Assessment of contaminants in Dubai coastal region, United Arab Emirates

Coastal uses and other human activities have inevitably impinged on the Gulf environment; therefore, these regions require continuous monitoring. The investigated area covered the maximum fragments of Dubai coastal region in the Arabian Gulf. The determination of major oxides and trace metal concentrations in Dubai sediments revealed three heavily and moderately contaminated regions. One is in the far northeastern part at Al-Hamriya Sts 1–3 and contaminated by Fe, Cu, Pb, and Zn; the second is in the mid-northeastern part at Dry Docks and contaminated by Cu, Ni, Pb, and Zn; and finally, the third is in the near southwestern part at Dubal and contaminated by Fe, Mg, Cr, Ni, and Zn. Al-Hamriya St 3 represented the highest values of Cu, Pb, and Zn, whereas Dubal exhibited the maximum values of Fe, Mg, Ba, Cr, Mn, Ni, and V. The anthropogenic discharge and natural deposits are the main sources of contamination. In general, all trace and major elements showed the minimal levels at Jebel Ali Sanctuary (Sts 11, 12, 13) except for Sr and Ca, which showed their maximum values. The highest concentrations of Ca and Sr are mainly attributed to carbonate gravel sands and sands, which cover most stations. Each of V and Ni showed negative correlation with TPH, which may be indicated that the source of oil contamination in the region is not related to crude oil but mostly attributable to anthropogenic sources. The significant positive correlation, which was found between trace metals and TOC indicates that organic matter plays an important role in the accumulation of trace metals in case of Cu, Zn, and Pb.     

Response of soil aggregate disintegration to the different content of organic carbon and its fractions during splash erosion

Aggregate disintegration is a critical process in soil splash erosion. However, the effect of soil organic carbon (SOC) and its fractions on soil aggregates disintegration is still not clear. In this study, five soils with similar clay contents and different contents of SOC have been used. The effects of slaking and mechanical striking on splash erosion were distinguished by using deionized water and 95% ethanol as raindrops. The simulated rainfall experiments were carried out in four heights (0.5, 1.0, 1.5 and 2.0 m). The result indicated that the soil aggregate stability increased with the increases of SOC and light fraction organic carbon (LFOC). The relative slaking and the mechanical striking index increased with the decreases of SOC and LFOC. The reduction of macroaggregates in eroded soil gradually decreased with the increase of SOC and LFOC, especially in alcohol test. The amount of macroaggregates (>0.25 mm) in deionized water tests were significantly less than that in alcohol tests under the same rainfall heights. The contribution of slaking to splash erosion increased with the decrease of heavy fractions organic carbon. The contribution of mechanical striking was dominant when the rainfall kinetic energy increased to a range of threshold between 9 J m⁻² mm⁻¹ and 12 m⁻² mm⁻¹. This study could provide the scientific basis for deeply understanding the mechanism of soil aggregates disintegration and splash erosion.     

One-dimensional consolidation of soil under multistage load based on continuous drainage boundary

In engineering practice, a rapid loading rate can result in ground failure when the strength of soft soils is relatively low, and a multistage loading scheme is always utilized to deal with this situation. Firstly, under a multistage load and the continuous drainage boundary, an analytical solution of excess pore-water pressure and consolidation degree is obtained by virtue of the superposition formula of excess pore-water pressure, and a more general continuous drainage boundary under arbitrary time-dependent load is developed. Then, a comparison with existing analytical solutions is conducted to verify the present solution. A preliminary attempt on applying the continuous drainage boundary into the finite element model is made, and the feasibility of the numerical model for the one-dimensional consolidation under the continuous drainage boundary is verified by comparing the results calculated by FEM with that from present analytical solution. Finally, the consolidation behavior of soil is investigated in detail for different int erface parameters or loading scheme. The results show that, in land reclamation projects, a horizontal drain should be placed close to the boundary with a smaller interface parameter to improve the consolidation efficiency. The degree of consolidation is also related to the applied time-dependent load and interface parameters.     

