Using the geologic setting of talc deposits as an indicator of amphibole asbestos content

This study examined commercial talc deposits in the U.S. and their amphibole-asbestos content. The study found that the talc-forming environment directly influenced the amphibole and amphibole-asbestos content of the talc deposit. Large talc districts in the U.S. have mined hydrothermal talcs that replaced dolostone. Hydrothermal talcs, created by siliceous fluids heated by magmas at depth, consistently lack amphiboles as accessory minerals. In contrast, mineable talc deposits that formed by contact or regional metamorphism consistently contain amphiboles, locally as asbestiform varieties. Examples of contact metamorphic deposits occur in Death Valley, California; these talc-tremolite deposits contain accessory amphibole-asbestos. Talc bodies formed by regional metamorphism always contain amphiboles, which display a variety of compositions and habits, including asbestiform. Some industrial mineral deposits are under scrutiny as potential sources of accessory asbestos minerals. Recognizing consistent relations between the talc-forming environment and amphibole-asbestos content may be used in prioritizing remediation or monitoring of abandoned and active talc mines.     

Release into the environment of metals by two vascular salt marsh plants

Metals in contaminated salt marshes are mainly locked in the anaerobic layer of sediments, where they are tightly bound as sulfides and organic complexes. Vascular plants survive in saturated soils in part by pumping O2 into their root zones, changing their microenvironment to an oxic one. This, along with chelating exudates, mobilizes metals, allowing uptake by the roots. We compared the common reed Phragmites australis and cordgrass Spartina alterniflora in lab and field studies for ways in which they handle trace metals. Both plants store most of their metal burden in their roots, but some is transported to aboveground tissues. Spartina leaves contain approximately 2-3 x more Cr, Pb, and Hg than Phragmites leaves, but equivalent Cu and Zn. Furthermore, Spartina leaves have salt glands, so leaf excretion of all metals is twice that of Phragmites. In-depth studies with Hg indicate that Hg excretion correlates with Na release but not with transpiration, which is 2.2 x higher in Phragmites; and that more Hg accumulates in early-appearing leaves than in upper (i.e. later) leaves in both species. Spartina thus makes more metals available to salt marsh ecosystems than Phragmites by direct excretion and via dead leaves which will enter the food web as detritus.     

Comparison of transfer functions in statistical downscaling models for daily temperature and precipitation over Canada

This study compares three linear models and one non-linear model, specifically multiple linear regression (MLR) with ordinary least squares (OLS) estimates, robust regression, ridge regression, and artificial neural networks (ANNs), to identify an appropriate transfer function in statistical downscaling (SD) models for the daily maximum and minimum temperatures (T_max and T_min) and daily precipitation occurrence and amounts (P_occ and P_amount). This comparison was made over twenty-five observation sites located in five different Canadian provinces (British Columbia, Saskatchewan, Manitoba, Ontario, and Québec). Reanalysis data were employed as atmospheric predictor variables of SD models. Predictors of linear transfer functions and ANN were selected by linear correlations coefficient and mutual information, respectively. For each downscaled case, annual and monthly models were developed and analysed. The monthly MLR, annual ANN, annual ANN, and annual MLR yielded the best performance for T_max, T_min, P_occ and P_amont according to the modified Akaike information criterion (AICu). A monthly MLR is recommended for the transfer functions of the four predictands because it can provide a better performance for the T_max and as good performance as the annual MLR for the T_min, P_occ, and P_amount. Furthermore, a monthly MLR can provide a slightly better performance than an annual MLR for extreme events. An annual MLR approach is also equivalently recommended for the transfer functions of the four predictands because it showed as good a performance as monthly MLR in spite of its mathematical simplicity. Robust and ridge regressions are not recommended because the data used in this study are not greatly affected by outlier data and multicollinearity problems. An annual ANN is recommended only for the T_min, based on the best performance among the models in terms of both the RMSE and AICu.     

Origin of Exceptionally Abundant Phonolites on Ua Pou Island (Marquesas, French Polynesia): Partial Melting of Basanites Followed by Crustal Contamination

On the basis of the first systematic mapping of Ua Pou, longknown for its exceptionally abundant phonolites, we estimatethat these rocks cover 65% of the surface of the island whereasmafic lavas cover 27% and intermediate ones 8%. The silica-undersaturatedsuite was erupted in a restricted time span (2·9–2·35Myr), following the emplacement of tholeiites derived from ayoung HIMU-type source at c. 4 Ma. Primitive basanites, derivedfrom a heterogeneous mantle source with a dominant EM II + HIMUsignature, represent likely parental magmas. The series is characterizedby a Daly gap defined by a lack of phonotephrites. We considerthat the most likely model for the origin of evolved lavas ispartial melting at depth of primitive basanites, leaving anamphibole-rich residuum and producing tephriphonolitic magmas.These tephriphonolitic magmas may have evolved by closed-systemfractional crystallization towards Group A phonolites. Threeother groups of phonolites could have been derived from tephriphonoliticmagmas by open-system fractional crystallization processes,characterized respectively by seawater contamination (GroupB), assimilation of nepheline syenite-type materials (GroupC) and extreme fractionation coupled with assimilation of theunderlying oceanic crust (Group D). The prominence of evolvedlavas is a consequence of their origin from partial meltingof mafic precursors followed by crustal contamination. KEY WORDS: Marquesas; French Polynesia; phonolite; partial melting; contamination     

Does upward seepage of river water and storm water runoff determine water quality of urban drainage systems in lowland areas? A case study for the Rhine–Meuse delta

