CO2 transfer between the upper mantle and the atmosphere: temporary storage in the lower continental crust

The CO₂ atmospheric content has shown large variations over geological times. High contents (up to one order of magnitude more than present-day values) ultimately correspond to discrete episodes of mantle degassing, either juvenile, or subduction-related (carbon recycling). A number of arguments (e.g. the continuous volume increase of carbonate-bearing sediments with time) suggest that, throughout the Earth's history, juvenile CO₂ has formed a major contribution to the global carbon budget of the Earth.
The absence of a direct relationship between major volcanic episodes and the average CO₂ atmospheric content suggests that volcanoes might not be the only way by which mantle CO₂ is transported to the surface. It is proposed that large quantities of juvenile CO₂ could temporarily be stored in the lower continental crust during major episodes of granulite formation. These are primarily caused by magmatic underplating and they result in a vertical accretion of the crust by accumulation of CO₂-bearing, mantle-derived magmas. Most of the CO₂ migrates through the crust during post-metamorphic evolution and isostatic restoration of the normal continental thickness. However, large quantities of CO₂ can still be present in some areas, notably as high-density fluids enclosed in minerals.     

Stable isotope geochemistry and structural elements of the Sabina region (Central Apennines, Italy)

Various tectonic features are present in the Meso-Cenozoic basin units of the Sabina region (Central Apennines, Italy): Mio-Pliocene northeasterly verging thrusts are followed by Plio-Pleistocene, N-S oriented right-lateral strike-slip faults. Stable isotope geochemistry and examination of meso- and microstructures show that strain conditions differed through the course of tectonic history. Carbon and oxygen isotope analyses of the calate-filled extensional fractures, the sigmoidal veins present between stylolitic cleavage surfaces, and fault plane surfaces with differing motion, demonstrate those different geneses.
The "C/'" C of the older calcite-filling fractures (present both in the thrust and the strike-slip systems) suggests a deposition from shallow, fresh water circulation. Furthermore, the calcite fill of en echelon systems, that occur in the southernmost Plio-Pleistocene units, is clearly the result of a more recent, right-lateral strike-slip movement, connected with shallow water circulation within Mesozoic limestones.
The sigmoidal vein fills are derived from solid-state pressure solution processes which were the result of strike-slip movement. The deformation pattern related to the older thrust system is similar, but less intense; this also demonstrates general recrystallization processes in a closed system.
This suggests that the total shortening of the deformed sections is lower than that obtained on the basis of solution on stylolitic planes, because a sigruficant volume of dissolved carbonates remained in the system.
Stable isotope analysis also confirms that the deformational history of strongly cleaved rocks in the Sabina region took place in two phases and that extensional fractures formed before stylolithic planes, as suggested by structural and field observations.     

MAP MAKING FOR PROFIT AND PLEASURE

Some of the economic and operational aspects of mapping are discussed, including the conditions that may offer air survey a competitive advantage over other methods. The financing of national mapping programmes around the world is increasingly market oriented, driven by the need to provide the end users with information that they can turn into sustainable economic growth and social progress. Despite these economic pressures, map makers seem to find their work more enjoyable and rewarding than most professionals.     

Astrometry from space: GAIA and planet detection

The proposed baseline GAIA mission will be able to detect the astrometric signature of Jupiter-size planets around of the order of a million stars, using either global or narrow-angle astrometry. If the mission can realize the higher astrometric accuracy that photon statistics allows for bright stars, lower-mass planets (from Earth size to ten times larger) can be found around ten to a few hundred stars.     

Analytical and numerical analysis of the generalized Shkarofsky function

The main analytical properties of the generalized Shkarofsky function and a numerical code for its computation are discussed. The results of a numerical analysis are compared with the results of an asymptotic analysis for parameter values relevant to the problem of whistler-mode propagation in the Earth's magnetosphere. This comparison allows us to specify the range of applicability of different approximations to the generalized Shkarofsky function, which have been used for the analysis of relativistic effects on whistler-mode propagation and instability.     

Ridge systems related to Martian impact craters

Wrinkle ridge systems within and around Martian highland craters were studied in order to find their basin-induced and regional aspects. Most prominent ridge directions indicate regional tectonic patterns. Radial ridges near large craters are often slightly deflected along regional or global ridge systems. Crater floor ridges have simpler local distributions. Smaller or older craters are less resistant against the effects of global or regional stress systems. In craters concentric ridge rings locate at 0.8 crater radius with additional minor rings at 0.66, 0.44 and 0.94 crater radius. This pattern illustrates compression of lava fill over buried topography.     

