The importance of dissolved organic compounds in the accumulation of copper by the american oyster,crassostrea virginica

The influence of various dissolved organic compounds upon copper accumulation by the American oyster, Crassostrea virginica was examined. Oysters were exposed to a range of copper concentrations (^64Cu) in the presence of filtered estuarine water (FEW), UV-photooxidized FEW and FEW amended with the additions of natural dissolved organic compounds—chitin and cellular orgaanic compounds (derived from the diatom, Thalassiosira pseudonana). Copper accumulation rates were significantly greater in the UV-treated medium and decreased with the addition of dissolved organics. When normalized on a per weight DOC basis, the reductions in copper accumulation rates were greater in the presence of chitin than cellular organic compounds. The results suggest that natural dissolved organics differ markedly with respect to their influence upon copper bioavailability.     

The subaqueous delta of the modern Huanghe (Yellow River)

The subaqueous delta of the Huanghe (Yellow River) has been studied using high-resolution acoustic systems. There are many subtle variations in sea floor morphology and sediment geometries; smooth, featureless areas are rare. The main components of the subaqueous delta include broad, shallow channels; moderately disturbed areas with near-surface cut and fill structures; heavily disturbed areas with sea floor depressions, pits, and gullies; and a smooth, gently sloping distal delta apron or rise. These features are not directly related to sediment settling from dilute surface plumes but are due to gravity-driven hyperpycnal underflows, submarine mass movements, and silt flows.     

P wave amplitude measurements at the Kaapvaal network: do they help in resolving deep earth structure?

Measurements of the amplitudes of seismic body waves at teleseismic distances have rarely resolved significant features mainly because of the large scatter of the data. However, amplitudes are easy to measure and may provide additional constraints on structure to supplement times and waveforms. A new approach to analysing body wave amplitudes at a regional network of similar instruments seeks to minimize scatter by first deriving amplitude station corrections analogous to station corrections for times. After correction for station effects, amplitudes from several events can be combined to give regional amplitude–distance curves without using information on event magnitudes. However, the earthquakes providing the observations must lie in a restricted range of azimuths from the stations of the network and provide considerable overlap in the range of distances between adjacent events, with no gaps in distance coverage. The advantages of the method are explored using P wave amplitudes from two sets of earthquakes in the Indonesian and South American regions recorded by the Kaapvaal network deployed across southern Africa. In the first example, high amplitudes near 88° distance suggest the presence of a small discontinuity at the top of D″ that causes constructive interference between the closely separated arrivals of a small triplication in the travel times. The second example, supplemented by calculations using synthetic data, shows how long-wavelength regional variations in amplitudes can be resolved to assist the interpretation of times and waveforms. However, the limited range of distances in the observations and lateral heterogeneities at any depths can result in bias or tilt of the amplitude–distance relationships. Constraining the depths of the structure causing the long-wavelength variations is a subject for future research.     

On the deterioration of icebergs in the marginal ice zone

Abstract

During the Labrador Ice Margin Experiment (LIMEX) of March‐April 1989, the International Ice Patrol (IIP) of the United States Coast Guard deployed two satellite‐tracked TIROS Arctic Drifter (TAD) platforms on two medium‐sized tabular icebergs. The icebergs were drifting in sea ice of about 9/10 concentration east of Newfoundland. These deployments were part of an experiment to examine differential sea‐ice/iceberg motion during spring conditions near the ice margin. Sea‐ice concentration and movement data were collected concurrently by other LIMEX investigators.

The TADs, deployed on 11 March 1989, were tracked using the ARGOS data collection and location system carried on two NOAA polar‐orbiting satellites of the TIROS family. For two months following the deployment, IIP periodically attempted to relocate the icebergs during routine aerial iceberg patrols. One of the TADs stopped transmitting on 23 April 1989 probably because of a major calving event that resulted in the TAD being crushed. As of 24 April the drift rate of the other TAD nearly doubled compared with its drift rate prior to that date, indicating that it had fallen off the iceberg and was floating on water. By 24 April there was no sea ice near either of the two icebergs.

The TAD data provide a unique datasetfor modelling the deterioration of icebergs while they emerge out of the marginal ice zone and travel in open water. It is shown that a good knowledge of the environmental conditions, pariicularly water temperature and sea state, are critical to model successfully the deterioration and calving of the two icebergs.     

