Newly Discovered Fish Faunas from the Early Triassic, Karoo Basin, South Africa, and their Correlative Implications

Recent collecting in exposures of the lowermost Burgersdorp Formation (Beaufort Group), of the Karoo Basin of South Africa, has revealed a previously unknown fish fauna from the Early Triassic (Scythian), lowermost Cynognathus Assemblage Zone (CAZ), which forms an important component of the total vertebrate assemblage. The newly discovered fish material includes lungfish, saurichthyids, and a large microfauna that includes numerous isolated chondrichthyan teeth, two fin spine fragments, and actinopterygian scales and teeth. The latest fish finds, together with the lowermost Cynognathus Assemblage Zone vertebrate faunas, make this Karoo Basin Assemblage Zone one of the most diverse Early Triassic faunal assemblages, comparable in faunal diversity to those from the Czatkowice Formation (Poland) and the Arcadia Formation (Australia). The presence of the lungfish Ptychoceratodus phillipsi in the early Middle Triassic Cynognathus Assemblage Zone (Subzone B), and in the underlying latest Early Triassic Cynognathus Assemblage Zone (Subzone A), indicates that these lungfish could serve as range index fossils within the CAZ, and thus are potentially useful biostratigraphic markers across the Early-Middle Triassic boundary. Furthermore the ‘new’ fish fauna provides a vital marine realm link in particular with the faunas of Madagascar and Australia, that is unavailable using the tetrapod faunal elements of the lower CAZ.     

Effect of broken clouds on satellite-based columnar water vapor retrieval

We investigate the effect of broken clouds on the satellite-based retrieval of columnar water vapor using a near-infrared radiance ratio technique. A typical difference between the retrieval using only pixels directly illuminated by the Sun and pixels with mixed illumination containing direct sunlight as well as cloud shadows is found to be within 3%.     

Scheme for development of monitoring networks for springs in Bavaria, Germany

The present groundwater monitoring network in Bavaria consists mostly of wells and only a small number of natural groundwater springs, all of which are analyzed for mainly the common physical and chemical constituents in groundwater. In order to develop a long-term groundwater management plan for all the groundwater resources of Bavaria, the Bavarian State Office for Water Management intends to establish a separate spring-monitoring network throughout the 11 groundwater provinces of the state. As a first step, significant physicochemical parameters that show considerable annual fluctuation (after monitoring 1–3 years) were determined at 21 springs or spring systems to create a basic data set to guide future monitoring. A selection procedure was developed around four parameters: (1) geological units, which includes the principal aquifers; (2) rate of spring discharge; (3) land utilization within a catchment; and (4) approximate size of the subterranean catchment. However, in the initial phase of the study, only the first three parameters were investigated. These parameters established a matrix for evaluating each groundwater region of Bavaria to aid in the selection of additional springs for the proposed monitoring network. Electronic Publication     

Fate of organic carbon reaching the deep sea floor: a status report

The rates of organic carbon oxidation by O₂, NO₃^?, MnO₂, Fe₂O₃ and SO₄^? have been calculated for five pelagic Pacific and Atlantic sites using simple diffusion-reaction models. O₂ everywhere oxidizes > 90% of the raining C_org; the fraction oxidized by the secondary oxidants decreases as the rain rate of organic C to the seafloor decreases. A large fraction of the C_org escaping oxidation by O₂ is oxidized by the secondary oxidants. Hence while these oxidants play a small role in remineralization, they are important in regulating the burial of organic matter and the consequent removal from the oceans of reduced carbon and nutrients.     

A multivariate design framework for river confluences

ABSTRACT

Throughout the last decade copula functions were widely used to assess a wide range of hydrological problems, often focusing on two distinct variables. In many of these studies it was ignored whether the two variables of interest actually occurred simultaneously (e.g. two annual maximum time series were analysed in a multivariate statistical framework). Here we introduce a novel approach to derive bivariate design events using copula functions allowing both simultaneous and non-simultaneous occurrence of the variables to be modelled. The methodology is exemplarily applied to assess the combined flood occurrence at the confluence of the rivers Rhine and Sieg (Germany). The results underline the validity of the methodology. Employing a hydrodynamic numerical model furthermore shows that commonly used statistical approaches to select a single design event out of a vast number of possible combinations can be critical for practical design purposes.

