Biaxial test simulations using a packing of polygonal particles

The mechanical response of cohesionless granular materials under monotonic loading is studied by performing molecular dynamic simulations. The diversity of shapes of soil grains is modelled by using randomly generated convex polygons as granular particles. Results of the biaxial test obtained for dense and loose media show that samples achieve the same void ratio at large strains independent of their initial density state. This limit state resembles the so‐called critical state of soil mechanics, except for some stress fluctuations, which remain for large deformations. These fluctuations are studied at the micro‐mechanical level, by following the evolution of the co‐ordination number, force chains and the fraction of the sliding contacts of the sample. Copyright © 2007 John Wiley & Sons, Ltd.     

Late Pleistocene and Early Holocene lake‐level fluctuations in the Lahontan Basin,Nevada: Implications for the distribution of archaeological sites

The Great Basin of the western U.S. contains a rich record of Late Pleistocene and Holocene lake‐level fluctuations as well as an extensive record of human occupation during the same time frame. We compare spatial‐temporal relationships between these records in the Lahontan basin to consider whether lake‐level fluctuations across the Pleistocene‐Holocene transition controlled distribution of archaeological sites. We use the reasonably well‐dated archaeological record from caves and rockshelters as well as results from new pedestrian surveys to investigate this problem. Although lake levels probably reached maximum elevations of about 1230–1235 m in the different subbasins of Lahontan during the Younger Dryas (YD) period, the duration that the lakes occupied the highest levels was brief. Paleoindian and Early Archaic archaeological sites are concentrated on somewhat lower and slightly younger shorelines (_1220–1225 m) that also date from the Younger Dryas period. This study suggests that Paleoindians often concentrated their activities adjacent to large lakes and wetland resources soon after they first entered the Great Basin. © 2008 Wiley Periodicals, Inc.     

Influence of Intra- and Interspecific Interactions on Short-term Movement of the Amphipod Corophium volutator in Varying Environmental Conditions

Movement of animals on intertidal mudflats can have profound consequences for population and community dynamics. Such movement is often influenced by biotic interactions, but the abiotic environment can also be important, affecting the strength of species’ interactions and even changing their outcome. Here, we focused on two biotic interactions and examined their effect on movement of the burrow-dwelling amphipod Corophium volutator: intraspecific interactions (specifically, the effect of conspecific density) and interspecific interactions with a competitor–predator, the mud snail Ilyanassa obsoleta (=Nassarius obsoletus). We assessed the magnitude of the temporal variation and examined the influence of pertinent abiotic variables (lunar cycle, presence of tide pools). Despite substantial temporal variation in movement levels, density of conspecifics did not influence emigration or immigration rates of C. volutator. Mud snails negatively affected immigration of C. volutator, and this was consistent across all lunar phases. However, mud snails influenced mortality and emigration of C. volutator in a contrasting way relative to lunar phases; sometimes amphipods evaded snails and survived, but at other times did not emigrate and were killed. The presence of tide pools did not change the nature or strength of the snail–amphipod interaction. Our results further clarify the complex interactions between C. volutator and I. obsoleta and suggest that resources on the mudflat are sufficient to sustain high densities of amphipods in a density-independent manner. Further, they highlight the importance of considering multiple environmental variables when examining interspecific interactions.     

Elemental Composition of Mnemiopsis leidyi A. Agassiz 1865 and Its Implications for Nutrient Recycling in a Long Island Estuary

