Oil-weathering behavior in Arctic environments

Oil-weathering processes in ice-free subarctic and Arctic waters include spreading, evaporation, dissolution, dispersion of whole-oil droplets into the water column, photochemical oxidation, water-in-oil emulsification, microbial degradation, adsorption onto suspended particulate material, ingestion by organisms, sinking, and sedimentation. While many of these processes also are important factors in ice-covered waters, the various forms of sea ice (depending on the active state of ice growth, extent of coverage and/or decay) impart drastic, if not controlling, changes to the rates and relative importance of different oil-weathering mechanisms. Flow-through seawater wave-tank experiments in a cold room at −35°C and studies in the Chukchi Sea in late winter provide data on oil fate and effects for a variety of potential oil spill scenarios in the Arctic. Time-series chemical weathering data are presented for Prudhoe Bay crude oil released under and encapsulated in growing first-year columnar ice through spring breakup.     

Lower Cambrian patch reefs and associated sediments: southern Labrador, Canada

The complex pattern of biological accretion, internal sedimentation, early lithification, and biological destruction, that characterizes modern reefs and many fossil reefs has been recognized in archaeocyathid-rich patch reefs of Lower Cambrian age in the Forteau Formation, southern Labrador. Patch reefs occur as isolated masses or complex associations of many discrete masses of archaeocyathid-rich limestone and skeletal lime sands, surrounded by well-bedded skeletal limestones and shales. Each reef is composed of many loafshaped mounds stacked on top of one another. The limestone of each mound comprises archaeocyathids and Renalcis or Renalcis-like structures in a matrix of argillaceous lime mud rich in sponge spicules, trilobite and salterellid skeletons. Numerous growth cavities roofed by pendant Renalcis-like organisms and Renalcis are partially to completely filled with geopetal sediment indicating that much of the matrix was deposited as internal sediment. Two stages of diagenetic alteration are recognized: (1) syn-depositional, which affected only the reefs, and (2) post-depositional, which affected both reefs and inter-reef sediments. On the sea floor reef sediments were pervasively cemented and fibrous carbonate was precipitated in intraskeletal and growth cavities. These limestones and cements as well as archaeocyathid skeletons, were subsequently bored by endolithic organisms. Later post-depositional subaerial diagenesis resulted first in dissolution of certain skeletons and precipitation of calcite cement above the water table, followed by extensive precipitation of pore-filling calcite below the water table. These carbonate reefs are similar in structure to the basal pioneer accumulations of much younger lower and middle Palaeozoic reefs. They did not develop into massive ‘ecologic’ reefs because archaeocyathids never developed the necessary large, massive, hemispherical skeletons. This occurrence indicates that reefs developed more or less coincident with, and not long after, the appearance of skeletal metazoans in the Lower Cambrian.     

大数据驱动下的数字古地理重建：现状与展望

古地理学是一门强数据依赖性学科,古地理重建作为古地理学的核心任务之一,着眼于研究地质历史时期地球表面的地理、生物、气候面貌及其演化规律。随着大数据时代的来临,海量古地理数据的不断积累和计算机技术的高速发展使得标准化、智能化的数字古地理重建成为可能。文章通过介绍国内外与古地理相关的代表数据库及团队,总结其优缺点,提出大数据驱动下的数字古地理重建核心思路:(1)建立标准化的古地理学知识体系;(2)建立开放互动、动态更新的古地理数据库,并利用机器阅读技术等拓展数据来源;(3)建立标准化的古地理学数据质量控制体系;(4)利用机器学习技术建立各类型古地理重建模型,深度挖掘数据;(5)以可实时更新的智能数字地图集或多维动画形式输出成果。     

Geochemistry and Intrusive History of the Ashland Pluton, Klamath Mountains, California and Oregon