Experimental simulation of Titan's atmosphere: Detection of ammonia and ethylene oxide

For several years now, an experimental simulation of Titan's atmosphere has been on going at LISA. A cold plasma is established in a gas mixture representative of the atmosphere of the satellite. In these experiments, more than 70 organic compounds have been identified, including the first identification in this type of experimental simulation of C₄N₂ already detected in its solid form on Titan, which suggests that the setup correctly mimics the chemistry of Titan's atmosphere.We have carried out the first experimental simulation including O-containing compounds in order to study the influence of the presence of CO on the chemical behavior of Titan's atmosphere. With the help of gas chromatography–mass spectrometry (GC–MS) and infrared spectroscopy (IRS) we can thus determine which minor species still undetected in Titan's atmosphere are likely to be present and understand the complex chemistry of the atmosphere of this satellite. Surprisingly we have identified unpredicted O-containing gaseous compounds, mainly ethylene oxide (also named oxirane, C₂H₄O). This molecule has been observed in the interstellar medium by observation in the millimeter region (Astrophys. J. 489 (1997) 553; Astron. Astrophys. 337 (1998) 275). On the contrary, the predicted O-compounds (formaldehyde and methanol) have not been identified in this experiment. Furthermore, we have identified NH₃ in the gaseous products with an initial mixture of N₂ (98%) and CH₄ (2%).The paper describes the experimental device used in this work, in particular the IRS and GC–MS techniques. We also comment the results related to the detection of the O-containing compounds and NH₃ and their implications on our knowledge of the chemistry of Titan's atmosphere and on the retrieval of the future Titan data expected from Cassini-Huygens.     

Simulating methane emission from a Chinese rice field as influenced by fertilizer and water level

Natural and agricultural wetlands are considered to be the major sources of global atmospheric methane (CH₄). A one‐dimensional model was developed to simulate methane emission and used to examine the influence of various physical processes on the rate of methane emission. Three processes involved in the methane emission are implemented in the model: production, reoxidation and transport. Three transport pathways were considered: diffusion across water–air or soil–air interfaces, ebullition and diffusion through plants. These pathways are influenced by soil properties, plant growth, water‐table conditions, temperature and external inputs (e.g. fertilizer). The model was used to examine the seasonal variation of the methane emission at a rice field in Hunan, China, which was observed during a field experiment for consecutive (early and late) rice seasons in 1992. The observed seasonal variations of methane emission, and role of plants in transporting methane to the atmosphere, are captured by the model simulation. Further model applications were conducted to simulate effects of fertilizer and water‐level condition on the methane emission. The results indicate that unfermented organic fertilizer produces a higher methane emission rate than mineral fertilizer. The simulations with treatments of a deep‐water covering and constant moisture reduced the methane emission. The rice field study provides a framework for further development of the model towards simulations based on spatially distributed variables (e.g. water table, soil temperature and vegetation) at a regional scale. Copyright © 2003 John Wiley & Sons, Ltd.     

Frequency distributions and correlations of solar X-ray flare parameters

We have determined frequency distributions of flare parameters from over 12000 solar flares recorded with the Hard X-Ray Burst Spectrometer (HXRBS) on the Solar Maximum Mission (SMM) satellite. These parameters include the flare duration, the peak counting rate, the peak hard X-ray flux, the total energy in electrons, and the peak energy flux in electrons (the latter two computed assuming a thick-target flare model). The energies were computed above a threshold energy between 25 and 50 keV. All of the distributions can be represented by power laws above the HXRBS sensitivity threshold. Correlations among these parameters are determined from linear regression fits as well as from the slopes of the frequency distributions. Variations of the frequency distributions were investigated with respect to the solar activity cycle.Theoretical models for the frequency distribution of flare parameters depend on the probability of flaring and the temporal evolution of the flare energy build-up. Our results are consistent with stochastic flaring and exponential energy build-up, with an average build-up time constant that is 0.5 times the mean time between flares. The measured distributions of flares are also consistent with predicted distributions of flares from computer simulations of avalanche models that are governed by the principle of self-organized criticality.