Organotin levels in Nazaré canyon (west Iberian Margin, NE Atlantic) and adjacent coastal area

Organotin compounds (OTs) are ubiquitous in the marine environment and high concentrations (μg g(-1) range) in sediments from different coastal areas around the world have been reported. However, few reports have described the OTs contamination status in the offshore and deep sea environment. This work investigated organotin levels in Nazaré canyon for the first time. Levels of monobutyltin (MBT), dibutyltin (DBT), tributyltin (TBT), diphenyltin (DPT), triphenyltin (TPT), dioctyltin (DOT) and trioctyltin (TOT) were quantified in sediment samples from the upper flanks of the canyon and from the adjacent coastal area. TBT levels detected in the canyon flanks are about two to three orders of magnitude lower than those found in the coastal area. Nevertheless, when quantifiable, TBT levels in the canyon samples were higher than the Environmental Assessment Criteria set for TBT in sediments by the OSPAR Commission indicating that at those locations negative ecological impacts are likely to occur.     

Review of oil and HNS accidental spills in Europe: identifying major environmental monitoring gaps and drawing priorities

The European Atlantic area has been the scene of a number of extensive shipping incidents with immediate and potential long-term impacts to marine ecosystems. The occurrence of accidental spills at sea requires an effective response that must include a well executed monitoring programme to assess the environmental contamination and damage of the affected marine habitats. Despite a number of conventions and protocols developed by international and national authorities that focused on the preparedness and response to oil and HNS spills, much remains to be done, particularly in relation to the effectiveness of the environmental monitoring programmes implemented after oil and HNS spills. Hence, the present study reviews the status of the environmental monitoring programmes established following the major spill incidents over the last years in European waters, aiming at identifying the key monitoring gaps and drawing priorities for an effective environmental monitoring of accidental spills.     

Distribution and thickness of sedimentary facies in the coastal dune, beach and nearshore sedimentary system at Maspalomas, Canary Islands

Numerous studies have shown that most beaches and coastal dune systems of the world are currently eroding but very few have investigated the combined sediment budgets of subaerial and nearshore submarine systems. In the case of the dune field of the Maspalomas Natural Special Reserve (in the south of Gran Canaria), the adjacent Maspalomas and El Inglés beaches and the adjacent submarine platform, the sediment budgets have been severely affected by erosion over the past few decades. The objectives of this study were to investigate the availability of sand within the modern sedimentary system, including the coastal dunes, the beaches and the submerged shelf, but also to assess local sediment sinks. An isopach map generated on the basis of topo-bathymetric data and seismic-reflection profiles revealed that sediment thickness varies from 0–22 m in the study area. Expanses of relatively low sediment thickness were identified in the south-western sector of the coastal dune field along Maspalomas beach, and in the nearshore region to the south of this beach. These localized sediment-deficit areas earmark Maspalomas beach as the most vulnerable shore strip threatened by erosion. The shallow seismic data also revealed that the submarine platform south of Maspalomas represents a marine terrace cut into an ancient alluvial fan, thus documenting an influence of the geomorphological heritage on the present-day morphodynamics. A side-scan sonar mosaic of this nearshore platform enabled the delimitation of areas covered by rock, boulders and gravel, vegetated sand patches and a mobile sand facies, the latter including ripple and megaripple fields. The megaripple field in a valley close to the talus of the marine terrace has been identified as a major sediment sink of the Maspalomas sedimentary system. It is fed by south-westerly storm-wave events. The sediment deficit in the coastal dune field and along Maspalomas beach can therefore only be explained by a currently faster loss of sediment to an offshore sink than can be compensated by the supply of sand from outside the system.     