An original semi‐discrete approach to assess gas conductivity of concrete structures

For civil engineering structures with a tightness role, structural permeability is a key issue. In this context, this paper presents a new proposition of a numerical modelling of leakage rate through a cracked concrete structure undergoing mode I cracking. The mechanical state of the material, considered in the framework of continuum mechanics based on finite element modelling, is described by means of the stress‐based nonlocal damage model which takes into account the stress state and provides realistic local mechanical fields. A semi‐discrete method based on the strong discontinuity approach to estimate crack opening is then considered in the post‐treatment phase. Using a Poiseuille's like relation, the coupling between the mechanical state of the material and its dry gas conductivity is performed. For validation purposes, an original experimental campaign is conducted on a dry concrete disc loaded in a splitting setup. During the loading, gas conductivity and digital image correlation analysis are performed. The comparison with the 3D experimental mechanical global response highlights the performance of the mechanical model. The comparison between crack openings measured by digital image correlation and estimated by the strong discontinuity method shows a good agreement. Finally, the results of the semi‐discrete approach coupled with the gas conductivity compared with experimental data show a good estimation of the structural conductivity. Consequently, if the mechanical problem is well modelled at the global scale, then the proposed approach provides good estimation of gas conductivity. Copyright © 2016 John Wiley & Sons, Ltd.     

Hydrology and geomorphology of the Upper White Nile lakes and their relevance for water resources management in the Nile basin

Remote sensing data and digital elevation models were utilized to extract the catchment hydrological parameters and to delineate storage areas for the Ugandan Equatorial Lakes region. Available rainfall/discharge data are integrated with these morphometric data to construct a hydrological model that simulates the water balance of the different interconnected basins and enables the impact of potential management options to be examined. The total annual discharges of the basins are generally very low (less than 7% of the total annual rainfall). The basin of the shallow (5 m deep) Lake Kioga makes only a minor hydrological contribution compared with other Equatorial Lakes, because most of the overflow from Lake Victoria basin into Lake Kioga is lost by evaporation and evapotranspiration. The discharge from Lake Kioga could be significantly increased by draining the swamps through dredging and deepening certain channel reaches. Development of hydropower dams on the Equatorial Lakes will have an adverse impact on the annual water discharge downstream, including the occasional reduction of flow required for filling up to designed storage capacities and permanently increasing the surface areas of water that is exposed to evaporation. On the basis of modelling studies, alternative sites are proposed for hydropower development and water storage schemes. Copyright © 2012 John Wiley & Sons, Ltd.     

Root‐related rhodochrosite and concretionary siderite formation in oxygen‐deficient conditions induced by a ground‐water table rise

Sedimentological, mineralogical, stable carbon and oxygen isotope determinations and biomarker analyses were performed on siderite concretions occurring in terrestrial silts to understand their formation and to characterize the sedimentary and diagenetic conditions favouring their growth. High δ¹³C values (6·4‰ on average) indicate that siderite precipitated in an anoxic environment where bacterial methanogenesis operated. The development of anoxic conditions during shallow burial was induced by a change in sedimentary environment from flood plain to swamp, related to a rise of the ground‐water table. Large amounts of decaying plant debris led to efficient oxygen consumption within the pore‐water in the peat. Oxygen depletion, in combination with a decrease in sedimentation rate, promoted anoxic diagenetic conditions under the swamp and favoured abundant siderite precipitation. This shows how a change in sedimentary conditions can have a profound impact on the early‐diagenetic environment and carbonate authigenesis. The concretions contain numerous rhizoliths; they are cemented with calcium‐rhodochrosite, a feature which has not been reported before. The rhodochrosite cement has negative δ¹³C values (?16·5‰ on average) and precipitated in suboxic conditions due to microbial degradation of roots coupled to manganese reduction. The exceptional preservation of the epidermis/exodermis and xylem vessels of former root tissues indicates that the rhodochrosite formed shortly after the death of a root in water‐logged sediments. Rhodochrosite precipitated during the initial stages of concretionary growth in suboxic microenvironments within roots, while siderite cementation occurred simultaneously around them in anoxic conditions. These suboxic microenvironments developed because oxygen was transported from the overlying oxygenated soil into sediments saturated with anoxic water via roots acting as permeable conduits. This model explains how separate generations of carbonate cements having different mineralogy and isotopic compositions, which would conventionally be regarded as cements precipitated sequentially in different diagenetic zones during gradual burial, can form simultaneously in shallow burial settings where strong redox gradients exist around vertically oriented permeable root structures.     

