Characteristics of spectral aerosol optical depths over India during ICARB

Spectral aerosol optical depth (AOD) measurements, carried out regularly from a network of observatories spread over the Indian mainland and adjoining islands in the Bay of Bengal and Arabian Sea, are used to examine the spatio-temporal and spectral variations during the period of ICARB (March to May 2006). The AODs and the derived Ångström parameters showed considerable variations across India during the above period. While at the southern peninsular stations the AODs decreased towards May after a peak in April, in the north Indian regions they increased continuously from March to May. The Ångström coefficients suggested enhanced coarse mode loading in the north Indian regions, compared to southern India. Nevertheless, as months progressed from March to May, the dominance of coarse mode aerosols increased in the columnar aerosol size spectrum over the entire Indian mainland, maintaining the regional distinctiveness. Compared to the above, the island stations showed considerably low AODs, so too the northeastern station Dibrugarh, indicating the prevalence of cleaner environment. Long-range transport of aerosols from tshe adjoining regions leads to remarkable changes in the magnitude of the AODs and their wavelength dependencies during March to May. HYSPLIT back-trajectory analysis shows that enhanced long-range transport of aerosols, particularly from the west Asia and northwest coastal India, contributed significantly to the enhancement of AOD and in the flattening of the spectra over entire regions; if it is the peninsular regions and the island Minicoy are more impacted in April, the north Indian regions including the Indo Gangetic Plain get affected the most during May, with the AODs soaring as high as 1.0 at 500 nm. Over the islands, the Ångström exponent (α) remained significantly lower (～1) over the Arabian Sea compared to Bay of Bengal (BoB) (～1.4) as revealed by the data respectively from Minicoy and Port Blair. Occurrences of higher values of α, showing dominance of accumulation mode aerosols, over BoB are associated well with the advection, above the boundary layer, of fine particles from the east Asian region during March and April. The change in the airmass to marine in May results in a rapid decrease in α over the BoB.     

Aerobic degradation of organic carbon inferred from dinoflagellate cyst decomposition in Southern Ocean sediments

Organic carbon (OC) burial is an important process influencing atmospheric CO₂ concentration and global climate change; therefore it is essential to obtain information on the factors determining its preservation. The Southern Ocean (SO) is believed to play an important role in sequestering CO₂ from the atmosphere via burial of OC. Here we investigate the degradation of organic-walled dinoflagellate cysts (dinocysts) in two short cores from the SO to obtain information on the factors influencing OC preservation. On the basis of the calculated degradation index kt, we conclude that both cores are affected by species-selective aerobic degradation of dinocysts. Further, we calculate a degradation constant k using oxygen exposure time derived from the ages of our cores. The constant k displays a strong relationship with pore-water O₂, suggesting that decomposition of OC is dependent on both the bottom- and pore-water O₂ concentrations.     

Palaeoflood activity and climate change over the last 1400 years recorded by lake sediments in the north‐west European Alps

A high‐resolution sedimentological and geochemical study of a high‐altitude proglacial lake (Lake Blanc, Aiguilles Rouges, 2352 m a.s.l.) revealed 195 turbidites, 190 of which are related to flood events over the last 1400 years. We used the coarsest sediment fraction of each turbidite as a proxy for the intensity of each flood event. Because most flood events at this locality are triggered by localized summer convective precipitation events, the reconstructed sedimentary record reveals changes in the frequency and intensity of such events over the last millennium. Comparisons with other temperature, palaeohydrological and glacier reconstructions in the region suggest that the most intense events occurred during the warmest periods, i.e. during the Medieval Climate Anomaly (AD 800–1300) and the current period of global warming. On a multi‐decadal time scale, almost all the flood frequency peaks seem to correspond to warmer periods, whereas multi‐centennial variations in flood frequency appear to follow the regional precipitation pattern. Consequently, this new Alpine flood record provides further evidence of a link between climate warming and an increase in the frequency and intensity of flooding on a multi‐decadal time scale, whereas the centennial variability in flood frequencies is related to regional precipitation patterns. Copyright © 2013 John Wiley & Sons, Ltd.     

