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排序方式: 共有117条查询结果,搜索用时 218 毫秒
1.
Brent L. Lewis Pamela D. Holt Steven W. Taylor Steven W. Wilhelm Charles G. Trick Alison Butler George W. Luther III 《Marine Chemistry》1995,50(1-4)
Thermodynamic stability constants have been estimated for the complexation of iron(III) with catecholate-type siderophores isolated from the marine bacterium Alteromonas luteoviolacea and from the marine cyanobacterium Synechococcus sp. PCC 7002. Stability constants were determined utilizing the “chelate scale” of Taylor et al. (1994). The scale is based upon a linear relationship between the reduction potentials and the pH-independent thermodynamic stability constants for known iron(III) complexes. Log K values for the alterobactin B ferric iron complex are 43.6 ± 1.5 at pH 8.2 and 37.6 ± 1.2 at pH 6, consistent with a shift from bis-catecholate to monosalicylate/monocatecholate iron coordination with decreasing pH. Synechococcus isolates PCC 7002 Nos. 1 and 3 formed iron(III) complexes with stability constants of approximately 38.1 ± 1.2 and 42.3 ± 1.5, respectively. The binding strengths of the iron(III) complexes examined in this study are quite high, suggesting that catecholate siderophores may play a role in the solubilization and biological uptake of iron in the marine environment. 相似文献
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R. Burrows I.A. Walkington N.C. Yates T.S. Hedges J. Wolf J. Holt 《Applied Ocean Research》2009,31(4):229-238
With concerns mounting over the UK’s energy future and the effects of climate change, it will soon become paramount that all viable sources of renewable energy are fully exploited. This study has examined the scope for reliable and fully predictable tidal electricity generation from the conjunctive operation of 5 major estuary barrages on the West Coast of the UK in an attempt to establish the potential scale of the extractable resources. Two levels of investigation have been undertaken: simple 0-D (‘two-tank’) modelling of barrage energy generation under different operational modes, using the hydraulic characteristics of turbine performance; and 2-D modelling of tidal hydrodynamics over a wide sea area in a computational grid incorporating the barrages with turbines and sluices. It has been demonstrated that more than 33TWh per year of electricity should be attainable, from 22GW of installed capacity, this representing close to 10% of present UK demand. 相似文献
7.
Gorka Merino Manuel Barange Julia L. Blanchard James Harle Robert Holmes Icarus Allen Edward H. Allison Marie Caroline Badjeck Nicholas K. Dulvy Jason Holt Simon Jennings Christian Mullon Lynda D. Rodwell 《Global Environmental Change》2012,22(4):795-806
Expansion in the world's human population and economic development will increase future demand for fish products. As global fisheries yield is constrained by ecosystems productivity and management effectiveness, per capita fish consumption can only be maintained or increased if aquaculture makes an increasing contribution to the volume and stability of global fish supplies. Here, we use predictions of changes in global and regional climate (according to IPCC emissions scenario A1B), marine ecosystem and fisheries production estimates from high resolution regional models, human population size estimates from United Nations prospects, fishmeal and oil price estimations, and projections of the technological development in aquaculture feed technology, to investigate the feasibility of sustaining current and increased per capita fish consumption rates in 2050. We conclude that meeting current and larger consumption rates is feasible, despite a growing population and the impacts of climate change on potential fisheries production, but only if fish resources are managed sustainably and the animal feeds industry reduces its reliance on wild fish. Ineffective fisheries management and rising fishmeal prices driven by greater demand could, however, compromise future aquaculture production and the availability of fish products. 相似文献
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Analysis of the mean wind, equivalent potential temperature and virtual potential temperature profiles observed by the National Center for Atmospheric Research (NCAR) Electra aircraft and obtained from dropwindsondes and ship-launched radiosondes were made in conjunction with synoptic observations to study the structure of the monsoon boundary layer over the Arabian Sea during MONEX 79. Comparison of mean profiles indicates the monsoon boundary layer to be much different from the trade wind boundary layer. Results confirm the existence of a boundary-layer jet known as East African or Somali Jet. Regions of multiple cloud layers at roughly the height of the capping inversion layer were associated with the jet. Regions in which a more well-mixed layer was observed showed a jet structure depressed in height. A free-jet surface-layer model appears to describe the mean wind structure of this jet observed during the present study and by others. An approximate balance of forces was found in the monsoon boundary layer between friction, advective acceleration, Coriolis and pressure gradient forces. Friction and advective acceleration terms were significant in the lower levels of the boundary layer. Forces in a typical trade wind boundary layer were found to be approximately one order of magnitude smaller than those observed in the monsoon boundary layer. 相似文献
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Observations from research ships which took part in the Indo-Soviet Monsoon Experiment of 1977 (MONSOON 77) and the International Monsoon Experiments (MONEX 79) over the central Arabian Sea and the north central Bay of Bengal were analyzed to study the mean wind and temperature structure of the monsoon boundary layer during active and break conditions. Mean profiles of wind speed and direction along with virtual potential temperature obtained by averaging data from several research ships during 1977 and 1979 indicate that onset conditions were associated with substantial increases in wind speed over the Arabian Sea and a shift to strong southwest flow. Monsoon onset was also characterized by near-neutral to slightly unstable temperature profiles in the lowest kilometer. Break conditions in 1977 in which the monsoon trough moved northward and substantial (5 mb) pressure rises were noted over the Arabian Sea show wind speeds typically decreasing from approximately 18 m s–1 during active conditions to roughly 8 m s –1. Temperature profiles during break conditions are similar to those observed in pre-monsoon conditions in that the boundary layer is observed to be generally much more stable up to 900 mb. Above 900 mb, profiles of virtual potential temperature show little variation.Analysis of latent and sensible heat fluxes during June 1977 calculated by the bulk aerodynamic method indicates values of latent heat flux during active conditions to be roughly two to three times larger than those during break conditions. Sensible heat flux shows an increase from approximately 20 to 80 W m –1 during the onset of the monsoon. Surface fluxes of water vapor indicate the importance of water vapor transport over the ship observation region in the central Arabian Sea during active conditions. Onset of the monsoon over the Arabian Sea is accompanied by an increase in the surface moisture flux by a factor of about two. Time histories of precipitable water show decreases of approximately 15% from active to break periods. 相似文献
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A method is reported for the production of synthetic porous sandstones containing cracks of known dimensions and geometry with respect to the matrix. A synthetic sandstone was manufactured from Sand cemented with an epoxy glue. The cracks of known geometry were introduced into the material in the manufacturing stage, by emplacing thin metallic discs in the Sand-epoxy matrix. These discs were chemically leached out of the consolidated porous sandstone. Acoustic anisotropy. and shear-wave splitting were observed in the synthetic sandstones. For the dry sample the observed angular dependence of the P- and S- wave velocities (at 100 kHz) compares well, qualitatively, with the theoretical models of Hudson and of Thomsen. Quantitatively, however, the experimental data fits Hudson's model better. For the case of a saturated sample the experimental results are in excellent agreement with Thomsen's model. Hudson's model, on the other hand, predicts a different angular dependence for P-waves. This demonstrates that the concept of fluid transfer between cracks and the ambient porosity can be a significant process. The results reported here are from the first successful experiment in which the theoretical models were tested on a porous material containing a known crack geometry. 相似文献