CUTLASS observations of a high-m ULF wave and its consequences for the DOPE HF Doppler sounder

The CUTLASS (Co-operative UK Twin Located Auroral Sounding System) Finland HF radar, whilst operating in a high spatial and temporal resolution mode, has measured the ionospheric signature of a naturally occurring ULF wave in scatter artificially generated by the Tromsø Heater. The wave had a period of 100 s and exhibited curved phase fronts across the heated volume (about 180 km along a single radar beam). Spatial information provided by CUTLASS has enabled an m-number for the wave of about 38 to be determined. This high-m wave was not detected by the IMAGE (International Monitor for Auroral Geomagnetic Effects) network of ground magnetometers, as expected for a wave of a small spatial scale size. These observations offer the first independent confirmation of the existence of the ground uncorrelated ULF wave signatures previously reported in measurements recorded from an HF Doppler sounder located in the vicinity of Tromsø. These results both demonstrate a new capability for geophysical exploration from the combined CUTLASS-EISCAT ionospheric Heater experiment, and provide a verification of the HF Doppler technique for the investigation of small scale ULF waves.     

The seismic velocity distribution in the vicinity of a mine tunnel at Thabazimbi, South Africa

Analysis of the refracted arrivals on a seismic reflection profile recorded along the wall of a tunnel at an iron mine near Thabazimbi, South Africa, shows variations in P-wave velocity in dolomite away from the de-stressed zone that vary between 4.4 and 7.2 km/s, though values greater than 5.8 km/s predominate along most of the profile. The seismic velocities at the tunnel wall, however, vary between 4.2 and 5.2 km/s. Time–depth terms are in the range from 0.1 to 0.9 ms, and yield thicknesses of the zone disturbed by the tunnel excavations of between 2 and 9 m. The very low seismic velocities away from the tunnel wall in two regions are associated with alcoves or ‘cubbies’ involving offsets in the wall of up to 10 m. The large variations in seismic velocity resolved over distances less than 15 m with signals of wavelength around 6–9 m are attributed to variations in the sizes and concentrations of fracture systems and cracks, and in the degree of groundwater saturation of the fracture systems. The results suggest that seismic velocity variations from reflection surveys may also assist modelling studies of the stress regime in deep mines, particularly if both P and S wave velocity variations can be determined. The seismic velocity variations inferred also show that application of refraction static corrections in the processing of ‘in-mine’ seismic reflection profiles is as important as in surface surveys, because of the higher frequencies of the seismic energy recorded in the deep mine environment.     

Techniques for the Determination of Cyanide in a Process Environment: A Review

The determination of cyanide in various forms is important for industrial processes as well as for environmental investigations and monitoring associated with these processes. The accurate determination of cyanide is difficult for various reasons. Depending on the pH of the solution, cyanide is present both in molecular form (HCN) and ionic form (CN). Furthermore, cyanide is a good complexing reagent and reacts with almost all cations resulting in complexes with widely varying properties, such as stabilities, solubilities and rates of reaction. Cyanide also breaks down in sunlight and air, so that sampling and sample treatment become very important aspects to consider in the methodologies. During the last fifty years the determination of cyanide has been approached from various angles and a myriad of methods has been developed for its determination. This study represents a survey of methods commonly used in industrial laboratories for the analysis of cyanide-containing solutions. An overview of the nomenclature often used for the various forms of cyanides is discussed and the values resulting from a particular analysis will be interpreted. Most common interferences in samples originating from gold processing plants will be discussed.     

Pathology of fathead minnows (Pimephales promelas) exposed to chlorine dioxide and chlorite.

Fathead minnows (Pimephales promelas) were exposed to the biocide chlorine dioxide (0.13 and 0.19 mg l-1) for up to 12 h and to its primary decomposition product, chlorite (177 and 304 mg l-1), for up to 96 h followed by recovery periods of up to 14 days. Chlorine dioxide exposure produced dose-dependent gill pathology including epithelial lifting, hypertrophy, hyperplasia, lamellar fusion, and necrosis. Complete recovery, even in fish with severe hypertrophy and lamellar fusion, was achieved within 4 days. Chlorite did not produce gill pathology even at a lethal exposure level (304 mg l-1 for 96 h) but did elicit a chronic inflammatory response with a marked increase in circulating and fixed phagocytes within hematopoietic and vascular tissues. This study indicates that chlorine dioxide is approximately 1000 times more toxic to fathead minnows than chlorite. Further, exposure of fathead minnows to these distinct but related compounds is consistently associated with very different pathologies.     

