Radiation Products in Processed Ices Relevant to Edgeworth-Kuiper-Belt Objects

Near the inner edge of the Edgeworth-Kuiper Belt (EKB) are Pluto and Charon, which are known to have N₂- and H₂O-dominated surface ices, respectively. Such non-polar and polar ices, and perhaps mixtures of them, also may be present on other trans-Neptunian objects. Pluto, Charon, and all EKB objects reside in a weak, but constant UV-photon and energetic ion radiation environment that drives chemical reactions in their surface ices. Effects of photon and ion processing include changes in ice composition, volatility, spectra, and albedo, and these have been studied in a number of laboratories. This paper focuses on ice processing by ion irradiation and is aimed at understanding the volatiles, ions, and residues that may exist on outer solar system objects. We summarize radiation chemical products of N₂-rich and H₂O-rich ices containing CO or CH₄, including possible volatiles such as alcohols, acids, and bases. Less-volatile products that could accumulate on EKB objects are observed to form in the laboratory from acid-base reactions, reactions promoted by warming, or reactions due to radiation processing of a relatively pure ice (e.g., CO → C₃O₂). New IR spectra are reported for the 1–5 mu;m region, along with band strengths for the stronger features of carbon suboxide, carbonic acid, the ammonium and cyanate ions, polyoxymethylene, and ethylene glycol. These six materials are possible contributors to EKB surfaces, and will be of interest to observers and future missions.     

A possible presence of HeH+ in white dwarfs

The equivalent width calculations for the fundamental vibration rotation band lines of HeH⁺ have been carried out for a non-DA white dwarf model with an effective temperature of 12 000 K. BothP andR branch lines with rotational quantum numbersJ=3 to 18 were included in the calculations. A search for these lines in helium rich white dwarfs is suggested.     

Die Entfernung von Cadmiumionen aus Spülwässern der galvanischen Industrie mittels Ionenaustausch

In laboratory investigations with model waters, the behaviour of selected cation-exchange resins (Amberlite 200 C, Duolite C-25, Lewatit S-100, Wofatit KPS and Wofatit KS-10) is tested. The usable volume capacity of the resins in the forms of H, Na and NH₄ as well as the water content and the total volume capacity after 25 cycles of loading/regeneration are determined. It is recommended to use Amberlite 200 C and Wofatit KS-10.     

A technique for calibration of monostatic echosounder systems

A calibration technique has been adapted to render complete system calibrations of high-frequency acoustical instrumentation. This is based on standard targets; specifically, precisely manufactured spheres composed of tungsten carbide with 6% cobalt binder. The use of multiple sphere sizes was found to be advantageous, both as an independent check of the calibrations, and so that resonances in the sphere responses at certain frequencies could be avoided. Complete system gains and beam patterns, which include effects of bandpass filters and finite-pulse lengths, were determined by moving the spheres individually in the transducer far-fields. Use of this procedure ensures control over the acoustical characteristics of transducers, which may change from the time of manufacture and first testing due, for example, to platform mounting. It also provides a direct means of measuring the sampling volume at relatively high and constant signal-to-noise ratios. Implementation of this technique is discussed using a multifrequency sonar system as an example     

Preparation,collisional decay and transfer of alignment in C2H2 21

Stimulated Raman scattering is used to prepare ensembles of aligned acetylene molecules in thev ₂=1 excited vibrational level. Decay and transfer of the alignment is followed by laser induced fluorescence. Measurements of the initially excited alignment agree well with theoretical calculations. The rate constants for decay decrease as the rotational quantum numberJ of the excited level increases.     

Solar radio burst (type III)

This article describes the observations of a type III radio burst observed at 103 MHz simultaneously by the two radio telescopes situated at Rajkot (22.3°N, 70.7°E) and Thaltej (23°N, 72.4°E). This event occurred on September 30, 1993 at about 0430 UT and lasted for only half a minute. The event consisted of several sharp spikes in a group. The rise and fall time of these are comparable, however the peaks of individual spikes varied by a factor of four. The comparison of these observations with the data of solar radio spectrograph HiRAS indicates that this was a metric radio burst giving highest emission at about 103 MHz.     

Measurements of the north polar cap of Mars and the Earth's northern hemisphere ice and snow cover

The boundaries of the polar caps of Mars have been measured on more than 3000 photographs since 1905 from the plate collection at the Lowell Observatory. For the Earth, the polar caps have been accurately mapped only since the mid 1960's when satellites were first available to synoptically view the polar regions. The polar caps of both planets wax and wane in response to changes in the seasons, and interannual differences in polar cap behavior on Mars as well as Earth are intimately linked to global energy balance. Data on the year to year variations in the extent of the north polar caps of Mars and Earth have been assembled and compared, although only 6 years of concurrent data were available for comparison.