Geology and petroleum potential of the Fairway Basin in the Tasman Sea

The Fairway Basin is a large, generally north – south-trending, sediment-filled structure in water 1500 – 3000 m deep, on the eastern slope of the Lord Howe Rise in the Tasman Sea, and is partly within Australian jurisdiction. It was poorly known until a few years ago, when seismic profiling and piston coring cruises were carried out. The basin, about 1100 km long and 120 – 200 km wide, can be divided into three segments—north, central and south—that trend northwest, north and north-northwest, respectively. All three segments probably formed by thinning of continental crust during breakup of Lord Howe Rise and surrounding aseismic continental ridges in the Late Cretaceous and Paleocene. Normal faulting, large inputs of terrigenous sediment and subsidence to bathyal marine depths occurred during that time. A period of compression, perhaps related to overthrusting on New Caledonia, occurred in the Eocene, leading to uplift (and in parts, erosion) of northern Lord Howe Rise, and reversal of faulting in the basin. By the Oligocene, the area was again in bathyal depths, and pelagic ooze and some turbidites accumulated. The basinal sequence is generally 2000 – 4000 m thick, with 1200 – 3200 m of Cretaceous to Eocene sediment concentrated in depocentres, capped by 500 – 800 m of Oligocene and younger sediment. In the depocentres, numerous sedimentary diapirs pierce sedimentary sequences. The sedimentary diapirs appear to be fed by Cretaceous muds deposited during rifting. Often, these diapirs are overlain by faults extending to the seafloor, and hummocky bathymetry is possibly caused by fluid escape. The overall geology suggests that the Fairway Basin may be a large frontier hydrocarbon province. Seismic profiles display a bottom-simulating reflector above many depocentres, 500 – 700 m below the seafloor. The bottom-simulating reflector has positive polarity, which could result from a diagenetic phase transformation, a thin gas hydrate layer with a sharp top, or from the sharp base of a gas layer (probably beneath gas hydrates). Standard piston cores taken above diapirs and apparent fluid-escape features have recovered little gas. Other than drilling, the next steps in assessing petroleum potential are to clearly document fluid-escape structures, and to sample any fluids emitted for hydrocarbons.     

Geospatial analysis between the environment and past incidences of West Nile virus in bird specimens in Ontario,Canada

Over recent years, the prevalence of the West Nile virus (WNV) in Canada has greatly increased due to various factors including changes in feeding behavior among WNV vectors. To understand whether changes in climate are a significant factor, the association between the environment and cases of WNV-infected bird specimens from 2009 to 2012 in Ontario, Canada, was examined using SAS and Quantum Geographic Information Systems (QGIS). Through a generalized linear mixed analysis, monthly totals of cooling degree days (CDD) and a two-way interaction between maximum temperature (Tmax) and precipitation were significantly positively associated to past incidences of WNV; while Tmax, precipitation, and a two-way interaction between CDD and precipitation were significantly negatively associated to past incidences of WNV. With the effects of increased warming, locations at higher latitudes in Canada may soon be at risk to WNV, as a positive case of WNV in a bird specimen was found close to the near north of Ontario in 2012.     

La theorie des deux magmas fondamentaux dans le volcanisme intracontinental et l'evolution geochimique des laves du Mont-Dore (France)

Résumé Les auteurs utilisent toutes les données chimiques, volcanologiques, chronologiques et tectonophysiques fournies pour un certain nombre de massif continentaux (Mont-Dore et autres). La synthèse de toutes ces études montre qu'il existe deux magmas continentaux indépendants: le magma basaltique venant du manteau (sima) et le magma rhyolitique fourni par la croûte supérieure (sial). Le mélange de ces deux magmas et l'action secondaire de la' gravité et de la pneumatolyse expliquent logiquement la totalité des phénomènes géochimiques des volcans continentaux.

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The authors used all the chemical, volcanological, chronological and tectonophysical data supplied for a certain number of continental mountain massifs (Mont-Dore and others). The synthesis of these studies shows that there are two independent continental magmas: the basaltic magma coming from the mantle (sima) and the rhyolitic magma supplied by the upper crust (sial). The mixing of these two magmas, with the secondary action of gravity and pneumatolysis logically explains the totality of the geochemical phenomena in continental volcanoes.

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Zusammenfassung Die Autoren benutzten alle chemischen, vulkanologischen, chronologischen und tektonisch-physikalischen Daten, die von einer bestimmten Anzahl von kontinentalen Massiven (Mont-Dore und andere) entnommen wurden.Das Ergebnis dieser Studien zeigt, daß es zwei voneinander unabhängige kontinentale Magmen gibt.Das basaltische Magma, vom Sima stammend, und das rhyolitische Magma aus der oberen Sial-Kruste. Die Vermischung dieser beiden Magmen und die zusätzliche Wirkung der Gravitation und Pneumatolyse erklären auf natürliche Weise die Gesamtheit der geochemischen Phänomene des kontinentalen Vulkanismus.