Response to “Comment on ‘Otolith Microchemistry Reveals Substantial Use of Freshwater by Southern Flounder in the Northern Gulf of Mexico’” by Pedro Morais

Lowe et al. (Estuar Coast 34:630–639, 2011) used Sr/Ca in the otoliths of juvenile southern flounder (Paralichthys lethostigma) to demonstrate the importance of low-salinity habitats in the northern Gulf of Mexico during early life. While otolith cores indicated that most southern flounder originated in high-salinity environments (elevated Sr/Ca in otolith core) and moved into lower salinity habitats (decreased Sr/Ca outside of the otolith core), approximately one third of the sampled individuals had otolith core chemistry that indicated spawning or hatching in or near freshwater habitats (low Sr/Ca throughout the otolith). Morais (Estuar Coast 34:630–639, 2012) proposes a different interpretation: he suggests that the high Sr/Ca found in 68 % of juvenile otolith cores (and low Sr/Ca just outside of the core region) may be due to females hydrating their eggs in offshore (high-salinity) waters, with spawning, hatching, and egg/larval development all actually occurring in low-salinity environments (his “sea-run mother” hypothesis). While there is ample literature supporting the importance of maternal contributions to otolith microchemistry during vitellogenesis, it is our contention that such contributions ultimately depend on the ecology and reproductive physiology of each species. Further, a mass inshore migration of adult southern flounder during their spawning season is counter to the well-documented life history patterns for this species throughout its range. While we appreciate Morais' perspective, we continue to stand by the conclusion of our original paper.     

On the application of magnetic methods for the characterisation of space weathering products

Space weathering is now commonly accepted to modify the optical and magnetic properties of airless body regoliths throughout the Solar System. Although the precise formation processes are not well understood, the presence of ubiquitous sub-microscopic metallic iron (SMFe) grains in lunar soils and corresponding spectral analyses have explained both the unique optical and magnetic properties of such soils. More recently, a variety of ion irradiation, laser melting and vaporisation and impact experiments have been shown to reproduce these effects in the laboratory. Such experiments are crucial to the study of the formation of SMFe under controlled conditions. To date, more emphasis has been placed on optical analyses of laboratory samples, as these address directly the mineralogical interpretation of remote sensing data. However, the magnetic analyses performed on the Apollo and Luna samples have provided useful qualitative and quantitative evaluation of regolith metallic iron content. These techniques are reviewed here, demonstrated on pulsed laser irradiated olivine powder, and their utility for determining the quantity and size distribution of this metallic iron discussed. Ferromagnetic resonance, multi-frequency magnetic susceptibility, vibrating sample magnetometry and thermomagnetic measurements were carried out. Each showed trends expected for the conversion of paramagnetic Fe²⁺ in olivine to fine-grained Fe⁰, with some grains in the superparamagnetic size range. Although evidence for superparamagnetic iron was found, the quantity of sub-microscopic metallic iron produced in these experiments proved insufficient to make conclusive measurements of either the quantity or size distribution of this iron. Improvements to both the experimental and analytical procedures are discussed to better enable such measurements in the future.     

Pulsar PSR B2303+30: a single system of drifting subpulses, moding and nulling

Analyses of multiple pulse sequences of the pulsar PSR B2303+30 reveal two distinct emission modes. One mode (B) follows a steady even–odd pattern and is more intense. The second mode (Q) is characteristically weak, but has intermittent drift bands with a periodicity of approximately 3 P ₁/cycle, and nulls much more frequently than the B mode. Both modes occur with roughly equal frequency, and their profiles have a similar single-humped form with a slight asymmetry. Our observations and analyses strongly suggest that the subpulse drift rates in both modes are linked in a series of cycles, which can be modelled as relaxing oscillations in the underlying circulation rate.     

Facies in a Devonian‐Carboniferous volcanic fore‐arc succession,Campwyn Volcanics,Mackay district,central Queensland∗

The Middle Devonian to Early Carboniferous Campwyn Volcanics of coastal central Queensland form part of the fore‐arc basin and eastern flank of the volcanic arc of the northern New England Fold Belt. They consist of a complex association of pyroclastic, hyaloclastic and resedimented, texturally immature volcaniclastic facies associated with shallow intrusions, lavas and minor limestone, non‐volcanic siliciclastics and ignimbrite. Primary igneous rocks indicate a predominantly mafic‐intermediate parentage. Mafic to intermediate pyroclastic rocks within the unit formed from both subaerial and ?submarine to emergent strombolian and phreatomagmatic eruptions. Quench‐fragmented hyaloclastite breccias are widespread and abundant. Shallow marine conditions for much of the succession are indicated by fossil assemblages and intercalated limestone and epiclastic sandstone and conglomerate facies. Volcanism and associated intrusions were widely dispersed in the Campwyn depositional basin in both space and time. The minor component of silicic volcanic products is thought to have been less proximal and derived from eruptive centres to the west, inboard of the basin.