Mid-Miocene thermal impact on the lithosphere by sub-lithospheric convective mantle material: Transition from high- to moderate-Mg magmatism beneath Vitim Plateau,Siberia

High-Mg lavas are characteristic of the mid-Miocene volcanism in Inner Asia.In the Vitim Plateau,small volume high-Mg volcanics erupted at 16-14 Ma.and were followed with voluminous moderate-Mg lavas at 14-13 Ma.In the former unit,we have recorded a sequence of(1) initial basaltic melts,contaminated by crustal material,(2) uncontaminated high-Mg basanites and basalts of transitional(K-Na-K) compositions,and(3) picrobasalts and basalts of K series;in the latter unit a sequence of(1) initial basalts and basaltic andesites of transitional(Na-K-Na) compositions and(2) basalts and trachybasalts of K-Na series.From pressure estimation,we infer that the high-Mg melts were derived from the sublithospheric mantle as deep as 150 km,unlike the moderate-Mg melts that were produced at the shallow mantle.The 14-13 Ma rock sequence shows that initial melts equilibrated in a garnet-free mantle source with subsequently reduced degree of melting garnet-bearing material.No melting of relatively depleted lithospheric material,evidenced by mantle xenoliths,was involved in melting,however.We suggest that the studied transition from high-to moderate-Mg magmatism was due to the mid-Miocene thermal impact on the lithosphere by hot sub-lithospheric mantle material from the Transbaikalian low-velocity(melting) domain that had a potential temperature as high as 1510℃.This thermal impact triggered rifting in the lithosphere of the Baikal Rift Zone.     

Biological reduction of chlorinated solvents: Batch-scale geochemical modeling

Simulation of biodegradation of chlorinated solvents in dense non-aqueous phase liquid (DNAPL) source zones requires a model that accounts for the complexity of processes involved and that is consistent with available laboratory studies. This paper describes such a comprehensive modeling framework that includes microbially mediated degradation processes, microbial population growth and decay, geochemical reactions, as well as interphase mass transfer processes such as DNAPL dissolution, gas formation and mineral precipitation/dissolution. All these processes can be in equilibrium or kinetically controlled. A batch modeling example was presented where the degradation of trichloroethene (TCE) and its byproducts and concomitant reactions (e.g., electron donor fermentation, sulfate reduction, pH buffering by calcite dissolution) were simulated. Local and global sensitivity analysis techniques were applied to delineate the dominant model parameters and processes. Sensitivity analysis indicated that accurate values for parameters related to dichloroethene (DCE) and vinyl chloride (VC) degradation (i.e., DCE and VC maximum utilization rates, yield due to DCE utilization, decay rate for DCE/VC dechlorinators) are important for prediction of the overall dechlorination time. These parameters influence the maximum growth rate of the DCE and VC dechlorinating microorganisms and, thus, the time required for a small initial population to reach a sufficient concentration to significantly affect the overall rate of dechlorination. Self-inhibition of chlorinated ethenes at high concentrations and natural buffering provided by the sediment were also shown to significantly influence the dechlorination time. Furthermore, the analysis indicated that the rates of the competing, nonchlorinated electron-accepting processes relative to the dechlorination kinetics also affect the overall dechlorination time. Results demonstrated that the model developed is a flexible research tool that is able to provide valuable insight into the fundamental processes and their complex interactions during bioremediation of chlorinated ethenes in DNAPL source zones.     

Great Silk Road on the Territory of Kazakhstan: From Past to Future

The Great Silk Road is a trade route linking the East and West which gave impetus to the development of ancient society, and Kazakhstan is the heart of the trade route. At the initial stage, intensive transaction of goods took place between the West and East through The Great Silk Road. This paper reviewed the history of development of the Silk Road and suggested that today to construct the "New Silk Road", Kazakhstan should face many issues, and take many steps to become a Eurasian hub through taking full of advantages. Above all, developing mechanisms of integration and sustainable development is our urgent need.     

