全文获取类型
收费全文 | 90488篇 |
免费 | 1785篇 |
国内免费 | 815篇 |
专业分类
测绘学 | 2686篇 |
大气科学 | 7077篇 |
地球物理 | 18476篇 |
地质学 | 30530篇 |
海洋学 | 7596篇 |
天文学 | 20720篇 |
综合类 | 268篇 |
自然地理 | 5735篇 |
出版年
2021年 | 578篇 |
2020年 | 711篇 |
2019年 | 776篇 |
2018年 | 1660篇 |
2017年 | 1582篇 |
2016年 | 2237篇 |
2015年 | 1476篇 |
2014年 | 2203篇 |
2013年 | 4589篇 |
2012年 | 2319篇 |
2011年 | 3270篇 |
2010年 | 2784篇 |
2009年 | 3941篇 |
2008年 | 3505篇 |
2007年 | 3222篇 |
2006年 | 3298篇 |
2005年 | 2806篇 |
2004年 | 2840篇 |
2003年 | 2656篇 |
2002年 | 2545篇 |
2001年 | 2296篇 |
2000年 | 2271篇 |
1999年 | 2000篇 |
1998年 | 1919篇 |
1997年 | 1921篇 |
1996年 | 1682篇 |
1995年 | 1615篇 |
1994年 | 1462篇 |
1993年 | 1319篇 |
1992年 | 1220篇 |
1991年 | 1122篇 |
1990年 | 1328篇 |
1989年 | 1150篇 |
1988年 | 1049篇 |
1987年 | 1265篇 |
1986年 | 1118篇 |
1985年 | 1367篇 |
1984年 | 1561篇 |
1983年 | 1478篇 |
1982年 | 1384篇 |
1981年 | 1269篇 |
1980年 | 1123篇 |
1979年 | 1062篇 |
1978年 | 1123篇 |
1977年 | 1024篇 |
1976年 | 958篇 |
1975年 | 890篇 |
1974年 | 928篇 |
1973年 | 965篇 |
1972年 | 602篇 |
排序方式: 共有10000条查询结果,搜索用时 281 毫秒
821.
Philippe E. Raison Regis Jardin Daniel Bouëxière Rudy J. M. Konings Thorsten Geisler Claudiu C. Pavel Jean Rebizant Karin Popa 《Physics and Chemistry of Minerals》2008,35(10):603-609
The crystallographic structures of the synthetic cheralite, CaTh(PO4)2, and its homolog CaNp(PO4)2 have been investigated by X-ray diffraction at room temperature. Rietveld analyses showed that both compounds crystallize in the monoclinic system and are isostructural to monazite LnPO4 (Ln = La to Gd). The space group is P21/n (I.T. = 14) with Z = 2. The refined lattice parameters of CaTh(PO4)2 are a = 6.7085(8) Å, b = 6.9160(6) Å, c = 6.4152(6) Å, and β = 103.71(1)° with best fit parameters R wp = 4.87%, R p = 3.69% and R B = 3.99%. For CaNp(PO4)2, we obtained a = 6.6509(5) Å, b = 6.8390(3) Å, c = 6.3537(8) Å, and β = 104.12(6)° and R wp = 6.74%, R p = 5.23%, and R B = 6.05%. The results indicate significant distortions of bond length and angles of the PO4 tetrahedra in CaTh(PO4)2 and to a lesser extent in CaNp(PO4)2. The structural distortions were confirmed by Raman spectroscopy of CaTh(PO4)2. A comparison with the isostructural compounds LnPO4 (Ln = Ce and Sm) confirmed that the substitution of the large rare earth trivalent cations with Ca2+ and Th4+ introduces a distortion of the PO4 tetrahedra. 相似文献
822.
Biaxial test simulations using a packing of polygonal particles 总被引:1,自引:0,他引:1
The mechanical response of cohesionless granular materials under monotonic loading is studied by performing molecular dynamic simulations. The diversity of shapes of soil grains is modelled by using randomly generated convex polygons as granular particles. Results of the biaxial test obtained for dense and loose media show that samples achieve the same void ratio at large strains independent of their initial density state. This limit state resembles the so‐called critical state of soil mechanics, except for some stress fluctuations, which remain for large deformations. These fluctuations are studied at the micro‐mechanical level, by following the evolution of the co‐ordination number, force chains and the fraction of the sliding contacts of the sample. Copyright © 2007 John Wiley & Sons, Ltd. 相似文献
823.
