A measurement of the 362 GHz absorption line of Mars atmospheric H2O2

The 362.156 GHz absorption spectrum of H₂O₂ in the Mars atmosphere was observed on September 4 of 2003, employing the James Clerk Maxwell Telescope (JCMT) sub-millimeter facility on Mauna Kea, Hawaii. Radiative transfer analysis of this line absorption yields an average volume mixing ratio of 18±0.4 ppbv within the lower (0-30 km) Mars atmosphere, in general accordance with standard photochemical models (e.g., Nair et al., 1994, Icarus 111, 124-150). Our derived H₂O₂ abundance is roughly three times greater than the upper limit retrieved by Encrenaz et al. (2002, Astron. Astrophys. 396, 1037-1044) from infrared spectroscopy, although part of this discrepancy may result from the different solar longitudes (L_s) of observation. Aphelion-to-perihelion thermal forcing of the global Mars hygropause generates substantial (>200%) increases in HO_x abundances above ∼10 km altitudes between the L_s=112° period of the Encrenaz et al. upper limit measurement and the current L_s=250° period of detection (Clancy and Nair, 1996, J. Geophys. Res. 101, 12785-12590). The observed H₂O₂ line absorption weakens arguments for non-standard homogeneous (Encrenaz et al., 2002, Astron. Astrophys. 396, 1037-1044) or heterogeneous (Krasnopolsky, 2003a, J. Geophys. Res. 108; 2003b, Icarus 165, 315-325) chemistry, which have been advocated partly on the basis of infrared (8 μm) non-detections for Mars H₂O₂. Observation of Mars H₂O₂ also represents the first measurement of a key catalytic specie in a planetary atmosphere other than our own.     

Mapping of Io's thermal radiation by the Galileo photopolarimeter-radiometer (PPR) instrument

Between 1999 and 2002, the Galileo spacecraft made 6 close flybys of Io during which many observations of Io's thermal radiation were made with the photopolarimeter-radiometer (PPR). While the NIMS instrument could measure thermal emission from hot spots with T>200 K, PPR was the only Galileo instrument capable of mapping the lower temperatures of older, cooling lava flows, and the passive background. We tabulate all data taken by PPR of Io during these flybys and describe some scientific highlights revealed by the data. The data include almost complete coverage of Io at better than 250 km resolution, with extensive regional coverage at higher resolutions. We found a modest poleward drop in nighttime background temperatures and evidence of thermal inertia variations across the surface. Comparison of high spatial resolution temperature measurements with observed daytime SO₂ gas pressures on Io provides evidence for local cold trapping of SO₂ frost on scales smaller than the 60 km resolution of the PPR data. We also calculated the power output from several hot spots and estimated total global heat flow to be about 2.0-2.6 W m⁻². The low-latitude diurnal temperature variations for the regions between obvious hot spots are well matched by a laterally-inhomogeneous thermal model with less than 1 W m⁻² endogenic heat flow.     

Transport of ionizing radiation in terrestrial-like exoplanet atmospheres

The propagation of ionizing radiation through model atmospheres of terrestrial-like exoplanets is studied for a large range of column densities and incident photon energies using a Monte Carlo code we have developed to treat Compton scattering and photoabsorption. Incident spectra from parent star flares, supernovae, and gamma-ray bursts are modeled and compared to energetic particles in importance. Large irradiation events with fluences of 10⁶-10⁹ erg cm⁻² at the conventional habitable zone can occur at a rate from many per day (flares from young low-mass parent stars) to ∼100 per Gyr (supernovae and gamma-ray bursts). We find that terrestrial-like exoplanets with atmospheres thinner than about 100 g cm⁻² block nearly all X-rays, but transmit and reprocess a significant fraction of incident γ-rays, producing a characteristic, flat surficial spectrum. Thick atmospheres (?100 g cm⁻²) efficiently block even γ-rays, but nearly all the incident energy is redistributed into diffuse UV and visible aurora-like emission, increasing the effective atmospheric transmission by many orders of magnitude. Depending on the presence of molecular UV absorbers and atmospheric thickness, up to 10% of the incident energy can reach the surface as UV reemission. For the Earth, between 2×10⁻³ and 4×10⁻² of the incident flux reaches the ground in the biologically effective 200-320 nm range, depending on O₂/O₃ shielding. For atmospheres thicker than ∼50 g cm⁻² in the case of pure Rayleigh scattering and ∼100 g cm⁻² in the case of O₂/O₃ absorption, the UV reemission exceeds the surficial transmitted ionizing radiation. We also discuss the effects of angle of incidence and derive a modified two-stream approximation solution for the UV transfer. Finally, we suggest that transient atmospheric ionization layers can be frequently created at altitudes lower than the equilibrium layers that result from steady irradiation and winds from the parent star. We suggest that these events can produce frequent fluctuations in atmospheric ionization levels and surficial UV fluxes on terrestrial-like planets.     

