Co-management of landfill leachate concentrate with brick waste by solidification/stabilization treatment

The treatment of landfill leachate by reverse osmosis (RO) generates huge volumes of heavily polluted concentrate that has to be properly treated before its discharge into the environment. The aim of this work was to assess the solidification/stabilization (S/S) treatment of the leachate concentrate (LC) for chemical/physical immobilization of contaminants and for obtaining durable monolithic matrix suitable for storage, landfilling, or use. In addition, the possible use of brick waste as a partial replacement of natural aggregates used for S/S process was investigated. Concrete mixtures were prepared using local PC, sand, gravel, and tap water/LC. The substitution of coarse aggregate material by brick waste was examined for the replacement ratios 25, 50, and 75%. Hardened concrete specimens were subject to compressive test as well as flexural strength test at 7 and 28 days. Besides, a leaching test was performed, and the collected eluates were analyzed for pH, total dissolved solids, chemical oxygen demand, chlorides, sulfates, phosphorus, and heavy metals. The aggregate replacement with brick waste showed various trends according to the substituted fraction size and ratio. A 28-day compressive strength of more than 25 MPa was obtained even at 50% simultaneous substitution of PC, gravel, and sand. Leaching test analysis confirmed that S/S could be a successful treatment for RO LC decreasing most of the pollutants to comply with landfilling criteria, except for chromium known to be mobile at high pH. Furthermore, the substitution of natural aggregates with brick waste revealed the possibility to cast valuable masonry units. However, a long-term assessment is still needed to ensure the mechanical and chemical stability/durability of concrete.     

Asia-Pacific mussel watch: monitoring contamination of persistent organochlorine compounds in coastal waters of Asian countries

Contamination of persistent organochlorines (OCs) such as PCBs (polychlorinated biphenyls), DDT and its metabolites (DDTs), HCH (hexachlorocyclohexane) isomers (HCHs), chlordane compounds (CHLs), and HCB (hexachlorobenzene) were examined in mussels collected from coastal waters of Asian countries such as Cambodia, China, Hong Kong, India, Indonesia, Japan, Korea, Malaysia, Philippines, Far East Russia, Singapore, and Vietnam in 1994, 1997, 1998, 1999, and 2001 to elucidate the contamination status, distribution and possible pollution sources and to assess the risks on aquatic organisms and human. OCs were detected in all mussels collected from all the sampling sites investigated. Considerable residue levels of p,p(')-DDT and alpha-HCH were found in mussels and the concentrations of DDTs and HCHs found in mussels from Asian developing countries were higher than those in developed nations suggesting present usage of DDTs and HCHs along the coastal waters of Asian developing countries. On the other hand, lower concentrations of PCBs detected in mussels from Asian developing countries than those in developed countries indicate that PCBs contamination in mussels is strongly related to industrial and activities. To our knowledge, this is a first comprehensive report on monitoring OCs pollution in the Asia-Pacific region.     

Mapping groundwater recharge potential zones in arid region using GIS and Landsat approaches,southeast Tunisia

The rapid growth of population and agricultural and industrial activities has caused an increase in demand on the Jeffara aquifers of Gabes (southeast Tunisia). In fact, the over-pumping of this aquifer system has resulted in water-level declines ranging from 0.25 to 1 m/year during the past three decades. The aim of this study is to identify favourable artificial recharge sites of this aquifer system based on the combined use of remotely sensed data, a geographic information system (GIS), the Shuttle Radar Topography Mission (SRTM) product and a multiple criteria decision making (MCDM) technique. The delineation of artificial recharge zones shows high to moderate potential for groundwater recharge (40%) in the Gabes region, with high precision of good potential proposed sites. Recharge processes need to account for natural conditions and ecosystems.     

Permeability of Municipal Solid Waste in Bioreactor Landfill with Degradation

Bioreactor landfills are operated for rapid stabilization of waste, increased landfill gas generation for cost-effective energy recovery, gain in landfill space, enhanced leachate treatment, and reduced post closure maintenance period. The fundamental process of waste stabilization in bioreactor landfill is recirculation of generated leachate back into the landfills. This creates a favorable environment for rapid microbial decomposition of the biodegradable solid waste. In order to better estimate the generated leachate and design of leachate recirculation system, clear understanding of the permeability of the Municipal Solid Waste (MSW) with degradation and the factors influencing the permeability is necessary. The objective of the paper is to determine the changes in hydraulic properties of MSW in bioreactor landfill with time and decomposition. Four small-scale bioreactor landfills were built in laboratory and samples were prepared to represent each phase of decomposition. Then, the changes in hydraulic properties of MSW in bioreactor landfill with time and decomposition were determined. A series of constant head permeability tests were performed on the samples generated in laboratory scale bioreactor landfills to determine variation of permeability of MSW with degradation. The test results indicated that the permeability of MSW in bioreactor landfills decreases with decomposition. Based on the test results, the permeability of MSW at the first phase of degradation was estimated as 0.0088 cm/s at density 700 kg/m³. However, with degradation, permeability decreased to 0.0013 cm/s at the same density, for MSW at Phase IV.     

Geochemical characteristics of Holocene sediments from Chuadanga district,Bangladesh: Implications for weathering,climate, redox conditions,provenance and tectonic setting

The present research deals with the geochemical characteristics of the Holocene sediments from Alamdanga area, Chuadanga district, Bangladesh. Main goals of the study are to delineate source rock characteristics, degree of chemical weathering and sorting processes and behavior of redox conditions during deposition of the sediments. Geochemical characteristics of the sediments show comparatively a wide variation in accordance with stratigraphy in their major element contents （e.g. SiO2 69.46-82.13, A1203 2.28-8.88 in wt%）, reflecting the distinctive provenance and in part an unstable period in terms of tectonic activity. Geochemical classification of the sediments shows mostly sub-arkose with few sub-litharenites. Some major and trace elements display comprehensible correlation with A1203 confirming their possible hydraulic fraetionation. The chemical index of alteration （CIA＊）, W＊ index, index of compositional variability （ICV）, plagioclase index of alteration （PIA＊） values and the ratio of SIO2/Al2O3, suggest low degrees of chemical weathering in the source areas as well as immature to moderately mature the sediments. The sediments suggest semi-arid climatic trends within oxic deltaic depositional conditions during the Holocene, at 3-12 ka. Whole rock geochemistry and discrimination diagrams demonstrate the continental signature derivatives, which might have been derived from the felsic to intermediate igneous rocks （granitic plutonic rocks） as well as from quartzose sedimentary/metamorphic provenance. These typical sources are present in a vast region of the Himalayan belt and catchment areas of Ganges. The tectonic setting of the sediments demarcates typically passive margin with slightly continental arc system.