Processes controlling very low sedimentation rates on the continental slope of the Gonone-Orosei canyon system,NE Sardinia—terrestrial and oceanic significance

The narrow shelf and upper slope immediately above the Gonone canyon head off NE Sardinia represent areas of very low sedimentation rates. Along the sides of the canyon head (1,600 m water depth), the sediment deposits are homogeneous but show alternating light-grey intervals rich in carbonate and dark-grey ones rich in organic matter, possibly related to distal turbidite processes. Deposits older than 50,000 years are already encountered at core depths of 2.50 m, the sedimentation rates varying from 6–21 cm/10³ years in the lower parts of two cores and from 1.5–3 cm/10³ years in the upper parts. At about 35,000 years BP, both cores show a simultaneous drop in sedimentation rate by a factor of 3, probably in response to local mechanisms of channel avulsion. Lithological, mineralogical and geochemical properties reveal the environmental factors which are responsible for the extremely slow sediment accumulation. The southernmost sector of the coast, and partly also of the shelf, consists of Jurassic limestones which supply only small amounts of fine-grained material transported in suspension. During the last sea-level highstand, the accumulation of the Cedrino River pro-delta remained restricted to the coast, the low siliciclastic sediment yields resulting in poor shelf sediment trapping. The present morphology of the canyon head prevented the occurrence of gravity processes in the deeper part of the canyon system, including the coring sites. Accordingly, deposition was mainly fed by hemipelagic material of planktonic origin, together with only moderate terrigenous inputs. On a wider late Pleistocene timescale, seismic data indicate the occurrence of a coarse-grained, layered turbidite facies, implying a very different architecture of the canyon drainage system probably prior to 60,000 years BP.     

Phase-equilibrium geobarometers for silicic rocks based on rhyolite-MELTS. Part 2: application to Taupo Volcanic Zone rhyolites

Constraining the pressure of crystallisation of large silicic magma bodies gives important insight into the depth and vertical extent of magmatic plumbing systems; however, it is notably difficult to constrain pressure at the level of detail necessary to understand shallow magmatic systems. In this study, we use the recently developed rhyolite-MELTS geobarometer to constrain the crystallisation pressures of rhyolites from the Taupo Volcanic Zone (TVZ). As sanidine is absent from the studied deposits, we calculate the pressures at which quartz and feldspar are found to be in equilibrium with melt now preserved as glass (the quartz +1 feldspar constraint of Gualda and Ghiorso, Contrib Mineral Petrol 168:1033. doi: 10.1007/s00410-014-1033-3. 2014). We use glass compositions (matrix glass and melt inclusions) from seven eruptive deposits dated between ~320 and 0.7 ka from four distinct calderas in the central TVZ, and we discuss advantages and limitations of the rhyolite-MELTS geobarometer in comparison with other geobarometers applied to the same eruptive deposits. Overall, there is good agreement with other pressure estimates from the literature (amphibole geobarometry and H₂O–CO₂ solubility models). One of the main advantages of this new geobarometer is that it can be applied to both matrix glass and melt inclusions—regardless of volatile saturation. The examples presented also emphasise the utility of this method to filter out spurious glass compositions. Pressure estimates obtained with the new rhyolite-MELTS geobarometer range between ~250 to ~50 MPa, with a large majority at ~100 MPa. These results confirm that the TVZ hosts some of the shallowest rhyolitic magma bodies on the planet, resulting from the extensional tectonic regime and thinning of the crust. Distinct populations with different equilibration pressures are also recognised, which is consistent with the idea that multiple batches of eruptible magma can be present in the crust at the same time and can be tapped simultaneously by large eruptive events.     

Arsenic Cycling in Hydrocarbon Plumes: Secondary Effects of Natural Attenuation

Monitored natural attenuation is widely applied as a remediation strategy at hydrocarbon spill sites. Natural attenuation relies on biodegradation of hydrocarbons coupled with reduction of electron acceptors, including solid phase ferric iron (Fe(III)). Because arsenic (As) adsorbs to Fe‐hydroxides, a potential secondary effect of natural attenuation of hydrocarbons coupled with Fe(III) reduction is a release of naturally occurring As to groundwater. At a crude‐oil‐contaminated aquifer near Bemidji, Minnesota, anaerobic biodegradation of hydrocarbons coupled to Fe(III) reduction has been well documented. We collected groundwater samples at the site annually from 2009 to 2013 to examine if As is released to groundwater and, if so, to document relationships between As and Fe inside and outside of the dissolved hydrocarbon plume. Arsenic concentrations in groundwater in the plume reached 230 µg/L, whereas groundwater outside the plume contained less than 5 µg/L As. Combined with previous data from the Bemidji site, our results suggest that (1) naturally occurring As is associated with Fe‐hydroxides present in the glacially derived aquifer sediments; (2) introduction of hydrocarbons results in reduction of Fe‐hydroxides, releasing As and Fe to groundwater; (3) at the leading edge of the plume, As and Fe are removed from groundwater and retained on sediments; and (4) downgradient from the plume, patterns of As and Fe in groundwater are similar to background. We develop a conceptual model of secondary As release due to natural attenuation of hydrocarbons that can be applied to other sites where an influx of biodegradable organic carbon promotes Fe(III) reduction.     