Observations with the Visual and Infrared Mapping Spectrometer (VIMS) during Cassini's flyby of Jupiter

The Cassini Visual and Infrared Mapping Spectrometer (VIMS) is an imaging spectrometer covering the wavelength range 0.3-5.2 μm in 352 spectral channels, with a nominal instantaneous field of view of 0.5 mrad. The Cassini flyby of Jupiter represented a unique opportunity to accomplish two important goals: scientific observations of the jovian system and functional tests of the VIMS instrument under conditions similar to those expected to obtain during Cassini's 4-year tour of the saturnian system. Results acquired over a complete range of visual to near-infrared wavelengths from 0.3 to 5.2 μm are presented. First detections include methane fluorescence on Jupiter, a surprisingly high opposition surge on Europa, the first visual-near-IR spectra of Himalia and Jupiter's optically-thin ring system, and the first near-infrared observations of the rings over an extensive range of phase angles (0-120°). Similarities in the center-to-limb profiles of H⁺₃ and CH₄ emissions indicate that the H⁺₃ ionospheric density is solar-controlled outside of the auroral regions. The existence of jovian NH₃ absorption at 0.93 μm is confirmed. Himalia has a slightly reddish spectrum, an apparent absorption near 3 μm, and a geometric albedo of 0.06±0.01 at 2.2 μm (assuming an 85-km radius). If the 3-μm feature in Himalia's spectrum is eventually confirmed, it would be suggestive of the presence of water in some form, either free, bound, or incorporated in layer-lattice silicates. Finally, a mean ring-particle radius of 10 μm is found to be consistent with Mie-scattering models fit to VIMS near-infrared observations acquired over 0-120° phase angle.     

Seasonal change in the deep atmosphere of Uranus

We present high-resolution radio maps of Uranus, made from data collected in 1994 at wavelengths of 2 and 6 cm, which show large-scale changes occurring deep and rapidly in the troposphere. Brightness features in these maps are significantly different from those observed throughout the 1980's. These differences are not due to the changing viewing geometry, but result from atmospheric changes in the 5 to 50 bar region. All the observations show strong latitudinal variations in absorber abundance and/or temperature, causing the South Pole to appear brighter than lower latitudes. The transition between bright pole and darker latitudes is always near −45°, but between 1989 and 1994 the contrast between the regions increased significantly. This suggests that the large-scale circulation in the upper 50 bars of the uranian Southern Hemisphere changed. Older, disk-averaged microwave observations have suggested that seasonal variability occurs, but these new maps are the first to provide detailed timing and location information which can be used to test dynamical models.     

FUSE Observations of EC14026 Stars

We present a FUSE abundance analysis of EC14026 stars. We compare the abundances of heavy elements in the atmospheres of EC14026 stars to non-pulsating stars with similar atmospheric parameters, and investigate whether weak stellar winds could explain the coexistence of variable and non-variable sdB stars in the log g – T_eff diagram. We also present preliminary results on time-dependent diffusion calculations of iron in presence of radiative levitation and mass loss, and show how weak stellar winds can affect the diffusive equilibrium between gravitational settling and radiative support.