Pollen sequence from the Chilean Lake District during the Llanquihue glaciation in marine Oxygen Isotope Stages 4–2

Pollen stratigraphy of a core taken from a fen at Fundo Nueva Braunau (40°17.49′S, 73°04.83′W), situated 2 km beyond the western border of Llanquihue‐age glacial drift, spans an age range from an estimated 60 000–70 000 BP to about 14 000 ¹⁴C yr BP (marine Oxygen Isotope Stages 4–2). The location at present is in the contact zone of Valdivian Evergreen Forest and Lowland Deciduous Beech Forest. Early and late in the pollen record, as indicated by assemblages of southern beech (Nothofagus dombeyi type) and grass (Gramineae), the site was located in Subantarctic Parkland. Intervening assemblages represent expansion of Valdivian–North Patagonian Evergreen Forest (> 49 355 to about 40 000 ¹⁴C yr BP) and North Patagonian Evergreen Forest–Subantarctic Parkland (approximately 40 000 to 30 000 ¹⁴C yr BP). Climate over the time span was under the storm regime of the Southern Westerlies and apparently uninterruptedly wet. When Subantarctic Parkland expanded, cold conditions with summer temperatures estimated at 8–9°C (7°C lower than present) resulted in episodes of glacier maxima. Climate moderated during the period of forest expansion, at which time glaciers were in a state of recession. Contrasting with the continuously wet climate of the Lake District for the period of record, climate in semi‐arid–arid, subtropical Chile underwent extended intervals of precipitation. Data from both the terrestrial and marine realm implicate the Southern Westerlies as the cause of intensified storm activity at lower latitudes. Copyright © 2000 John Wiley & Sons, Ltd.     

The fate of heavy metals in an estuarine tropical system

The scope of this work is the study of the distribution and accumulation of Cu, Cr, Cd, Pb and Hg in waters and sediments from Guanabara Bay, Rio de Janeiro. An attempt was made to balance removal to the sediments and outputs from the bay. Metal contamination in the sediments is only observed at short distances from the identified point sources. In spite of high primary productivity, the sediments are relatively poor in organic carbon content due to intensive respiratory processes already occurring in the water column. This, together with a very efficient tidal current system which brings oxygen-rich waters in contact with anoxic sediments, certainly plays an important role in heavy metal remobilization.     

Finding meaningful participation in volunteer geographic information and citizen science: a case comparison in environmental application

ABSTRACT

Volunteer geographic information (VGI) and citizen science (CS) have been used as a way to promote a form of democratization of knowledge. Crowdsourcing facilitates the massive collection of data through nonexpert volunteers. This study compares 57 VGI and CS projects through a cross-case comparison method to explore the level of involvement of participants, based on three main analytic dimensions (project rationale, actor interaction, and data flow) and 12 sub-variables. The primary goal of this research is to analyze the purpose and the role of technology in VGI and CS projects, using three matrices to explore emerging trade-offs. Finally, we synthesized the workflow of VGI and CS project and compared based on project purposes. At the end of this study, five main purposes were found among the selected projects, uncovering that data collection is the most common purpose. A general workflow can be conceptualized, but detail implementation will involve various trade-offs, especially between local involvement and large-area expert-oriented protocol implementations. By exploring diverse relationships among selected variables of analysis in VGI and CS projects, this study pretends to build a foundation for larger, global meta-analysis that can bring some transparency in the epistemic interactions between experts and nonexperts.     

Inorganic ions and trace metals bulk deposition at an Atlantic Coastal European region

The inorganic chemical composition (major ions and trace metals) of bulk deposition samples collected monthly with bulk collectors at seven Atlantic Coastal European cities (Galicia, Northwest of Spain) during wet season (September 2011 to March 2012) has been assessed and compared. Trace metals (Al, As, Ba, Co, Cr, Cu, Fe, Mn, Ni, Pb, Sr, V and Zn) were analysed in soluble fraction and non-soluble fraction (after acid extraction) of the bulk deposition by inductively coupled plasma-mass spectrometry. Major inorganic ions (Cl^?, NO₃ ^?, SO₄ ^2?, Na⁺, K⁺, Ca²⁺, Mg²⁺ and NH₄ ⁺) were analysed in the soluble fraction of the bulk deposition by capillary zone electrophoresis. Univariate analysis (ANOVA and Multiple Range Test) according to the location of each sampling site was performed. Results also suggest a great influence of cleaner Atlantic air masses. After partition coefficients and enrichment factor estimation, similar sources could be assigned for the ionic and metal composition of bulk deposition at seven urban sites.