喀拉通克铜镍矿床硫同位素组成特征及其地质意义

硫同位素研究在喀拉通克岩体的地壳物质混染过程中有重要意义。通过对块状和浸染状矿石、斑点状和脉状矿石以及围岩中硫化物进行硫同位素测试,分析了黄铜矿、黄铁矿、磁黄铁矿的硫同位素在硫化物中的富集状态,探讨了喀拉通克铜镍矿床硫同位素组成特征及其地质意义。结果表明:块状矿石的同位素测定值与标准值之间的千分偏差δ(34S)为(-1.30～1.84)×10-3,浸染状矿石的δ(34S)为(-2.50～0.85)×10-3,脉状矿石的δ(34S)为(-1.54～3.00)×10-3,围岩中黄铁矿的δ(34S)为(-7.8～-3.3)×10-3;硫同位素在硫化物中的富集从大到小依次为黄铁矿、磁黄铁矿、黄铜矿,说明硫化物之间基本达到了硫同位素平衡;喀拉通克铜镍矿床的硫主要来自于地幔,只在岩浆熔离作用形成的浸染状矿石和岩浆后期热液阶段形成的脉状矿石以及晚期黄铁矿中有少量或局部地壳硫混染的痕迹;地壳硫的加入没有在岩浆源区发生,可能发生在岩浆上升并发生硫化物就地熔离的局部过程中,几乎不对硫饱和及硫化物的熔离产生影响;岩浆在地壳深部发生的橄榄石、铬铁矿等矿物的分离结晶作用,有可能是促使硫饱和与硫化物熔离的主要因素。     

Paratacamite from Gypsum Veins in Sandstones of the Kuqa Basin,Xinjiang, China: Implications for a New Epigenetic Cu Enrichment Mechanism

The Kuqa Basin filled with Paleogene evaporite series is located in the northeast of the Tarim Basin, Xinjiang, China. It is famous for sandstone‐hosted Cu deposits formed by synsedimentary processes. However, our recent studies reveal that there has been another Cu mineralization mechanism in this basin. Field investigations show that there is a close relationship among faults, salt domes, and brine. Cu deposits are mainly located in two east–west‐trending anticlinal belts in the basin, adjacent to salt domes in the belts. Cu minerals in gypsum veins of the Jidike and Kangcun formations have been investigated by SEM, EDS, and X‐ray diffraction methods. The occurrence of paratacamite in gypsum veins has been reported to coexist with glauberite and halite in the joint planes of sandstones. In addition, it occurs accompanying residual crystal salt encrustation in limestone fractures, or in sandstones in dendritic form. These features indicate that the surface‐Cu enrichment in the Kuqa Basin might have originated from Cu‐bearing brine in the underlying evaporite units, which migrated upward along fractures. In addition, the presence of H₂S in the east–west fault belt in the Kuqa Basin, and the discovery of surface sulfur, calcium carbonate, and covellite, suggest thermochemical sulfate reduction near salt domes in the deeper parts of the rock units. This process resulted in the generation of reduced brine and provided a favorable environment for Cu enrichment. Therefore, the surface‐Cu mineralization near salt domes is interpreted to be the result of Cu‐bearing brine migrating upward to the surface along faults (or joints) following the intrusion of deep salt domes. The geological evidence indicates the presence of reducing brine and Cu‐bearing brine near the salt dome in the deeper rocks of the Kuqa Basin, thus making the intrusive contact zone of the salt dome a favorable site for the epigenetic enrichment of Cu. Our study demonstrates that Cu enrichment in the Kuqa Basin resulted not only from synsedimentary deposition but also through epigenetic enrichment associated with salt dome intrusion and brine‐rich fluids.     