A.M.D. van Rotterdam-Los S.P. Vriend M.J. van Bergen P.F.M. van Gaans 《Journal of Geochemical Exploration》2008,96(1):53-68
Acid water from the Banyuputih river (pH 3.5) is used for the irrigation of agricultural land in the Asembagus coastal area (East Java, Indonesia), with harmful consequences for rice yields. The river water has an unusual composition which is caused by seepage from the acidic Kawah Ijen crater lake into the river. This unique irrigation setting allows the study of soil acidification in situ. This paper assesses the effects of volcanogenically contaminated irrigation water on the chemical properties of the agricultural soils.The changes in soil properties were evaluated by comparing samples taken from the topsoil and sub-soil (1–3 m depth) from areas irrigated with acid water and areas irrigated with neutral water. The field survey thus resulted in four soil categories. Bulk soil composition, organic matter content, moisture content and particle size distribution were determined. Reactive phases were quantified with the selective extractions 1 M KCl, 0.1 M Na-pyrophosphate and 0.2 M acid ammonium oxalate (AAO).By comparing the four soil categories it is shown that the use of the naturally polluted irrigation water has had a large influence on the chemical composition of the topsoil. The composition of the soil solution has changed over the entire investigated soil profile. Furthermore the acid irrigation water has strongly modified the composition of the reactive phases, extracted as KCl, pyrophosphate, and AAO extractable elements, and also the bulk soil composition has been significantly modified. Overall this has resulted in the net dissolution of some elements and the net precipitation of others. The changes in the reactive phases and bulk soil composition are only apparent in the topsoil (0–20 cm) but not in the deeper soil. 相似文献
824.
A.R. Salgueiro P. Freire vila H. Garcia Pereira J.M. Santos Oliveira 《Journal of Geochemical Exploration》2008,98(1-2):15
Based on an environmental geochemistry case study carried out in the neighbourhood of a W–Sn abandoned mine, the pollution in stream sediments was modelled through a Global Contamination Index. Such an index permits one to summarize the combination of deleterious elements in a single variable, obtained by the projection of samples onto the first axis of a PCASD (Principal Components Analysis of Standardized Data) applied to the entire n × p matrix containing the available concentrations of p = 16 elements in the set of n = 220 collected samples.In order to provide a sound basis for a coherent planning of the remediation process which will be put in operation in the affected area, it is necessary to balance the costs of reclaiming with the probabilities of exceeding the upper limits accepted for concentrations of environmentally harmful elements in sediments. Given these limits, they are back-transformed in the index values, providing a practical threshold between ‘clean’ and ‘contaminated’ samples. On the other hand, the minimum dimension of the cell to be reclaimed is restrained by the selected remediation process to be applied in the affected area. Hence, to meet the constraints of such a remediation process, it is required to estimate the probabilities of exceeding the index threshold in technologically meaningful sub-areas. For this end, the Indicator Block Kriging technique was applied, producing a series of maps where sub-areas to be reclaimed can be spotted for different probability levels. These maps, on which the decision making remediation agency can rely for its cost-benefit analysis, take into account both the spatial structure of ‘clean’ vs. ‘contaminated’ samples and the constraints of the reclaiming process. 相似文献
825.
The Nordic geological surveys: Geology for society in practice 总被引:1,自引:0,他引:1
Morten Smelror Andreas AhlstrФm Lena Ekelund Jens Morten Hansen Keijo Nenonen Anette K. Mortensen 《《幕》》2008,31(1):193-200
Since the mid-nineteenth century., when the first of the Nordic Geological Surveys were established, they have generated a substantial amount of information on the Earth's crust, its natural resources, its processes, and on the geological history of Nordic areas. The collective mission of the geological surveys is to carry out "Geology for Society", by doing research and providing services, and by making geological information and data easily accessible to all the varied end users in industry, government agencies, government institutes, public administrations, technical offices, academia and research institutes, as well as for private individuals. The present paper gives a brief overview of a few, selected, research areas and projects currently undertaken by the Nordic geological surveys. These serve as practical examples of how the Nordic geological surveys address important societal problems and challenges that require geological input for their solution. 相似文献
826.
827.
H. M. Hussein K. M. Abou Elenean I. A. Marzouk A. Peresan I. M. Korrat E. Abu El-Nader G. F. Panza M. N. El-Gabry 《Natural Hazards》2008,47(3):525-546
The aim of the present work is to compile and update a catalogue of the instrumentally recorded earthquakes in Egypt, with
uniform and homogeneous source parameters as required for the analysis of seismicity and seismic hazard assessment. This in
turn requires a detailed analysis and comparison of the properties of different available sources, including the distribution
of events with time, the magnitude completeness, and the scaling relations between different kinds of magnitude reported by
different agencies. The observational data cover the time interval 1900–2004 and an area between 22°–33.5° N and 25°–36° E.
The linear regressions between various magnitude types have been evaluated for different magnitude ranges. Using the best
linear relationship determined for each available pair of magnitudes, as well as those identified between the magnitudes and
the seismic moment, we convert the different magnitude types into moment magnitudes M
W, through a multi-step conversion process. Analysis of the catalogue completeness, based on the M
W thus estimated, allows us to identify two different time intervals with homogeneous properties. The first one (1900–1984)
appears to be complete for M
W ≥ 4.5, while the second one (1985–2004) can be considered complete for magnitudes M
W ≥ 3. 相似文献
828.
