Rapid fish stock depletion in previously unexploited seamounts: the case of Beryx splendens from the Sierra Leone Rise (Gulf of Guinea)

Fish stocks associated with seamounts may be particularly susceptible to overexploitation. From January to July 2001, the Spanish Oceanographic Institute (IEO) conducted an experimental fishing survey entitled ‘Palguinea-2001’ on the seamounts of the Sierra Leone Rise. Beryx splendens (commonly called alfonsino) is the main commercial demersal fish associated with this area. The aim of this study was to investigate the effects of a demersal longline fishery targeting B. splendens on the previously unexploited small Machucambo Seamount over a short time-scale, and also to consider trends in pooled catch rate at another four seamounts. During 110 fishing days at Machucambo, a total catch of 207 tonnes of B. splendens was taken with a fishing effort of 1 309 070 hooks. A spectral analysis and red-noise spectra procedure (REDFIT) algorithm was used to identify the red-noise spectrum from the gaps in the observed time-series of catch per unit effort by weight. Our results show the potential impact of longline fishing pressure on an unexploited ecosystem – after approximately 50 fishing days, the stock appeared to decline substantially, as reflected by a marked drop in catch per unit effort. The apparent rapid decline of the stock might be related to the small size and the virgin state of the Sierra Leone seamounts. The results could be extrapolated to similar small seamounts elsewhere.     

Zeta potential of single and polymer-coated microbubbles using an adapted microelectrophoresis technique

The zeta potential of microbubbles, generated by injecting pressurised air into water and then releasing the pressure, was determined in the absence and presence of different polyacrylamides. Air was dissolved in either water or solutions of cationic, anionic, amphoteric or nonionic polymers at a constant pressure of four atmospheres. The charge of the bubbles at the shear-zeta plane was measured using a modified microelectrophoresis glass cell, held at a stationary level, at varying pH (2.0–12.0). Known practical problems with this technique were solved, and these solutions are described in detail. The anionic, amphoteric and nonionic polymers increased the negative charge of the bubbles, but the isoelectric point (iep) remained constant at about pH 2.0. Conversely, in the presence of the cationic polymer, the bubbles exhibited positive surface charges between pH 2.0 and 8.0 and an iep of pH 8.0. The results revealed the existence of an important interaction mechanism between air bubbles and polymeric macromolecules; neither this mechanism nor its practical implications have been reported in the literature to date, especially in the treatment of wastewater by flocculation followed by dissolved air flotation (DAF).     

Thermo-optical detection of defects and decarbonation in natural smithsonite

Natural hydrothermal ZnCO₃ crystal aggregates are nominally anhydrous phases with interfacial water, with substitutional divalent cations and decarbonation c. 300°C. All these common features must be involved during the experimental heating of a thermoluminescence (TL) glow curve up to 500°C: dehydration–dehydroxylation, phase transition and ion transition of point defects in Zn²⁺ positions. A representative specimen of natural smithsonite was analysed by X-ray fluorescence spectrometry, field emission scanning electron microscopy (FESEM) with a chemical probe of energy dispersive spectrometer, high temperature in situ X-ray diffraction, differential scanning calorimetry, differential thermal analyses coupled to thermogravimetry, TL, radioluminescence and high resolution spectra thermoluminescence (3DTL), to gain an overview of the spectra emission and defects linkages modified by heating from room temperature up to 500°C. The ZnCO₃ specimen contains minor amounts of Ca, Cu, Cr, Cd, Pb, Ce, Co, Ni, Mn and Fe. Under FESEM, it displays CaCO₃ clusters and oscillatory zoning distribution with lamellae ranging from Ca_0.11Zn_0.89 to Ca_0.19Zn_0.81. The analytical results suggest assignments of defects and processes to measured 3DTL emission bands, as follows: (1) peak at ~260°C, ~360 nm bonds, breaking during the thermal decarbonation process; (2) peak ~120°C, ~340 nm: non-bridging oxygen centres associated to a complex dehydration–dehydroxylation process and (3) peak at ~170°C, ~650 nm, crystal field effects on the thermoluminescence of Mn²⁺ centres and associated transitional elements in the ZnCO₃ phase. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users.     

Interplay between detrital and diagenetic processes since the last glacial maximum on the northwest Iberian continental shelf

Integrated analyses of magnetic, geochemical and textural data on six cores from the northwestern Iberian continental shelf allowed the reconstruction of the paleoenvironmental evolution of this area since the last glacial maximum (LGM). Four sedimentary units were identified, representing a succession from fluvial and subaerial settings to high and finally low-energy marine deposits subsequent to the post-LGM sea-level rise. The uppermost unit was deposited during the Holocene and its magnetic properties were controlled by the interplay between detrital input and early diagenetic reductive dissolution of magnetic minerals. Identification of a primary steady-state early diagenetic signal allowed the recognition of periods of increased detrital input, bounded by intervals of lower detrital input and intensified reductive diagenesis related to intensified upwelling in the area. These paleoenvironmental alternations are consistent with the climatic evolution of the late Holocene. During the Roman Warm Period and Medieval Warm Period, the combined effect of greater humidity and intense agricultural and mining activities led to a greater erosion and transport of detrital sediments to the shelf. In contrast, enhanced diagenetic reduction intervals, caused by upwelling intensification, were roughly coincident with the colder Dark Ages and the Little Ice Age.     