Editor Z.W. Kundzewicz; Associate editor S. Grimaldi     

Multiproxy analysis of a new terrestrial and a marine Cretaceous-Paleogene (K-Pg) boundary site from New Zealand

An integrated study of palynology, Mössbauer spectroscopy, mineralogy and osmium isotopes has led to the detection of the first K-Pg boundary clay layer in a Southern Hemisphere terrestrial setting. The K-Pg boundary layer was independently identified at centimetre resolution by all the above mentioned methods at the marine K-Pg boundary site of mid-Waipara and the terrestrial site of Compressor Creek (Greymouth coal field), New Zealand. Mössbauer spectroscopy shows an anomaly of Fe-containing particles in both K-Pg boundary sections: jarosite at mid-Waipara and goethite at Compressor Creek. This anomaly coincides with a turnover in vegetation indicated by an interval dominated by fern spores and extinction of key pollen species in both sections. In addition to the terrestrial floristic changes, the mid-Waipara section reveals a turnover in the dinoflagellate assemblages and the appearance of global earliest Danian index species. Geochemical data reveal relatively small iridium enrichments in the boundary layers of 321 pg/g at mid-Waipara and 176 pg/g at Compressor Creek. Unradiogenic ¹⁸⁷Os/¹⁸⁸Os values of the boundary clay reveal the presence of a significant extraterrestrial component. We interpret the accumulation of Fe nano-phases at the boundary as originating from both the impactor and the crystalline basement target rock. The goethite and jarosite are interpreted as secondary phases formed by weathering and diagenesis. The primary phases were probably controlled by the initial composition of the vapor plume and condensation kinetics rather than condensation thermodynamics. This investigation indicates that identification of Fe in nano-phases by Mössbauer spectroscopy is an accurate and cost-effective method for identifying impact event horizons and it efficiently complements widely used biostratigraphic and geochemical methods.     

Remediation of coal-mine drainage by a sulfate-reducing bioreactor: A case study from the Illinois coal basin,USA

This study reports changes in coal-mine drainage constituent concentrations through an anaerobic SO₄-reducing bioreactor monitored over a 3-a period. The purpose of the study was to identify and monitor over time the biogeochemical mechanisms that control the attenuation of toxic compounds in the mine drainage. This information is needed to investigate bioreactor performance and longevity. The water treated at the case example site, the Tab-Simco Mine, was highly acidic with an average pH of 2.9, a net acidity of 1674 mg/L CaCO₃ equivalent-CCE, and high levels of dissolved ${\text{SO}}_4^{2-}$, Al, Fe and Mn. The results of this study indicated that the treatment system increased the pH of the acid mine drainage (AMD) to 6.2 and decreased the median acidity to 22.7 mg/L CCE, ${\text{SO}}_4^{2-}$ from 2981 to 1750 mg/L, Fe from 450.6 to 1.76 mg/L, Al from 113 to 0.42 mg/L, and Mn from 36.4 to 23.3 mg/L. Geochemical modeling indicates that the bioreactor discharge is saturated with respect to the minerals alunite, gibbsite, siderite, rhodochrosite, jarosite, and Fe hydroxide precipitates. The observed trends also include seasonal variations in ${\text{SO}}_4^{2-}$ reduction and a general decline in the amount of alkalinity produced. The average δ³⁴S value of the ${\text{SO}}_4^{2-}$ in the untreated AMD was +7.3‰. In the bioreactor, δ³⁴S value of ${\text{SO}}_4^{2-}$ increased from an average of +6.9‰ to +9.2‰, suggesting the presence of bacterial SO₄ reduction processes. Preliminary results of a bacterial community analysis show that DNA sequences corresponding to bacteria capable of SO₄ reduction were present in the bioreactor outflow sample. However, these sequences were outnumbered by sequences similar to bacteria capable of reoxdizing reduced sulfur species. This study illustrates the dynamic nature of metal removal in SO₄-reducing bioreactor-based treatment systems.