Latitudinal variation of measured O3 photolysis frequencies J(O1D) and primary OH production rates over the Atlantic Ocean between 50° N and 30° S

The latitudinal variation of the photolysis frequency of ozone to O(¹D) atoms, J(O¹D), was measured using a filter radiometer during the cruise ANT VII/1 of the research vessel Polarstern in September/October 1988. The J(O¹D) noon values exhibited a maximum of 3.6×10^-5 s^-1 (2 sr) at the equator and decreased strongly towards higher latitudes. J(O¹D) reached highest values for clean marine background air with low aerosol load and almost cloudless sky. The J(O¹D) data, measured under these conditions and a temperature of 295 K, can be expressed by: % MathType!MTEF!2!1!+-% feaafiart1ev1aaatCvAUfeBSjuyZL2yd9gzLbvyNv2CaerbuLwBLn% hiov2DGi1BTfMBaeXatLxBI9gBaerbd9wDYLwzYbItLDharqqtubsr% 4rNCHbGeaGqiVu0Je9sqqrpepC0xbbL8F4rqqrFfpeea0xe9Lq-Jc9% vqaqpepm0xbba9pwe9Q8fs0-yqaqpepae9pg0FirpepeKkFr0xfr-x% fr-xb9adbaqaaeGaciGaaiaabeqaamaabaabaaGcbaGaamOsaiaacI% cacaqGpbWaaWbaaSqabeaaiiaacqWF8baFaaGccaqGebGaaeykaiaa% bccacqWF9aqpcaqGGaGaaeyzaiaabIhacaqGWbGaaeiiaiaabUhacq% GHsislcaaI4aGaaiOlaiaaicdacaaIYaGaeyOeI0IaaGioaiaac6ca% caaI4aGaaiiEaiaaigdacaaIWaWaaWbaaSqabeaacqGHsislcaaIZa% aaaOGaaeiiaiaabIhacaqGGaGaam4uaiabgUcaRiaaiodacaGGUaGa% aGinaiaacIhacaaIXaGaaGimamaaCaaaleqabaGaeyOeI0IaaGOnaa% aakiaadofadaahaaWcbeqaaiaaikdaaaGccaGG9bGaaeikaiaaboha% daahaaWcbeqaaiabgkHiTiaaigdaaaGccaGGPaaaaa!5EE9!\[J({\text{O}}^| {\text{D) }} = {\text{ exp \{ }} - 8.02 - 8.8x10^{ - 3} {\text{ x }}S + 3.4x10^{ - 6} S^2 \} {\text{(s}}^{ - 1} )\] where S represents the product of the overhead ozone column (DU) and the secant of the solar zenith angle. The meridional profile of the primary OH radical production rate P(OH) was calculated from the J(O¹D) measurements and simultaneously recorded O₃ and H₂O mixing ratios. While the latitudinal distribution of J(O¹D) and water vapour was nearly symmetric to the equator, high tropospheric ozone levels up to 40 ppb were observed in the Southern Hemisphere, SH, resulting in higher P(OH) in the SH.     

Piloting a network of small telescopes

The Pilot Small Telescope Network (PSTN) is a state‐of the art system of easily replicable and scalable hardware, software, servers, eXtensible Markup Language (XML) protocols, and network middleware connecting and developing a pilot array of robotic telescopes to one another and the user community. The PSTN is a developmental project that will allow growing access to these telescopes, and make available data to faculty, students and others in an environment of collaboration. The underlying goal of the PSTN is to broaden the quantity and quality of astronomical education and research, particularly with a focus on traditionally underserved populations. (© 2006 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

A textural analysis of Wellington Harbour sediments

Grain‐size and carbonate analyses have been carried out on bottom sediment samples of Wellington Harbour. From grain‐size parameters it was possible to establish a number of facies types and to outline sediment sources and directions of transport.     

Using Web Maps to Analyze the Construction of Global Scale Cognitive Maps

Game-based Web sites and applications are changing the ways in which students learn the world map. In this study, a Web map-based digital learning tool was used as a study aid for a university-level geography course in order to examine the way in which global scale cognitive maps are constructed. A network analysis revealed that clicks were negatively correlated with familiarity, but were positively correlated with area. More significantly, well-known countries did not act as central nodes within network-based mental models, but served a more complex mediating role in structuring the space between subregions.     

