Fluid-driven low-grade metamorphism in polydeformed rocks of Avalonia (Arisaig Group, Nova Scotia, Canada)

The Lower Silurian??Lower Devonian Arisaig Group (Antigonish Highlands) in the Canadian Appalachians is a sequence of shallow marine strata deposited after the accretion of Avalonia to Baltica during the closure of the Iapetus Ocean. Deformation of the strata is widely attributed to the Devonian Acadian orogeny and produced shallowly plunging regional folds and a cleavage of varying penetrativity. Phyllosilicate minerals from the finest-grained rocks exhibit very low-grade (diagenetic-anchizone) metamorphic conditions. X-ray diffraction study reveals that the sampled rocks contain quartz, K-white mica, chlorite, and feldspars; illite?Csmectite and chlorite?Csmectite mixed-layers are common but Na?CK mica and kaolinite occur only in some samples. The identification of illite?Csmectite mixed-layers in diagenetic samples, with Kübler Index >0.50 ??°2?? and the highly heterogeneous b-cell dimension of the K-white micas are in agreement with the variable chemical composition of dioctahedral micas, which present low illitic substitution and variable phengitic content. The spatial variation in the above crystal-chemical parameters was plotted along a NW?CSE composite cross section across the regional folds. No correlation was found between the metamorphic conditions and either the stratigraphic depth or the strain values measured by phyllosilicates orientation analyses, as a function of the penetrativity of the cleavage. However, the metamorphic grade generally increases towards the Hollow Fault, and is highest in samples located within a 1?km corridor from the fault surface. Incipient cleavage is observed in the anchizonal samples located in the vicinity of the Hollow Fault and in some of the diagenetic samples, indicating cleavage development under low temperatures (<200?oC). These relationships, together with regional syntheses, suggest low-grade metamorphism post-dated regional folding and was coeval with Late Carboniferous dextral movement along the Hollow Fault. Fluid circulation associated with movement along this major fault may be the driving mechanism for the increasing metamorphism towards it.     

Pollen‐ and diatom based environmental history since the Last Glacial Maximum from the Andean core Fúquene‐7, Colombia

The late Pleistocene–Holocene ecological and limnological history of Lake Fúquene (2580 m a.s.l.), in the Colombian Andes, is reconstructed on the basis of diatom, pollen and sediment analyses of the upper 7 m of the core Fúquene‐7. Time control is provided by 11 accelerator mass spectrometry (AMS) ¹⁴C dates ranging from 19 670 ± 240 to 6040 ± 60 yr BP. In this paper we present the evolution of the lake and its surroundings. Glacial times were cold and dry, lake‐levels were low and the area was surrounded by paramo and subparamo vegetation. Late‐glacial conditions were warm and humid. The El Abra Stadial, a Younger Dryas equivalent, is reflected by a gap in the sedimentary record, a consequence of the cessation of deposition owing to a drop in lake‐level. The early Holocene was warm and humid; at this time the lake reached its maximum extension and was surrounded by Andean forest. The onset of the drier climate prevailing today took place in the middle Holocene, a process that is reflected earlier in the diatom and sediment records than in the pollen records. In the late Holocene human activity reduced the forest and transformed the landscape. Climate patterns from the Late‐glacial and throughout the Holocene, as represented in our record, are similar to other records from Colombia and northern South America (the Caribbean, Venezuela and Panama) and suggest that the changes in lake‐level were the result of precipitation variations driven by latitudinal shifts of the Intertropical Convergence Zone. Copyright © 2003 John Wiley & Sons, Ltd.     

The influence of various seawater components on the buffer capacity for CO2

A series of experiments was performed using artificial seawater samples of increasing complexity, in order to identify, qualitatively and quantitatively, the contribution of main seawater components on the buffer capacity for CO₂.The results show that magnesium plays the most important role in the uptake, enhancing the capacity of the carbonate system alone by more than 100%.     

Lavras do Sul: A New Equilibrated Ordinary L5 Chondrite from Rio Grande do Sul,Brazil

The new Brazilian chondrite, Lavras do Sul, was found in 1985 at Lavras do Sul, Rio Grande do Sul State-Brazil (33°30′48″S; 53°54′65″W). It consists of a single mass weighing about 1 kg, covered by a black fusion crust with grayish interior. Four polished thin sections were prepared from a slice weighing 67 g on deposit at the Museu Nacional/UFRJ. It consists mostly of chondrules and chondrule fragments dispersed in a recrystallized matrix. Most chondrules are poorly defined and range in size from 300 to 2,000 μm, although some of them show distinct outlines, particularly when viewed under cross-polarized transmitted and reflected light. The texture of chondrules varies from non-porphyritic (e.g., barred-olivine, radial-pyroxene) to porphyritic ones (e.g., granular olivine as well as olivine-pyroxene). The meteorite contains mainly olivine (Fa_24.9), low-Ca pyroxene (Fs_22.6) and metal phases, with minor amounts of plagioclase, chromite and magnetite. Mössbauer Spectroscopy studies indicate that the metal phase is kamacite, tetrataenite and antitaenite. Veins of secondary iddingsite crosscut the thin section and some ferromagnesian silicates. The chemical composition indicates that Lavras do Sul is a member of the low iron L chondrite group. The poorly delineated chondritic texture with few well-defined chondrules, the occurrence of rare clinopyroxene and plagioclase (and maskelynite) with apparent diameters ranging from 5 to 123 μm led us to classify Lavras do Sul as an equilibrated petrologic type 5. The shock features of some minerals suggest a shock stage S3, and the presence of a small amount of secondary minerals such as iddingsite and goethite, a degree of weathering W₁. The meteorite name was approved by the Nomenclature Committee (Nom Com) of the Meteoritical Society (Meteoritic Bulletin Nº99).     