Timing of UHP metamorphism in the Hong’an area,western Dabie Mountains,China: evidence from zircon U–Pb age,trace element and Hf isotope composition

The Hong’an area (western Dabie Mountains) is the westernmost terrane in the Qinling-Dabie-Sulu orogen that preserves UHP eclogites. The ages of the UHP metamorphism have not been well constrained, and thus hinder our understanding of the tectonic evolution of this area. LA-ICPMS U–Pb age, trace element and Hf isotope compositions of zircons of a granitic gneiss and an eclogite from the Xinxian UHP unit in the Hong’an area were analyzed to constrain the age of the UHP metamorphism. Most zircons are unzoned or show sector zoning. They have low trace element concentrations, without significant negative Eu anomalies. These metamorphic zircons can be further subdivided into two groups according to their U–Pb ages, and trace element and Lu–Hf isotope compositions. One group with an average age of 239 ± 2 Ma show relatively high and variable HREE contents (527 ≥ Lu_N ≥ 14) and ¹⁷⁶Lu/¹⁷⁷Hf ratios (0.00008–0.000931), indicating their growth prior to a great deal of garnet growth in the late stage of continental subduction. The other group yields an average age of 227 ± 2 Ma, and shows consistent low HREE contents and ¹⁷⁶Lu/¹⁷⁷Hf ratios, suggesting their growth with concurrent garnet crystallization and/or recrystallization. These two groups of age are taken as recording the time of prograde HP to UHP and retrograde UHP–HP stages, respectively. A few cores have high Th/U ratios, high trace element contents, and a clear negative Eu anomaly. These features support a magmatic origin of these zircon cores. The upper intercept ages of 771 ± 86 and 752 ± 70 Ma for the granitic gneiss and eclogite, respectively, indicate that their protoliths probably formed as a bimodal suite in rifting zones in the northern margin of the Yangtze Block. Young Hf model ages (T _DM1) of magmatic cores indicate juvenile (mantle-derived) materials were involved in their protolith formation. Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users.     

山东高岭土矿成矿特征及成矿规律探讨

山东省已发现高岭土矿床18处,分为沉积型和风化残积型2种类型.沉积型高岭土矿受沉积作用的控制,石炭系-二叠系是其主要赋矿层位,广泛发育于鲁中地区北部的各煤田中.风化残积型高岭土矿则以中、小型矿床和矿点的形式零星分布于鲁南和鲁东各地.本文总结了山东省高岭土矿的成矿特征和成矿模式,通过典型矿床详细介绍了高岭土矿的矿体特征和...     

华北—东北地区震磁异常与日本强震对应关系

选取2009—2014年华北—东北地区发生的12次中等地震,对该区8个地磁台站记录的地磁Z分量日变幅进行小波分析及合成计算,与日本海沟同期发生的12次M≥6.5强震进行关联性分析,发现日本强震对中国华北—东北地区中等地震活动具有连带作用,表现在:①日本强震发生前后,华北或东北地区均有M4—5地震出现,频次一般为1—3,间隔几天至5个月左右;②2011年3月10日日本M9.1地震后,华北、东北地区中等地震震级有所升高,其中东北地区由M4升至M5,距日本最近的中俄交界甚至出现M6.1地震,华北地区唐山老震区出现1次M4.8地震,震级接近5;③每次日本强震出现后几天至2个月内,8个地磁台地磁Z分量小波细节6阶合成曲线值均出现2—6个月高值异常,但幅度大小与强震震级无明显规律可循,而华北或东北地区中等地震一般在异常高值出现前后低值附近发生。     

用钻孔应变观测研究北京地区活断层的现今活动

研究断层活动性的主要目的之一是了解地震危险性,与地震危险性最直接相关的是现今的断层活动情况.如果对当地断层分布和性质有比较清楚的了解,那么就可以根据位错理论用钻孔应变仪观测资料反演断层活动.用遗传算法进行这种反演可以在进行全局搜索的同时大大提高计算效率.北京地区的活断层研究程度比较高,同时有比较密集的钻孔应变观测台站.利用2003-2005年钻孔应变观测资料对北京地区活断层活动的初步尝试性反演表明,在此期间顺义-良乡断层北段和南口-孙河断层东南段的活动可能起主导作用,活动程度与小震活动有关系.     