The Geminga fraction

Radio-quiet γ-ray pulsars like Geminga may account for a number of the unidentified EGRET sources in the Galaxy. The number of Geminga-like pulsars is very sensitive to the geometry of both the γ-ray and radio beams. Recent studies of the shape and polarization of pulse profiles of young radio pulsars have provided evidence that their radio emission originates in wide cone beams at altitudes that are a significant fraction (1–10%) of their light cylinder radius. Such wide radio emission beams will be visible at a much larger range of observer angles than the narrow core components thought to originate at lower altitude. Using 3D geometrical modeling that includes relativistic effects from pulsar rotation, we study the visibility of such radio cone beams as well as that of the γ-ray beams predicted by slot gap and outer gap models. From the results of this study, one can obtain revised predictions for the fraction of Geminga-like, radio quiet pulsars present in the γ-ray pulsar population.      

Can the optical very large array be coupled with the JNLT?

Coupling the JNLT with the Keck telescope is of considerable interest. Further enhancement may be possible with auxiliary small telescopes, as planned for ESO's VLT. Current plans for installing the optical very large array at Mauna Kea provide opportunities for extra OVLA telescopes near the JNLT.A coudé field slicer is proposed for interferometric observing of a reference star together with the main object. Additions to the JNLT coudé spectrograph are also suggested for use as a speckle camera with multiple spectral channels.Paper presented at the Symposium on the JNLT and Related Engineering Developments, Tokyo, November 29–December 2, 1988.     

An XPEEM study of structural cation distribution in swelling clays. I. Synthetic trioctahedral smectites

X-PEEM images and XPS were collected on isolated layers of three synthetic swelling clays, one hectorite and two saponites with various charge, recording the Si(2p), Al(2p) and Mg(2p) core level spectra from the clay sheets. Spectra were fitted to determine the different components of the core levels. Due to their large full width at half maximum, Si XPS spectra were fitted using two to three doublets. It appears that, for a given clay mineral, Si, Al and Mg binding energies (BE) were constant, for all the observed layers. However, variations of the Si BE were observed depending on the nature of the mineral investigated. The various components obtained from the fit of Si spectra could be assigned to different substitution rates; binding energy shifting to lower values with substitution increase in the layer. Furthermore, variations in Si BE according to charge location were assigned to the influence of exchangeable cation.     

Oxygen isotope analyses of fine silica grains using laser-extraction technique: Comparison with oxygen isotope data obtained from ion microprobe analyses and application to quartzite and silcrete cement investigation

The laser fluorination technique reported here for analyzing the oxygen isotope composition (δ¹⁸O) of fine quartz size fractions 50-20, 20-10, 10-5, 5-2, 2-1 and <1 μm has been validated by comparison with the ion microprobe technique. It yields accurate δ¹⁸O data with an external precision better than 0.15‰. This is a significant methodological improvement for isotopic studies dealing with materials such as soil or biogenic oxides and silicates: particles are often too small and recovered in insufficient amount to be easily handled for ion microprobe analysis. Both techniques were used to investigate δ¹⁸O composition of a Cretaceous quartzite and silcrete sequence from the South-East of France. Quartzite cements average 31.04 ± 1.93‰. They formed from Mid-Cretaceous seawater. Higher in the series, silcretes cements average 26.66 ± 1.36‰. They formed from Upper- or post-Upper-Cretaceous soil water and groundwater. Oxygen isotope data show that the silicification steps from one mineralogical phase to another and from one layer to another (including from an upper pedogenic silcrete to a lower groundwater silcrete) occurred in a closed or weakly evaporating hydrological system.     

Improving Kirchhoff migration with repeated local plane-wave imaging? A SAR-inspired signal-processing approach in prestack depth imaging

A local plane-wave approach of generalized diffraction tomography in heterogeneous backgrounds, equivalent to Kirchhoff summation techniques when applied in seismic reflection, is re-programmed to act as repeated synthetic aperture radar (SAR) imaging for seismic prestack depth migration. Spotlight-mode SAR imaging quickly provides good images of the electromagnetic reflectivity of the ground via fast Fourier transform (FFT)-based signal processing. By calculating only the Green's functions connecting the aircraft to the centre of the illuminated patch, scattering structures around that centre are also recovered. SAR technology requires us to examine seismic imaging from the local point of view, where the quantity and quality of the available information at each image point are what are important, regardless of the survey geometry. When adapted to seismics, a local image of arbitrary size and sampling is obtained by FFT of seismic energy maps in the scattering wavenumber domain around each node of a pre-calculated grid of Green's functions. These local images can be used to generate a classic prestack depth-migrated section by collecting only their centres. However, the local images also provide valuable information around the centre, as in SAR. They can therefore help to pre-analyse prestack depth migration efficiently, and to perform velocity analysis at a very low cost. The FFT-based signal-processing approach allows local, efficient and automatic control of anti-aliasing, noise and resolution, including optimized Jacobian weights. Repeated local imaging could also be used to speed up migration, with interpolation between local images associated with a coarse grid of Green's functions, as an alternative to interpolation of Green's functions. The local images may, however, show distortions due to the local plane-wave approximation, and the velocity variations across their frame. Such effects, which are not necessarily a problem in SAR, should be controlled and corrected to further enhance seismic imaging. Applications to realistic models and to real data show that, despite the distortion effects, the local images can yield similar information to prestack depth migration, including common-image-point gathers for velocity analyses and AVO/AVA effects, at a much lower cost when a small target is considered.