Comparison of isotope pairing and N2:Ar methods for measuring sediment denitrification—Assumption, modifications, and implications

Denitrification has been measured during the last few years using two different methods in particular: isotope pairing measured on a triple-collector isotopic ratio mass spectrometer and N₂:Ar ratios measured on a membrane inlet mass spectrometer (MIMS). This study compares these two techniques in short-term batch experiments. Rates obtained using the original N₂∶Ar method were up to 3 to 4 times higher than rates obtained using the isotope pairing technique due to O₂ reacting with the N₂ during MIMS analysis. Oxygen combines with N₂ within the mass spectrometer ion source forming NO⁺ which reduces the N₂ concentration. The decrease in N₂ is least at lower O₂ concentrations and since oxygen is typically consumed during incubations of sediment cores, the result is often a pseudo-increase in N₂ concentration being interpreted as denitrification activity. The magnitude of this ocygen effect may be instrument specific. The reaction of O₂ with N₂ and the subsequent decrease in N₂ was only partly correctly using an O₂ correction curve for the relationship between N₂ and O₂ concentrations. The O₂ corrected N₂∶Ar denitrification rates were lower, but still did not match the isotope pairing rates and the variability between replicates was much higher. Using a copper reduction column heated to 600°C to remove all of the O₂ from the sample before MIMS analysis resulted in comparable rates (slightly lower), and comparable variability between replicates, to the isotope pairing technique. The N₂:Ar technique determines the net N₂ production as the difference between N₂ production by denitrification and N₂ consumption by N-fixation, while N-fixation has little effect on the isotope pairing technique which determines a rate very close to the gross N₂ production. When the two different techniques were applied on the same sediment, the small difference in rates obtained by the two methods seemed to reflect N-fixation as also supported from measurements of ethylene production in acetylene enriched sediment cores. The N₂:Ar and isotope pairing techniques may be combined to provide simultaneous measurements of denitrification and N-fixation. Both techniques have several assumptions that must be met to achieve accurate rates; a number of tests are outlined that can be applied to demonstrate that these assumptions are being meet.     

Oxygen and nutrient dynamics within mats of the filamentous macroalga Chaetomorpha linum

Concentration profiles of O₂, NH₄ ⁺, NO₃ ⁻, and PO₄ ³⁻ were measured at high spatial resolution in a 12-cm thick benthic mat of the filamentous macroalga Chaetomorpha linum. Oxygen and nutrient concentration profiles varied depending on algal activity and water turbulence. High surface irradiance stimulated O₂ production in the surface layers and introduced O₂ to deeper parts of the mat while the bottom layers of the mat and the underlying sediment were anoxic. Nutrient concentrations were highest in the bottom layers of the mat directly above the sediment nutrient source and decreased towards the surface layers due to algal assimilation and enhanced mixing with the overlying water column. Increased turbulence during windy periods resulted in more homogeneous oxygen and nutrient concentration profiles and shifted the oxic-anoxic interface downward. Denitrification within the mat, as measured by the isotope pairing technique on addition of ¹⁵NO₃ ⁻, was found to take place directly below the oxic-anoxic interface. Denitrification activity was always due to coupled nitrification-denitrification, whereby nitrifiers in the mat utilize NH₄ ⁺ diffusing from below and O₂ diffusing from above. The denitrification rate in the mat ranged from 22 μmol m⁻² h⁻¹ to 28 μmol m⁻² h⁻¹, approximately equivalent to that measured in the surrounding nonvegetated sediment. Although sediment denitrification is suppressed when the sediment surface is covered by a dense macroalgal mat, the denitrification zone may migrate up into the mat. In eutrophic estuaries with a large area of macroalgal cover, the physical structure and growth stage of algal mats may thus play an important role in the regulation of nitrogen removal by denitrification.     

辽宁盖县梁屯—矿洞沟碱性正长岩杂岩体的U—Pb和Sm—Nd年龄及其地质意义

辽宁梁屯 -矿洞沟杂岩体主要由辉石正长岩、霓辉正长岩和霓辉角闪正长岩等碱性岩石组成 ,具有全岩 Rb- Sr等时线年龄 186 6± 115 Ma和 ISr=0 .70 4 9的同位素特征 ,是我国目前报道的最古老的碱性正长岩类。本文报道了该岩体的锆石U- Pb和全岩 Sm- Nd同位素测试资料 ,获得了锆石 U- Pb同位素年龄为 185 7± 2 0 Ma、Sm- Nd等时年龄为 1787± 180 Ma、εNd(t) =- 4 .8～ - 5 .0的数据。它们反映出该杂岩体形成年龄的上限为 185 7± 2 0 Ma、下限不小于 1787± 180 Ma,来源于富集地幔物质。基于这些数据并结合区域地质资料分析 ,作者提出了华北地台北缘古元古宙存在有富集地幔储库 ,以及辽河群主体形成于 190 0 Ma以前的认识     

Multi-species chemical data assimilation with the Danish Eulerian hemispheric model: system description and verification