The Ashland pluton is a calc-alkaline plutonic complex thatintruded the western Paleozoic and Triassic belt of the KlamathMountains in late Middle Jurassic time. The pluton comprisesa series of compositionally distinct magma pulses. The oldestrocks are hornblende gabbro and two-pyroxene quartz gabbro withinitial ⁸⁷Sr/⁸⁶Sr = 0{dot}7044, ¹⁸O = 8{dot}7%, and REE patternswith chondrite normalized La/Lu = 7. These units were followedby a suite of tonalitic rocks (La_N/Lu_N = 7) and then by a suiteof K₂O- and P₂O₅ rocks of quartz monzodioritic affinity (La_N/Lu_N= 13–21; La_N/Sm_N = 2{dot}4–3{dot}) The quartz monzodioriticrocks were then intruded by biotite granodiorite and granitewith lower REE abundances but more fractionated LREE(La_N/Lu_N= 13–19; La_N/Sm_N = 4{dot}3–6 and they, in turn,were host to dikes and bosses of hornblende diorite. The latestintrusive activity consisted of aplitic and granitic dikes.Combined phase equilibria and mineral composition data, indicateemplacement conditions of approximately P_total = 2{dot}3kb,P_H2O between 1{dot}5 and 2{dot}2 kb, and f_O2 between the nickel-nickeloxide and hematite-magnetite buffers. Successive pulses of magma display increasing SiO₂ togetherwith increasing ¹⁸O and decreasing initial ⁸⁷Sr/⁸⁶Sr. The isotopicdata are consistent with either (1) combined fractional crystallizationof andesitic magma and concurrent assimilation of crustal materialcharacterized by low Sr₁ and high (¹⁸O or, more probably, (2)a series of partial melting events in which sources were successivelyless radiogenic but richer in ¹⁸O Each intrusive stage displaysevidence for some degree of crystal accumulation and/or fractionalcrystallization but neither process adequately accounts fortheir compositional differences. Consequently, each stage appearsto represent a distinct partial melting or assimilation event. The P₂O₅-rich nature of the quartz monzodiorite suite suggestsaccumulation of apatite. However, the suite contains abundantmafic microgranitoid enclaves and most apatite in the suiteis acicular. These observations suggest that magma mixing affectedthe compositional variation of the quartz monzodiorite suite.Mass balance calculations are consistent with a simple mixingprocess in which P₂O₅-rich alkalic basalt magma (representedby the mafic microgranitoid enclaves) was combined with a crystal-poorfelsic magma (represented by the tonalite suite), yielding aquartz monzodioritic magma that then underwent differentiationby crystal fractionation and accumulation.     

Symplectitic augite: evidence for discontinuous precipitation as an exsolution mechanism in Ca-rich clinopyroxene

Abstract Part of the augite in the Artfjället gabbro consists of symplectitic intergrowths between augite and blebs or lamellae of orthopyroxene. Mineral compositions are consistent with formation of these symplectites by exsolution of orthopyroxene from magmatic augite at a temperature of ca . 900–1000°C. The microstructures indicate that the exsolution mechanism is discontinuous precipitation, whereby the boundary of an augite grain sweeps through a neighbouring augite, leaving the symplectite in its wake. The formation of this symplectitic augite is catalysed by the presence of an intergranular water-rich fluid phase, which promotes grain boundary mobility.     

Phase Petrology and Mineral Chemistry of Coexisting Amphiboles from Telemark, Norway

Electron microprobe analyses of coexisting amphiboles, garnet,and cordierite in specimens collected from a single outcropprovide the basis for phase diagrams thought to be representativeof fixed external conditions in the sillimanite zone. A projectionthrough the compositions of quartz and plagioclase is employedto characterize the mineral facies and to facilitate comparisonswith other metamorphic terrains. Limiting recalculations whichbracket the possible range of Fe⁺³ contents in calcic amphiboleanalyses by electron probe permit an additional projection throughthe composition of magnetite, a ubiquitous phase. From thesedata the apparent non-ideality exhibited by various combinationsof coexisting cumming-tonite, anthophyllite, gedrite, and calcicamphibole is explained by intracrystalline cation ordering.     

Interlobate ice-sheet dynamics during the Last Glacial Maximum at Whitburn Bay, County Durham, England

This research reconstructs ice-sheet processes operating during the Late Devensian in northeast England. The article assesses the lithostratigraphy of the Devensian glacial tills of Whitburn Bay, eastern County Durham, and presents the first detailed analysis of petrological, geochemical and biostratigraphical data to reconstruct lithostratigraphy, provenance and iceflow pathways. Two Devensian tractions tills (the Blackhall and Horden tills) are separated by a boulder pavement, pointing to a switch in ice-bed conditions and the production of a melt-out lag prior to deposition of the upper traction till, the Horden Till. The Blackhall Till contains Magnesian Limestone, Carboniferous Limestone, Whin Sill dolerite and Old Red Sandstone, suggesting a northwesterly source, probably from the Midland Valley and the Southern Uplands. The Horden Till contains erratics and heavy minerals derived from crystalline bedrock sources in the Cheviot Hills and northeast Scotland. Within the Horden Till are numerous sand, clay and gravel-filled canals incised downwards into the diamicton which are attributed to a low-energy, distributed, subglacial canal drainage system. Coupled with hydro-fractures and the boulder pavement, this suggests that a partially decoupled, fast-flowing ice stream deposited the Horden Till. The uphill, landward direction of ice movement indicates that the ice stream was confined in the North Sea Basin, possibly by the presence of Scandinavian Ice.