Cosmic impact versus terrestrial origin of the Azuara structure (Spain): A review

Abstract— The Azuara structure is the largest one proposed so far in Spain as possibly related to a cosmic impact event. A review of the evidence set forward in favor of and against its cosmic origin indicates that the discussion is not yet finished. Some megascopic features (inverted stratigraphy, megabreccia, negative gravity anomalies) and shock‐metamorphic effects (planar deformational features) have been described in relation with the structure, although their real significance has been questioned and is still being debated. Comparison with other similar‐sized verified impacts suggests that unequivocal impactogenic features are yet to be found before the Azuara structure can be related to a cosmic impact. Until then, the Azuara structure should be considered as an unverified impact structure, and should not be included in global comprehensive maps of terrestrial impact structures.     

Evolution of temperature in granule and intergranular space

The temporal evolution of temperature in a dissolving granule and in an adjacent intergranular space is presented. The semi‐empirical evolutionary models have been calculated using an inversion method applied to 4‐min time series of Stokes I spectral line profiles. The models are presented in the form of the functional dependence of temperature T(log τ₅, t) on optical depth τ₅ at 500 nm and time t. The observed disappearance of the granule is accompanied with overall cooling of the granular photosphere. Temperature changes greater than 100 K have been found in deeper (log τ₅ ≥ 0) and upper layers (log τ₅ ≤ –2) whereas the intermediate layers are thermally stable. The intergranular space, which is 2 arcsec off the granule, keeps the temperature structure of the layers from log τ₅ = 0.5 to log τ₅ = –2 without global evolutionary changes except short‐term and spatially confined heating. Finally, the significant temperature changes in the upper layers (log τ₅ ≤ 2.5) observed during the time interval of 4 min are found to be typical for the granular and intergranular photosphere.     

Long-term perspective on the relationship between phytoplankton and nutrient concentrations in a southeastern Australian estuary

Sixteen years (1997–2013) of physicochemical, nutrient and phytoplankton biomass (Chlorophyll-a (Chl-a)) data and a decade (2003-2013) of phytoplankton composition and abundance data were analyzed to assess how the algal community in a temperate southeastern Australian estuary has responded to decreased chronic point source nitrogen loading following effluent treatment upgrade works in 2003. Nitrogen concentrations were significantly lower (P < 0.05) following enhanced effluent treatment and Chl-a levels decreased (P < 0.05) during the warmer months. Temperature and nutrient concentrations significantly influenced temporal changes of Chl-a (explaining 55% of variability), while salinity, temperature, pH and nutrient concentrations influenced phytoplankton abundance and composition (25% explained). Harmful Algal Bloom (HAB) dynamics differed between sites likely influenced by physical attributes of the estuary. This study demonstrates that enhanced effluent treatment can significantly decrease chronic point source nitrogen loading and that Chl-a concentrations can be lowered during the warmer months when the risk of blooms and HABs is greatest.     

Groundwater recharge in semi-arid carbonate aquifers under intensive use: the Estepa Range aquifers (Seville, southern Spain)

Quantifying groundwater recharge in carbonate aquifers located in semi-arid regions and subjected to intensive groundwater use is no easy task. One reason is that there are very few available methods suitable for application under such climatic conditions, and moreover, some of the methods that might be applied were originally designed with reference to non-carbonate aquifers. In addition, it is necessary to take into account the fact that, in any given aquifer, groundwater recharge is modified by the groundwater exploitation. Here we focus on four methods selected to assess their suitability for estimating groundwater recharge in carbonate aquifers affected by intensive exploitation. The methods were applied to the Estepa Range aquifers of Seville, southern Spain, which are subjected to different degrees of exploitation. Two conventional methods were used: chloride mass balance and daily soil–water balance. These results were compared with the results obtained by means of two non-conventional methods, designed for application to the carbonate aquifers of southern Spain: the APLIS and ERAS methods. The results of the different methods are analogous, comparable to those obtained in nearby non-exploited carbonate aquifers, confirming their suitability for use with carbonate aquifers in either natural or exploited regimes in a semi-arid climate.     

DAF–dissolved air flotation: Potential applications in the mining and mineral processing industry

Conventional and non-conventional flotation for mineral processing and for water (and wastewaters) treatment and reuse (or recycling) is rapidly broadening their applications in the mining field. Conventional flotation assisted with microbubbles (30–100 μm) finds application in the recovery of fine mineral particles (< 13 μm) and flotation with these fine bubbles is being used as a solid/liquid separation to remove pollutants. The injection of small bubbles to conventional coarse bubbles flotation cells usually leads to general improvements of the separation parameters, especially for the ultrafines (< 5 μm) ore particles. Results obtained are believed to occur by enhancing the capture of particles by bubbles, one of the main drawbacks in fine ore flotation. It is believed that by decreasing the bubble size distribution (through the injection of small bubbles), increases the bubble surface flux and the fines capture. DAF or dissolved air flotation with microbubbles, treating water, wastewater and domestic sewage is known for a number of years and is now gradually entering in the mining environmental area. This technology offers, in most cases, advantages over settling, filtration, precipitation, or adsorption onto natural and synthetic adsorbents. The targets are the removal of oils (emulsified or not), ions (heavy metals and anions) and the reuse or recirculation of the process waters. Advantages include better treated water quality, rapid start up, high rate operation, and a thicker sludge. New applications are found in the mining vehicles washing water treatment and reuse, AMD (acid mining drainage) neutralization and high rate solids/water separation by flotation with microbubbles. This work reviews some recent applications of the use of microbubbles to assist the recovery of very small mineral particles and for the removal of pollutants from mining wastewaters. Emphasis is given to the design features of innovative devices showing the potential of conventional and unconventional DAF flotation.     

Rainfall events and climate change in Mediterranean environments: an alarming shift from resource to risk in Eastern Spain

Natural Hazards - Consequences of climate change in Mediterranean environments are difficult to predict, partly because daily data do not fit with the timescale of Mediterranean processes, and...