The water quality of urban drainage ditches in lowlands in the Rhine‐Meuse delta was analysed with principal component analysis (PCA) during a dry period and a rain storm, and related to the seepage of polluted river water and effective impervious area (EIA). This was done in order to test the hypothesis that seepage of river water and storm water runoff from impervious areas strongly determine the water quality of urban drainage systems along large lowland rivers. Our analysis revealed that upward seepage of groundwater originating from rivers Rhine and Meuse was positively correlated with nitrate, potassium, sodium and chloride and negatively correlated with alkalinity, calcium, magnesium and iron. EIA was correlated with very few environmental variables (i.e. phosphate, pH and iron in the dry period and iron during the rain storm). Nickel and zinc concentrations generally exceeded the maximum allowable concentrations (MAC), while lead and phosphorus concentrations were just above the nutrient standards and MAC in a few locations during the rain storm. To optimize water quality in urban water systems, attention should be paid to all sources of pollution and not only to EIA. The impact of local groundwater seepage originating from large rivers in lowlands on the chemistry of urban water systems is often underestimated and should be taken into account when assessing water quality and improving water quality status. Copyright © 2009 John Wiley & Sons, Ltd.     

The role of meridional density differences for a wind-driven overturning circulation

Experiments with the coupled climate model CLIMBER-3α, which contains an oceanic general circulation model, show deep upwelling in the Southern Ocean to be proportional to the surface wind stress in the latitudinal band of Drake Passage. At the same time, the distribution of the Southern Ocean upwelling onto the oceanic basins is controlled by buoyancy distribution; the inflow into each basin being proportional to the respective meridional density difference. We observe approximately the same constant of proportionality for all basins, and demonstrate that it can be directly related to the flow geometry. For increased wind stress in the Southern Ocean, the overturning increases both in the Atlantic and the Indo-Pacific basin. For strongly reduced wind stress, the circulation enters a regime where Atlantic overturning is maintained through Pacific upwelling, in order to satisfy the transports set by the density differences. Previous results on surface buoyancy and wind stress forcing, obtained with different models, are reproduced within one model in order to distill a consistent picture. We propose that both Southern Ocean upwelling and meridional density differences set up a system of conditions that determine the global meridional overturning circulation.     

A tectonic model for the metamorphic evolution of the Basal Gneiss Complex, Western South Norway

A review of currently available information relevant to the Basal Gneiss Complex (BGC) of Western South Norway, combined with the authors'own observations, leads to the following conclusions.
1. Most of the BGC consists of Proterozoic crystalline rocks and probably subordinate Lower Palaeozoic cover.
2. The last major deformation of these rocks was during the Caledonian orogeny and involved large-scale thrusting, recumbent folding and doming. The structural development of the BGC is closely tied in with that of the Caledonian allochthon.
3. The whole eclogite-bearing part of the BGC has suffered a high pressure metamorphism with conditions of between 550°C, 12.5 kbar (Sunnfjord) and about 750°C, 20 kbar (Møre og Romsdal) at the metamorphic climax.
4. This metamorphism was of Caledonian age, probably rather early in the Caledonian tectonic history of the BGC and is considered to have been a rather transient event.
By setting these conclusions in a framework provided by geophysical evidence for the deep structure of the crust in southern Norway we have constructed a geotectonic model to explain the recorded metamorphic history of the BGC. It is suggested that considerable crustal thickening was caused by imbrication of the Baltic plate margin during continental collision with the Greenland plate. This resulted in high pressure metamorphism in the resulting nappe stack. Progradation of the suture caused underthrusting of the Baltic foreland below the eclogite-bearing terrain causing it to emerge at the Earth's surface, aided by tectonic stripping and erosion.
Application of isostacy equations to the model shows that eclogites can be formed by in-situ metamorphism in crustal rocks and reappear at the land surface above a normal thickness of crust in a single orogenic episode of approximately 65-70 Ma duration.     

The thermal conductivity for granite with various water contents

The thermal conductivities of granite were measured under different conditions of porosity and water content to investigate the effects of the porosity and water content on the thermal conductivity. For the dry samples, the thermal conductivities range from 2.12 W/mK for the rocks with a high porosity to 3.12 W/mK for the ones with a low porosity. Water-sorbed samples have greater thermal conductivities than dry samples of the same granite. The thermal conductivities range from 2.99 W/mK for granites with a high porosity to 3.62 W/mK for ones with a low porosity under saturated condition.     

Characterization of a chalcopyrite from Brazil by Mössbauer spectroscopy and other physicochemical techniques

We studied a chalcopyrite from a Cu ore deposit in Rio Grande do Sul, Brazil, by Mössbauer spectroscopy at room temperature and 110 K. Supporting methods to check for sample purity and to characterize further sample properties were slow-scanning X-ray powder diffraction and optical and microprobe analyses of polished sections of selected grains. Chemical analyses obtained using a scanning electron microscope equipped with an energy-dispersive X-ray spectrometer showed the sample to consist of homogeneous and essentially stoichiometric chalcopyrite (CuFeS₂). Mössbauer spectra taken at both the above temperatures consist of asymmetric magnetically ordered patterns with unequal intensities of the line pairs 1–6 and 2–5, pointing to the existence of non-equivalent or multiple Fe sites. Least-squares fittings evidenced that the resonance intensity ratio of subspectrum with lower quadrupole shift (indicative of a more symmetric environment) to that with higher shift is 69:31, at room temperature, and 68:32, at 110 K. Rietveld refinement of the XRD data indicates the existence of tetragonal [a = 0.52855(1) and c = 1.0412(1) nm] and cubic [a ₀ = 0.5273(2) nm] modifications in a proportion of 74:26, in good agreement with the Mössbauer data. The saturation magnetization of the sample was 32.7 J/(T kg), confirming the oxidation state of Fe as trivalent and pointing to little to no spin canting.