary Layer Under Different Entrainment Regimes

For the presentation and analysis of atmospheric boundary-layer (ABL) data, scales are used to non-dimensionalise the observed quantities and independent variables. Usually, the ABL height, surface sensible heat flux and surface scalar flux are used. This works well, so long as the absolute values of the entrainment ratio for both the scalar and temperature are similar. The entrainment ratio for temperature naturally ranges from −0.4 to −0.1. However, the entrainment ratio for passive scalars can vary widely in magnitude and sign. Then the entrainment flux becomes relevant as well. The only customary scalar scale that takes into account both the surface flux and the entrainment flux is the bulk scalar scale, but this scale is not well-behaved for large negative entrainment ratios and for an entrainment ratio equal to −1. We derive a new scalar scale, using previously published large-eddy simulation results for the convective ABL. The scale is derived under the constraint that scaled scalar variance profiles are similar at those heights where the variance producing mechanisms are identical (i.e., either near the entrainment layer or near the surface). The new scale takes into account that scalar variance in the ABL is not only related to the surface flux of that scalar, but to the scalar entrainment flux as well. Furthermore, it takes into account that the production of variance by the entrainment flux is an order of magnitude larger than the production of variance by the surface flux (per unit flux). Other desirable features of the new scale are that it is always positive (which is relevant when scaling standard deviations) and that the scaled variances are always of order 1–10.