Satellite retrievals of atmospheric composition provide a wealth of data on a global scale. These complement results from atmospheric chemistry-transport models (CTMs), and can be combined using data assimilation. We present two assimilation schemes coupled to the Danish Eulerian Hemispheric Model (DEHM), a three-dimensional, off-line CTM with full photochemistry: a variant on the ensemble Kalman filter and the three-dimensional variational scheme. The aim of this paper is to describe the two schemes and present an initial assessment of their impacts on model skill. Retrievals of multiple atmospheric trace gases are assimilated, namely: NO₂ tropospheric column densities, CH₄ total column densities, and partial column concentrations of O₃, CO and CH₄; these data are retrieved from four satellite sensors. Data for each species are assimilated independently of one another, and other species are only adjusted indirectly via the model’s chemistry and dynamics. Assimilation results are compared with measurements from surface monitoring stations and other satellite retrievals, and preliminary validation results are presented.Reference simulations (without assimilation) grossly underestimate surface CO concentrations, and both assimilation schemes eliminate this large and systematic model bias. The assimilation improves the spatial correlation of modelled CO with surface observations, and improves the spatial correlation between forecasts and retrievals for CO, NO₂ and O₃. Results for CH₄ show a loss of skill due to a mismatch in model bias between two assimilated CH₄ data-sets. Finally, we discuss differences in methodology and results between this paper and a recent study on multi-species chemical data assimilation. Joint optimisation of initial conditions and emission rates offers a promising direction for improving modelled boundary-layer concentrations.     

A hard X-ray telescope/concentrator design based on graded period multilayer coatings

It is shown that compact designs of multifocus, conical approximations to highly nested Wolter I telescopes, as well as single reflection concentrators, employing realistic graded period W/Si or Ni/C multilayer coatings, allow one to obtain more than 1000 cm² of on-axis effective area at 40 keV and up to 200 cm² at 100 keV. The degree of concentration is defined by a focusing factor i.e., the effective area divided by the half power focal area. For the cases studied, this is 400 at 40 keV and 200 at 100 keV for a 2 arcmin imaging resolution. This result is quite insensitive to the specifics of the telescope configuration provided that mirrors can be coated to an inner radius of 3 cm. Specifically we find that a change of focal length from 5 to 12 m affects the effective area by less than 10%. In addition the result is insensitive to the thickness of the individual mirror shell provided that it is smaller than roughly 1 mm. The design can be realized with foils as thin (0.4 mm) as used for ASCA and SODART or with closed, slightly thicker (1.0 mm) mirror shells as used for JET-X and XMM. The effect of an increase of the inner radius is quantified on the effective area for multilayered mirrors up to 9 cm. The calculated Field of View (full width at half maximum), ranges from 9 arcmin at 1 keV to 5 arcmin at 60 keV. Finally, the continuum sensitivity of the design assuming a signal to noise ratio of 5 and a 10% energy bandwidth has been calculated. For a balloon flight observation of 10⁴ sec. with a telescope having 2 arcmin imaging resolution the point source sensitivity is 3 · 10^–6 photons/cm²/s/keV up to 70 keV for a W/Si coated telescope and up to 100 keV for a Ni/C coated telescope. For a satellite observation time of 10⁵ sec and an imaging resolution of 1 arcmin the sensitivity is 10^–7 photons/cm²/s/keV which demonstrates the great potential of this hard X-ray imaging telescope in the energy range up to 100 keV.     

Observation-based evaluation of surface wave effects on currents and trajectory forecasts

Knowledge of upper ocean currents is needed for trajectory forecasts and is essential for search and rescue operations and oil spill mitigation. This paper addresses effects of surface waves on ocean currents and drifter trajectories using in situ observations. The data set includes colocated measurements of directional wave spectra from a wave rider buoy, ocean currents measured by acoustic Doppler current profilers (ADCPs), as well as data from two types of tracking buoys that sample the currents at two different depths. The ADCP measures the Eulerian current at one point, as modelled by an ocean general circulation model, while the tracking buoys are advected by the Lagrangian current that includes the wave-induced Stokes drift. Based on our observations, we assess the importance of two different wave effects: (a) forcing of the ocean current by wave-induced surface fluxes and the Coriolis–Stokes force, and (b) advection of surface drifters by wave motion, that is the Stokes drift. Recent theoretical developments provide a framework for including these wave effects in ocean model systems. The order of magnitude of the Stokes drift is the same as the Eulerian current judging from the available data. The wave-induced momentum and turbulent kinetic energy fluxes are estimated and shown to be significant. Similarly, the wave-induced Coriolis–Stokes force is significant over time scales related to the inertial period. Surface drifter trajectories were analysed and could be reproduced using the observations of currents, waves and wind. Waves were found to have a significant contribution to the trajectories, and we conclude that adding wave effects in ocean model systems is likely to increase predictability of surface drifter trajectories. The relative importance of the Stokes drift was twice as large as the direct wind drag for the used surface drifter.