Radar interferometry time series analysis of Mashhad subsidence

A large agricultural area located in 20 km north of the city of Mashhad in the north-east of Iran is subject to land subsidence. The subsidence rate was achieved in a couple of sparse points by precise leveling between 1995 and 2005, and continuous GPS measurements obtained from 2005 to 2006. In order to study the temporal behavior of the deformation in high spatial resolution, the small baseline subset (SBAS) algorithm was used to generate the interferometric SAR time series analysis. Time series analysis was performed using 19 interferograms calculated from 12 ENVISAT ASAR data spanning between 2003 and 2006. The time series results exhibited that the area is subsiding continuously without a significant seasonal effect. Mean LOS deformation velocity map obtained from time series analysis demonstrated a considerable subsidence rate up to 24 (cm/yr). In order to evaluate the time series analysis results, continuous GPS measurements as a geodetic approach were applied. The comparisons showed a great agreement between interferometry results and geodetic technique. Moreover, the information of various piezometric wells distributed in the area corresponding to 1995 to 2005 showed a significant decline in water table up to 20 meters. The correlation between the piezometric information and the surface deformation at well’s locations showed that the subsidence occurrence in Mashhad is due to the excess groundwater withdrawal.     

An unusual occurrence of coesite at the Lonar crater,India

Coesite has been identified within ejected blocks of shocked basalt at Lonar crater, India. This is the first report of coesite from the Lonar crater. Coesite occurs within SiO₂ glass as distinct ~30 μm spherical aggregates of “granular coesite” identifiable both with optical petrography and with micro‐Raman spectroscopy. The coesite+glass occurs only within former silica amygdules, which is also the first report of high‐pressure polymorphs forming from a shocked secondary mineral. Detailed petrography and NMR spectroscopy suggest that the coesite crystallized directly from a localized SiO₂ melt, as the result of complex interactions between the shock wave and these vesicle fillings.     

Adaptive model of plankton dynamics for the North Atlantic

Plankton ecosystems in the North Atlantic display strong regional and interannual variability in productivity and trophic structure, which cannot be captured by simple plankton models. Additional compartments subdividing functional groups can increase predictive power, but the high number of parameters tends to compromise portability and robustness of model predictions. An alternative strategy is to use property state variables, such as cell size, normally considered constant parameters in ecosystem models, to define the structure of functional groups in terms of both behaviour and response to physical forcing. This strategy may allow us to simulate realistically regional and temporal differences among plankton communities while keeping model complexity at a minimum.We fit a model of plankton and DOM dynamics globally and individually to observed climatologies at three diverse locations in the North Atlantic. Introducing additional property state variables is shown to improve the model fit both locally and globally, make the model more portable, and help identify model deficiencies. The zooplankton formulation exerts strong control on model performance. Our results suggest that the current paradigm on zooplankton allometric functional relationships might be at odds with observed plankton dynamics. Our parameter estimation resulted in more realistic estimates of parameters important for primary production than previous data assimilation studies.Property state variables generate complex emergent functional relationships, and might be used like tracers to differentiate between locally produced and advected biomass. The model results suggest that the observed temperature dependence of heterotrophic growth efficiency [Rivkin, R.B., Legendre, L., 2001. Biogenic carbon cycling in the upper ocean: effects of microbial respiration. Science 291 (5512) 2398-2400] could be an emergent relation due to intercorrelations among temperature, nutrient concentration and growth efficiency. A major advantage of using property state variables is that no additional parameters are required, such that differences in model performance can be directly related to model structure rather than parameter tuning.     

Compositional differences in enstatite chondrites based on carbon and nitrogen stable isotope measurements

Carbon and nitrogen abundance and isotopic compositions, from four EH4, one EH5, five EL6 chondrites and one aubrite, were determined by using stepped pyrolysis (N only) and combustion (N and C) extractions in attempts to distinguish the components present. Carbon contents range from 0.15 to 0.70 wt%, with no systematic relationship between carbon content and meteorite group or petrologic type. Whole-rock δ¹³C values range from −28.5 to −4.1 %., Most C occurs as graphite and when temperature steps above 700°C are considered, there is a difference between EH4,5 (δ¹³C = −9.1 to -5.8%.) and EL6 chondrites (δ¹³C = −6.7 to +4.2%.). Carbon in Bustee aubrite is isotopically lighter (δ¹³C = −24%.) than in any enstatite chondrite.

Nitrogen occurs as osbornite, sinoite and in isostructural substitution for oxygen in silicate lattice sites. Nitrogen abundances and isotopic compositions are more variable than C, due to the heterogenous distribution of N-bearing minerals. Three EL6's containing osbornite have higher N concentrations than other type 6 enstatite chondrites. Sinoite, where present, is depleted in ¹⁵N relative to osbornite. Nitrogen in the Bustee aubrite has a similar abundance and δ¹⁵N value to those of EL6's, again dominated by the presence of osbornite.

In addition to the refractory C-and N-bearing minerals there is also organic material (largely terrestrial contamination) and evidence for at least two “exotic” components. The first is a host for Xe (HL) and is characterized by δ¹³C <-−47%. and δ¹⁵N ≤−73%., whereas the second is less well-defined, but is marked by δ¹⁵N = +269%.