Young eclogite from the Greater Himalayan Sequence,Arun Valley,eastern Nepal: P–T–t path and tectonic implications

Garnet geochronology was used to provide the first direct measurement of the timing of eclogitization in the central Himalaya. Lu–Hf dates from garnet separates in one relict eclogite from the Arun River Valley in eastern Nepal indicate an age of 20.7 ± 0.4 Ma, significantly younger than ultra-high pressure eclogites from the western Himalaya, reflecting either different origins or substantial time lags in tectonics along strike. Four proximal garnet amphibolites from structurally lower horizons are 14–15 Ma, similar to post-eclogitization ages published for rocks along strike in southern Tibet. P–T calculations indicate three metamorphic episodes for the eclogite: i) eclogite-facies metamorphism at ～ 670 °C and ≥ 15 kbar at 23–16 Ma; ii) a peak-T granulite event at ～ 780 °C and 12 kbar; and iii) late-stage amphibolite-facies metamorphism at ～ 675 °C and 6 kbar at ～ 14 Ma. The garnet amphibolites were metamorphosed at ～ 660 °C. Three models are considered to explain the observed P–T–t evolution. The first assumes that the Main Himalayan Thrust (basal thrust of the Himalayan thrust system) cuts deeper at Arun than elsewhere. While conceptually the simplest, this model has difficulty explaining both the granulite-facies overprint and the pulse of exhumation between 25 and 14 Ma. A second model assumes that (aborted) subduction, slab breakoff, and ascent of India's leading edge occurred diachronously: ～ 50 Ma in the western Himalaya, ～ 25 Ma in the central Himalaya of Nepal, and presumably later in the eastern Himalaya. This model explains the P–T–t path, particularly heating during initial exhumation, but implies significant along-strike diachroneity, which is generally lacking in other features of the Himalaya. A third model assumes repeated loss of mantle lithosphere, first by slab breakoff at ～ 50 Ma, and again by delamination at ～ 25 Ma; this model explains the P–T–t path, but requires geographically restricted tectonic behavior at Arun. The P–T–t history of the Arun eclogites may imply a change in the physical state of the Himalayan metamorphic wedge at 16–25 Ma, ultimately giving rise to the Main Central Thrust by 15–16 Ma.     

The influence of marine inflows on the chemical composition of groundwater in small islands: the example of the Cyclades (Greece)

 Marine contamination of groundwater may be caused by seawater intrusion and by salt spray. The role of both processes was studied in the Cyclades archipelago on four small islands (45–195 km²) whose aquifers consist essentially of fractured, weathered metamorphic rocks. Annual rainfall ranges from 400 to 650 mm and precipitation has high total dissolved solids contents of 45–223 mg l^–1. The chemical characteristics of the groundwater, whose salinity is from 0.4 to 22 g l^–1, are strongly influenced by seawater intrusion. However, the effect of atmospheric input is shown in certain water sampling locations on high ground elevation where the dissolved chloride contents may attain 200 mg l^–1. Received: 14 November 1995 · Accepted: 9 September 1996     

Diagenesis of vascular plant organic matter components during burial in lake sediments

Diagenetic changes are difficult to distinguish from variations in sources of organic matter to sediments. Organic geochemical comparisons of samples of wood, bark, and needles from a white spruce (Picea glauca) living today and one buried for 10,000 years in lake sediments have been used to identify the effects of diagenesis on vascular plant matter. Important biogeochemical changes are evident in the aged spruce components, even though the cellular structures of the samples are well preserved. Concentrations of total fatty acids dramatically diminish; unsaturated and shorter chainlength components are preferentially lost from the molecular distributions. Concentrations of total alcohols are similar in the modern and 10,000-year-old wood and bark but markedly lowered in the aged needles. Hydrocarbon concentrations and distributions show little diagenetic change in the 10,000-year-old plant materials. Cellulose components in the wood decrease relative to lignin components, although both types of materials remain in high concentration in comparison to other organic components. Aromatization of abietic acid proceeds more rapidly in buried spruce wood than in bark; retene is the dominant polyaromatic hydrocarbon in the aged wood. In contrast to the variety of changes evident in molecular compositions, neither ¹³C values nor C/N ratios differ significantly in the bulk organic matter of modern and aged spruce components.     

Structural Setting of Strong Earthquakes in the Huabei Area of China

— Using P and S arrival times, which occurred within the Huabei seismic network, we carried out a tomographic inversion and compared results with the earthquake catalogue of the last 1000?years in the area. The results are as follows:¶1) The hypocenters of most of the strong shocks are distributed in the transitional zones between high- and low-velocity areas in the crust, especially at edges of high-velocity blocks.¶2) Strong shocks predominantly lie above low-velocity blocks, or in transitional zones between low- and high-velocity areas, in the lower crust.¶3) The tectonic settings for the Tangshan and the Sanhe-Pingu earthquakes are similar. Both are not known near large fault belts, and in zones with a sharp lateral velocity gradient.¶4) The Ninghe, Tangshan and Luanxia earthquakes are located in high-velocity blocks that differ in size and depth. This difference can explain the focal depth distribution of the Tangshan earthquake sequence, i.e., earthquakes are shallower in the northeastern Luanxian area but deeper in the southwestern Ninghe area.