The ctenophore Mnemiopsis leidyi is an ecologically important predator in temperate coastal environments. Their populations fluctuate seasonally, serving as sinks of nutrients during periodic blooms, but as sources via excretion and during population collapse. Ctenophores were analyzed for elemental composition (C, N, and P) during 2008 and 2009 in Great South Bay, NY, USA. Salt-free weight percent C, N, and P correlated positively with ctenophore sizes and zooplankton prey abundances. Nitrogen and P were higher at the onset of blooms than during collapse when prey were substantially fewer. Ctenophores collected during average to high zooplankton densities had atomic ratios averaging C/N ~6:1 and C/P ~66:1, but became C- and P-depleted (C/N ~5:1, C/P ~128:1) with decreasing zooplankton. Incubations demonstrated rapid remineralization of ctenophore biomass (as NH₄ ⁺, HPO₄ ^2?), following first order kinetics (e.g., k ~0.1–0.4 day^?1) with enriched stoichiometric N and P fractionation relative to biomass under both oxic and anoxic conditions. Based on reported excretion rates, nutrient regeneration from excretion by active populations greatly exceeds nutrients remineralized during population crashes. To our knowledge, this is the first study documenting natural seasonal patterns in ctenophore elemental stoichiometry as a function of ctenophore size and prey availability.     

Upper Jurassic record of Polyphylloseris (Egypt, Northern Sinai)

Genus Polyphylloseris is a scleractinian colonial coral that has been established by d’Orbigny (1849) from the Neocomian of Yonne, France. The genus is characterized by having elevated domal calices that are mammillar or craterlike in shape and with porous confluent septa. Columella is absent or rudimentary, and the lower surface of the corallum is covered with a thick and wrinkled holotheca. Specimens having the above-mentioned characteristics have been collected from the Upper Jurassic Arousiah Member of the Masajid Formation (Callovian–Oxfordian) of Gebel Maghara, Northern Sinai, Egypt. They are characterized by having a cupolate colonial form and porous pennulate septa which reach 40–50 in number. Based on these characters and other characters such as density of septa, height, and width of mammillar calices, the studied material is attributed to a new species named Polyphylloseris magharensis. The new species is a first undoubted record of Polyphylloseris in the Jurassic. Previously recorded undoubted ages of the genus are Early and Late Cretaceous. The fewer number of septa and the smaller-sized and closer mammillar calices allow differentiation of the species from other species such as Polyphylloseris icaunensis d’Orbigny and Polyphylloseris convexa d’Orbigny.     

Timescales of partial melting in the Himalayan middle crust: insight from the Leo Pargil dome, northwest India

The Leo Pargil dome (LPD) in northwest India exposes an interconnected network of pre-, syn-, and post-kinematic leucogranite dikes and sills that pervasively intrude amphibolite-facies metapelites of the mid-crustal Greater Himalayan sequence. Leucogranite bodies range from thin (5-cm-wide) locally derived sills to thick (2-m-wide) crosscutting dikes extending at least 100 m. Three-dimensional exposures elucidate crosscutting relations between different phases of melt injection and crystallization. Combined laser ablation inductively coupled plasma mass spectrometry U–Th/Pb geochronology and trace element analysis on well-characterized monazite grains from nineteen representative leucogranites yields a large, internally consistent data set of approximately 700 U–Th/Pb and 400 trace element analyses. Grain-scale variations in age correlate with trace element distributions and indicate semi-continuous crystallization of monazite from 30 to 18 Ma. The youngest U–Th/Pb ages in a given sample are consistent with the outcrop-scale crosscutting relations, whereas older ages within individual samples record inheritance from partially crystallized melt and source metapelites. U–Th/Pb isotopic and trace element data are incorporated into a model of melting within the LPD that involves (1) steady-state equilibrium batch melting of compositionally homogeneous metapelitic sources; (2) pulses of increased melt mobility lasting 1–2 m.y. resulting in segregation of melt from its source and amalgamation into mixed magmas; and (3) rapid emplacement and final crystallization of leucogranite bodies. Melt systems in the LPD evolved from locally derived, in situ melt in migmatitic source rocks into a vast network of dikes and sills in the overlying non-migmatitic host rocks.     