Mineralogy and geochemistry of El Dorado epithermal gold deposit, El Sauce district, central-northern Chile 总被引:1,自引:0,他引:1
J. Carrillo-Rosúa S. Morales-Ruano D. Morata A. J. Boyce M. Belmar A. E. Fallick P. Fenoll Hach-Alí 《Mineralogy and Petrology》2008,92(3-4):341-360
Summary The El Dorado Au-Cu deposit is located in an extensive intra-caldera zone of hydrothermal alteration affecting Upper Cretaceous
andesites of the Los Elquinos Formation at La Serena (≈ 29°47′S Lat., 70°43′W Long., Chile). Quartz-sulfide veins of economic potential are hosted by N25W and N20E
fault structures associated with quartz-illite alteration (+supergene kaolinite). The main ore minerals in the deposit are
pyrite, chalcopyrite ± fahlore (As/(As + Sb): 0.06−0.98), with electrum, sphalerite, galena, bournonite-seligmanite (As/(As
+ Sb): 0.21−0.31), marcasite, pyrrhotite being accessory phases. Electrum, with an Ag content between 32 and 37 at.%, occurs
interstitial to pyrite aggregates or along pyrite fractures. Pyrite commonly exhibits chemical zonation with some zones up
to 1.96 at.% As. Electron probe microanalyses of pyrite indicate that As-rich zones do not exhibit detectable Au values. Fluid
inclusion microthermometry shows homogenization temperatures between 130 and 352 °C and salinities between 1.6 and 6.9 wt.%
NaCl eq. Isotope data for quartz, ankerite and phyllosilicates and estimated temperatures show that δ18O and δD for the hydrothermal fluids were between 3 and 10‰ and between −95 and −75‰, respectively. These results suggest
the mineralizing fluids were a mixture of meteoric and magmatic waters. An epithermal intermediate-sulfidation model is proposed
for the formation of the El Dorado deposit.
Author’s present address: J. Carrillo-Rosúa, Dpto. de Didáctica de las Ciencias Experimentales, Universidad de Granada, Campus de Cartuja, 18071, Granada, Spain 相似文献
829.
Summary Boron-doped mullites were synthesized using aluminium nitrate-nonahydrate, tetraethoxysilane and boric acid in a sol–gel process
with subsequent annealing at 950 and 1300 °C for five hours. Two different bulk compositions with constant Al2O3 contents (60 and 70 mol%, respectively) and varying SiO2 plus B2O3 contents were investigated. X-ray powder diffraction analyses yielded a linear decrease of the lattice parameters with increasing
bulk B2O3 content, which was interpreted as to be due to boron incorporation. Related to the increasing boron content, corresponding
infrared spectra revealed a slight and continuous shift for most of the absorption bands. These data show that mullite is
able to incorporate large amounts of boron into its structure (up to about 20 mol% B2O3 depending on the bulk composition of the starting materials). Infrared analyses suggest that boron is incorporated into the
mullite structure in form of planar three-fold coordinated BO3 groups.
Author’s address: A. Beran, Institut für Mineralogie und Kristallographie, Universit?t Wien-Geozentrum, Althanstra?e 14, 1090 Wien, Austria 相似文献
830.
M. Mejías J. Garcia-Orellana J. L. Plata M. Marina E. Garcia-Solsona B. Ballesteros P. Masqué J. López C. Fernández-Arrojo 《Environmental Geology》2008,54(3):521-536
A methodology for the characterization of deep carbonate aquifers has been developed and applied to El Maestrazgo Jurassic
aquifer in Castellón, Spain. Characterization of these aquifer formations, located at more than 300 m deep, consisted of a
previous phase of compilation, analysis and synthesis of the existing information about the area, followed by a coordinated
combination of different speciality studies: geology, stratigraphy, structural analysis, hydrogeology, hydrochemistry, geophysics
and remote sensing. Geological studies included geological mapping, definition of stratigraphical units and facies and structural
analysis. The aim of the hydrogeology study was to define aquifer formations, recharge area, aquifer points inventory and
groundwater flow directions for the establishment of piezometric and water quality observation nets. Special techniques were
applied, like thermal infrared aerial images and the evaluation of submarine groundwater discharge by means of natural radium
isotopes. Hydrochemical techniques, including majority elements characterization and stable isotopes (18O, 2H and 3H) determination, allowed classifying hydrochemical facies and establishing a renewal pattern for water within the system.
Geophysics was useful in determining the aquifer geometry, the features of the basement and the petrophysical characteristics
of the geological formations. Preliminary results show an important tectonic complexity and the possibilities for groundwater
uses in the area of study. 相似文献