鄂尔多斯盆地南部地区延长组深水沉积构造特征及地质意义

鄂尔多斯盆地南部地区上三叠统延长组长7段发育有典型的重力流沉积。对野外露头剖面进行大量调查研究,发现研究区重力流沉积发育丰富的沉积构造,底层面构造、软沉积变形构造是主要的两种类型。这种深水沉积构造组合能够很好地揭示研究区广泛发育的一定坡度背景下深水重力流沉积体系。滑移-滑塌沉积、砂质碎屑流沉积、浊流沉积是研究区发育最为广泛的深水重力流沉积类型,滑移-滑塌及软沉积变形构造为触发机制沉积响应,底层面构造为砂质碎屑流沉积及浊流沉积响应。综合分析研究区地层发育的大量凝灰岩夹层、深水泥岩中发育的植物碎屑、深水砂岩中发育的大量浅黄色泥砾等沉积特征,认为地震、火山喷发及季节性洪水为研究区深水重力流沉积最有利的触发因素。     

天山奎屯河哈希勒根51号冰川表面运动特征分析

奎屯河哈希勒根51号冰川位于新疆奎屯市以南的天山依连哈比尔尕山北坡, 奎屯河上游支沟哈希勒根河源区. 1999年8月, 在该冰川上布设了用于冰川运动和冰川物质平衡观测研究的测杆18根, 并进行了冰川表面运动、冰川物质平衡和冰川末端变化的首次观测. 根据2000年8月和2001年8月的冰川运动观测资料, 分析了奎屯河哈希勒根51号冰川的运动特征和冰舌末端的变化状况. 结果表明: 奎屯河51号冰川应属于亚大陆型冰川; 1999/2000年度和2000/2001年度的表面运动值不大, 最大流速点的年运动速度为3.15 ma-1; 运动速度垂直分量UZ的变化规律同乌鲁木齐河源1号冰川的变化规律相同, 即消融区的显出流作用和积累区的显入流作用. 该冰川的冰舌末端处于相对稳定的退缩状态, 1964-1999年间平均退缩量约为1.4 m*a-1, 而1999-2001年间的平均退缩量为5.0 m*a-1, 反映出冰川退缩增大的趋势.     

基于感兴趣区域在区域层面上决策的SAR图像变化检测的方法研究

在现有的变化检测方法中,针对差分图像的方法得到了广泛的应用,但现有该框架下的技术都在在像素层面上决策产生的变化检测结果,这易使结果中存在诸如有噪声般散落的杂点、连通区域内有孔洞及边缘不平滑等缺陷。为此,本文给出一种在区域层面上决策生成变化检测结果的技术,其核心为抽取并处理感兴趣区域,而关键在于获取合适的抽取感兴趣区域的标签和如何在区域层面上生成变化检测结果。为使抽取的感兴趣区域包含几乎所有的变化类信息,我们用平稳小波变换和模糊C-均值(Fuzzy C-Means, FCM)算法分两步获取抽取感兴趣区域的标签;为在区域层面上生成变化检测结果,我们依据标签搜索感兴趣区域内所有的连通区域,并把每个连通区域看作为一个数据点,再由阈值技术处理这些数据点生成最终的变化检测结果。对真实SAR图像数据集的变化检测结果表明,其主观效果和客观性能都优于其他相关技术的。     

徐州土壤多环芳烃的环境地球化学迁移特征

选择江苏徐州黄棕壤进行不同深度层位多环芳烃含量的定量分析,研究并探讨了多环芳烃在土壤深度剖面中的地球化学迁移特征。研究结果显示,多环芳烃在徐州土壤剖面中主要集中在地表0~20 cm内。其中低环多环芳烃化合物的迁移能力较强,4~6环等高环化合物相对较难迁移,主要残留于地表生态系统环境中。