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Metamorphism and Structure of Penfold Creek Area, near Quesnel Lake, British Columbia

The Quesnel Lake area lies within the Omineca Crystalline Belt,and is underlain by the northern extremity of the Shuswap MetamorphicComplex. Closely spaced and steeply dipping isograds mark themargins of the metamorphic belt. In the Penfold Creek area onlyone and one-half miles separate the biotite and sillimaniteisograds. Related to this sharp increase in metamorphic gradethere is a marked change in the fold style. In the chloritezone are similar folds, showing a strong axial-plane cleavage,and tight refolded isoclines dominate in the sillimanite zone.Three periods of deformation and two periods of prograde metamorphismhave been recognized, with the first metamorphic period beingassociated with Phase 2 deformation and the second being post-Phase2. Regression analysis of possible mineral reactions in these rocksshows that they formed under conditions of a gradient in temperatureand possibly H₂O activity, and that most of the assemblages,although containing many phases, have at least two degrees offreedom. Thermodynamic analysis of mineral equilibria indicatesthat equilibrium was closely approached between solid solutionsinvolving garnet, plagioclase, biotite, white mica, and staurolitein the presence of Al₂SiO₅, quartz, and H₂O. The conditionsof metamorphism of rocks containing Al₂SiO₅ are estimated tobe 7000 ± 1500 bars, 680 ± 30 °C, activityof H₂O = 0.80 (approx.). Partial melting did not occur becauseof the reduced activity of H₂O. ^*Present address: Overseas Division, Institute of Geological Sciences, 5 Princes Gate, London SW7, England.     

The electrification of flowing gases by mechanical abrasion of mineral surfaces

In the past, a number of workers have shown that both charged and neutral particles are released from inorganic materials during fracture and abrasion. In this work we show that charge can be transported by electrification of flowing gases over a surface undergoing abrasion. These results are relevant to possible mechanisms of a number of observed electrical phenomena associated with fault motion and earthquake activity. Received: 14 July 1997 / Revised, accepted: 2 January 1998     

Evaluation of one-dimensional in situ leaching processes

A methodology to characterizing processes of in situ leaching is developed to investigate various parameters that may affect the recovery of a valuable mineral and assure a successful application of the in situ leaching technology. The governing equations of in situ leaching processes for the one-dimensional case are solved both analytically and numerically for both the consumption rate of a lixiviant and the production rate of a target mineral. A numerical simulator, which is developed to evaluate coupled effects among leaching kinetics, solution flow and transport of the dissolved mineral species in saturated ore deposits, is validated against the steady-state solutions and applied to investigate the transient effects of various parameters on the mineral recovery. Results from the evaluation indicate that there exists an optimal flow velocity range of leach solution for the effective leaching of a particular ore deposit. The determination of this optimal leaching velocity may become a key to the design of a real in situ leach mine. Results of the parameter sensitivity study illustrate the relative importance of other parameters such as porosity, ore grade, and reaction rate. Copyright © 1999 John Wiley & Sons, Ltd.     

Geochronology of zircon megacrysts from nepheline-bearing gneisses as constraints on tectonic setting: implications for resetting of the U-Pb and Lu-Hf isotopic systems

Nepheline-bearing gneisses from the 75 km² Tambani body in the Mozambique Belt of southern Malawi, are miaskitic biotite-nepheline monzodiorites, reflecting an absence of K-feldspar, alkali amphiboles or pyroxenes, and contain euhedral zircon megacrysts up to 5 cm across. The zircons contain U = 1–1,860 ppm, Th = 0–2,170 ppm and Y = 400–1,100 ppm, and very low concentrations of all other measured trace elements except Hf (HfO₂ = 0.53–0.92 wt. %). Cathodoluminescence images reveal oscillatory sector growth zoning and no evidence for xenocrystic cores, indicating that the zircons represent primary magmatic crystallization products that have survived amphibolite grade metamorphism. U-Pb isotopic analyses (by TIMS) yield an upper intercept age of 730 ± 4 Ma (MSWD = 1.7), which we interpret as the time of magmatic crystallization of the zircons. This is coincident with 11 SHRIMP spot analyses, which yield a mean age of 729 ± 7 Ma (MSWD = 0.37). Metamorphism, at 522 ± 17 Ma as suggested by monazite, caused partial Pb-loss during local recrystallization of zircon. Lu-Hf isotopic data for three whole-rock samples of nepheline-bearing gneiss are collinear with those for zircon megacrysts, and correspond to an age of 584 ± 17 Ma (MSWD = 0.37. We interpret the Lu-Hf array to represent a mixing line defined by the Hf isotopic signature of primary zircon and that of the rock-forming minerals reset during metamorphic (re-)crystallization; hence the 584 Ma age is likely geologically meaningless. Given the well-defined association of nepheline syenites (and phonolitic volcanic equivalents) with continental rifting, we suggest that the Tambani body represents a magmatic product formed at 730 Ma during the break-up of the Rodinia supercontinent. The 522 Ma age is akin to other Pan-African metamorphic ages that record collisional suturing events during the final assembly of Gondwana. Zircon-bearing nepheline gneisses thus preserve a record of intra-continental rifting and of continental collision in southern Malawi.