Study of horizontal drain effect on slope stability

Slope failure usually occurs when soil particles are unable to build a strong bond with each other and become loose because of the presence of water. Water pressure weakens the ties between the particles and they tend to slip. Therefore, this study focused on the use of horizontal drains to reduce water entry and control the ground water level as a method of slope stabilization. Several previous studies have shown that the use of horizontal drains to lower the water level in soil is one of the fastest and cheapest slope stabilization methods. The main objective of this study is to analyze the effect of horizontal drains on slope stability. Information on slope condition during the landslides which happened at Precinct 9, Putrajaya, Malaysia was used for analytical simulation. Seep/W and Slope/W analyses were carried out with GeoStudio version 2007 software. Slopes with and without horizontal drains were then compared in terms of groundwater level and factor of safety (FOS) values. Scenarios were created for seven types of soil namely: residual, clay, silt, loam, sandy loam, sandy clay loam, and silt clay loam for a case wise analysis. The effect of daily steady rainfall and realcondition rainfall was studied. These cases were studied to find the effectiveness of horizontal drains as a slope stabilization tool. The results revealed that when a drain was installed on a slope, the groundwater level dropped immediately and the safety factor of the slope increased. Sandy loam (sL) soil was identified as the best candidate for a horizontal drain. Its highly saturated hydraulic conductivity Ks facilitated groundwater drain through the horizontal drain effectively. Silt clay loam (scL) soil was identified as the least effective candidate.     

Sedimentologic attributes of the Proterozoic siliciclastic packages of the Garhwal–Kumaun Lesser Himalaya,India: Implication for their relationship and palaeobasinal conditions

The present work addresses the long-standing issues on the characterization aspect of the Proterozoic siliciclastic successions exposed in the central part of the Lesser Himalaya, restricted between the Main Boundary Thrust (MBT) and the Main Central Thrust (MCT). Geologic, sedimentologic, and petrographic study divides the Lesser Himalaya in two zones- northern Palaeo- Mesoproterozoic Inner Lesser Himalayan (ILH) and southern Neoproterozoic Outer Lesser Himalayan (OLH) zones. The major lithofacies recognized from the zones are - (i) coarse grained siliciclastic (CGS), (ii) interbedded medium and fine-grained siliciclastic (IMFS), (iii) argillite (ARG), and (iv) siliciclastic–argillite rhythmites (SAR). Amongst all these facies, the nearshore IMFS facies shows consistent presence in both OLH and ILH zones. From the facies distribution pattern, a northwest–southeasterly trending palaeo- shoreline has been envisaged. The CGS facies in the ILH hints towards an alluvial fan setting during 1.8 Ga rifting phase associated with penecontemporaneous basic magmatism. Compositionally, the siliciclastics of both the zones (ILH and OLH) are arenite and wacke types with minimal variation in their detrital proportions, derived from the early Proterozoic (between 2.4-1.6Ga) Aravalli-Delhi Supergroup provenance. Nearly matching types and content of detrital modes and the lithofacies pattern of the ILH and OLH siliciclastics probably conclude the derivation from the rising (nearby) Aravalli-Delhi orogen and deposition in a foreland like situation.