Isolated and mildly interacting spiral galaxies: Rotation curves and metallicities

We present the study of long slit spectra in the region ofHα emission line of a sample of 111 spiral galaxies with recognizable and well defined spiral morphology and with a well determined environmental status, ranging from isolation to non-disruptive interaction with satellites or companions. The form and properties of the rotation curves (RC) are considered as a function of the isolation degree, morphological type, t, and luminosity. The line ratios are used to estimate the metallicity of all the detected HII regions, thus producing a composite metallicity profile for different types of spirals. We have found that isolated galaxies (ISO) tend to be of later types and lower luminosity than the interacting galaxies (INT). The outer parts of the RC of ISO tend to be flatter than in INT, but they show similar relations between global parameters. The scatter of the Tully-Fisher (TF) relation defined by ISO is significantly lower than that of INT. The [NII]/Hα ratios, used as a metallicity indicator, show a clear trend between Z and t, with earlier spirals showing higher ratios; this trend is tighter when instead of t the gradient of the inner RC, G, is used; no trend is found with the change in interaction status. The Z-gradient of the disks depends on the type, being almost flat for early spirals, and increasing for later types. The [NII]/Hα ratios measured for disk HII regions of INT are higher than for normal/ISO objects, even if all the galaxy families present similar distributions of Hα Equivalent Width. This revised version was published online in August 2006 with corrections to the Cover Date.     

Structural Alignment Methods with Applications to Geospatial Ontologies

We consider the problem of enabling interoperability and information sharing among geospatial applications that use ontologies to describe their concepts and the relationships among them. We present two fully automatic alignment methods that use the graph structures of a pair of ontologies to establish their alignment, that is, the semantic correspondences between their concepts. We have tested our methods on geospatial ontologies pertaining to wetlands and four other pairs that belong to a repository that has been used in the Ontology Alignment Evaluation Initiative (OAEI). Using these ontologies, we have compared the effectiveness (precision and recall) of our methods against the Similarity Flooding Algorithm that was proposed by others and show that for each of the tested ontologies one of our methods is at least as effective as their method. We have tuned the performance of our methods by introducing a greedy approach that reduces the number of concepts that get compared. This approach reduces runtime by approximately 30% with a minor compromise to the effectiveness of the results. To further validate our approach, we participated in the OAEI competition to align a pair of ontologies, each with a few thousand concepts.     

Organotin levels in Nazaré canyon (west Iberian Margin, NE Atlantic) and adjacent coastal area

Organotin compounds (OTs) are ubiquitous in the marine environment and high concentrations (μg g(-1) range) in sediments from different coastal areas around the world have been reported. However, few reports have described the OTs contamination status in the offshore and deep sea environment. This work investigated organotin levels in Nazaré canyon for the first time. Levels of monobutyltin (MBT), dibutyltin (DBT), tributyltin (TBT), diphenyltin (DPT), triphenyltin (TPT), dioctyltin (DOT) and trioctyltin (TOT) were quantified in sediment samples from the upper flanks of the canyon and from the adjacent coastal area. TBT levels detected in the canyon flanks are about two to three orders of magnitude lower than those found in the coastal area. Nevertheless, when quantifiable, TBT levels in the canyon samples were higher than the Environmental Assessment Criteria set for TBT in sediments by the OSPAR Commission indicating that at those locations negative ecological impacts are likely to occur.     

Review of oil and HNS accidental spills in Europe: identifying major environmental monitoring gaps and drawing priorities

The European Atlantic area has been the scene of a number of extensive shipping incidents with immediate and potential long-term impacts to marine ecosystems. The occurrence of accidental spills at sea requires an effective response that must include a well executed monitoring programme to assess the environmental contamination and damage of the affected marine habitats. Despite a number of conventions and protocols developed by international and national authorities that focused on the preparedness and response to oil and HNS spills, much remains to be done, particularly in relation to the effectiveness of the environmental monitoring programmes implemented after oil and HNS spills. Hence, the present study reviews the status of the environmental monitoring programmes established following the major spill incidents over the last years in European waters, aiming at identifying the key monitoring gaps and drawing priorities for an effective environmental monitoring of accidental spills.