Mineralogical and Geochemical Constraints on the Sediment Sources of Late Stone Age Pottery from the Birimi Site,Northern Ghana

The mineralogy and bulk chemical compositions of 15 Kintampo (Late Stone Age) potsherds from the Birimi site on the Gambaga Escarpment and eight samples of local sediment were determined with the intent of characterizing these wares and identifying the material used in their manufacture. Sediment from clay pits still used by potters north of the escarpment contains iron‐rich laterite clasts (100 × XFeO_t = 100 × FeO_t/[FeO_t + Al₂O₃ + SiO₂] ≥10). Sedimentary clasts in stream sediments are relatively siliceous and iron‐poor (100 × XFeO_t < 10). Bulk geochemical data together with the compositions of lithic clasts (laterite, siltstone/sandstone) link the pottery to sediment sources, including escarpment sediments not presently used by Ghanaian potters. Fresh granite clasts found in some of the sherds were not found in the analyzed sediment samples, although some of their distinctive mineralogical constituents (e.g., variably barian alkali feldspar) are present. The analytical data suggest that pots found at Birimi were made locally by mixing escarpment sediment with clay and stream sediment brought in from below the escarpment. This contrasts with present‐day practice, whereby the pots themselves are imported. The place where Birimi pottery was made and the outcrop source of aluminous sediment (mudstone with an “escarpment” trace element signature) used in these wares, however, remain unidentified. © 2013 Wiley Periodicals, Inc.     

Ambient pressure thermal desorption spectroscopy (AP-TDS) of NiO/SiO2 catalysts

The Sabatier reaction is a key process in the “power-to-gas” application which is considered to contribute to future chemical energy storage systems. In this contribution we focus on the catalytic active sites of a NiO catalyst supported on SiO₂ (NiO/SiO₂) which is commonly used in the Sabatier reaction. A novel technique for the characterization of the active sites is presented and discussed using thermal desorption spectroscopy at ambient pressure. This analytical tool is operated under reaction conditions and allows element specific measurements during the catalytic process of CO₂ reforming towards methane. Beside the desorption experiments, XPS and XAS measurements of pristine and catalytically used samples are performed to determine the influence of the Sabatier reaction conditions on the surface structure of the catalyst.     

Mount Woolnough: the submerged volcano,SE of Sydney,NSW

Part of a larger investigation of the sea bed off Sydney was a study of the extinct submarine volcano Mount Woolnough. It is located approximately 41 km east of Kurnell, NSW, and protrudes 175 m above the sediment cover at depths of approximately ?550 to ?375 m. Volcanic rock, approximately 2.2 km in diameter, is exposed above the sediment sea floor and is much smaller than its magnetic expression (approximately 13 km in diameter). Samples dredged from Mount Woolnough were conglomerates with phosphatic nodules and volcanic fragments set in a fine foraminiferal sediment matrix. Zircons within the mafic fragments yielded a minimum age of 261 Ma.     

Structure and metamorphism of the Calliope Volcanic Assemblage: Implications for middle to Late Devonian orogeny in the northern New England Fold Belt

The Late Silurian to Middle Devonian Calliope Volcanic Assemblage in the Rockhampton region is deformed into a set of northwest‐trending gently plunging folds with steep axial plane cleavage. Folds become tighter and cleavage intensifies towards the bounding Yarrol Fault to the east. These folds and associated cleavage also deformed Carboniferous and Permian rocks, and the age of this deformation is Middle to Late Permian (Hunter‐Bowen Orogeny). In the Stanage Bay area, both the Calliope Volcanic Assemblage and younger strata generally have one cleavage, although here it strikes north to northeast. This cleavage is also considered to be of Hunter‐Bowen age. Metamorphic grade in the Calliope Volcanic Assemblage ranges from prehnite‐pumpellyite to greenschist facies, with higher grades in the more strongly cleaved rocks. In the Rockhampton region the Calliope Volcanic Assemblage is part of a west‐vergent fold and thrust belt, the Yarrol Fault representing a major thrust within this system.

A Late Devonian unconformity followed minor folding of the Calliope Volcanic Assemblage, but no cleavage was formed. The unconformity does not represent a collision between an exotic island arc and continental Australia as previously suggested.