Strontium stable isotopes fractionate in the soil environments?

This study shows that the stable isotopic composition of strontium (the ⁸⁸Sr/⁸⁶Sr ratio expressed as δ^88/86Sr value relative to the NBS987 standard) varies significantly in sedimentary terrestrial environments. The abundances of ⁸⁶Sr, ⁸⁸Sr isotopes were analyzed by MC-ICP-MS “Nu Plasma”. All studied rocks and waters show δ^88/86Sr values that are distinctly different from the measured NBS987 standard (yielding 0.01 ± 0.05‰, all errors are reported as 2σ). Modern corals from the northern Gulf of Aqaba, Red Sea yielded significantly different value than seawater (δ^88/86Sr = 0.22 ± 0.07‰, compared to 0.35 ± 0.06‰, respectively), in an excellent correlation with the δ^88/86Sr analyses reported by Fietzke and Eisenhauer [Fietzke, J., Eisenhauer, A., 2006. Determination of temperature-dependent stable strontium isotopes (⁸⁸Sr/⁸⁶Sr) fractionation via bracketing standard MC-ICP-MS. Geochm. Geophys. Geosyst. 7 (no. 8)] on other coral samples. All carbonate samples that originated in the marine environment: corals (porites and acropora from the northern Gulf of Aqaba); Cretaceous limestone and runoff from the Judea Mountains as well as lacustrine evaporitic aragonite (Dead Sea); and Red Sea and Atlantic seawater yield an average δ^88/86Sr value of 0.26 ± 0.1‰. On the other hand, secondary materials (products of chemical weathering) from the terrestrial environment of the Judea Mountain such as terra rossa soil and speleothem calcite (that derives its Sr from the above-lying soil) yielded significantly lower δ^88/86Sr value of − 0.17 ± 0.06‰. This indicates that strontium isotopes fractionate in the soil environment calling for a possible development of strontium isotopes as a tracer for processes of chemical weathering and pedogenesis.     

Large‐scale regional delineation of riparian vegetation in the arid and semi‐arid Pilbara region,WA

Multiscene Landsat 5 TM imagery, Principal Component Analysis, and the Normalized Difference Vegetation Index were used to produce the first region‐scale map of riparian vegetation for the Pilbara (230,000 km²), Western Australia. Riparian vegetation is an environmentally important habitat in the arid and desert climate of the Pilbara. These habitats are supported by infrequent flow events and in some locations by groundwater discharge. Our analysis suggests that riparian vegetation covers less than 4% of the Pilbara region, whereas almost 10.5% of this area is composed of groundwater dependent vegetation (GDV). GDV is often associated with open water (river pools), providing refugia for a variety of species. GDV has an extremely high ecological value and are often important Indigenous sites. This paper demonstrates how Landsat data calibrated to Top of Atmosphere reflectance can be used to delineate riparian vegetation across 16 Landsat scenes and two Universal Transverse Mercator spatial zones. The proposed method is able to delineate riparian vegetation and GDV, without the need for Bidirectional Reflectance Distribution Function correction. Results were validated using ground truth data from local and regional scale vegetation surveys.     

Plankton distribution associated with frontal zones in the vicinity of the Pribilof Islands

We studied the effect of four types of fronts, the coastal front, the middle front, the shelf partition front and the shelf break front on the quantitative distribution and the composition of plankton communities in the Pribilof area of the eastern Bering Sea shelf in late spring and summer of 1993 and 1994. The coastal fronts near St. Paul and St. George Islands and the coastal domains encircled by the fronts featured specific taxonomic composition of planktonic algae, high abundance and production of phytoplankton, as well as large numbers of heterotrophic nanoplankton. The coastal fronts also were characterized by high values of total mesozooplankton biomass, high concentrations of Calanus marshallae, as well as relatively high abundances of Parasagitta setosa and Euphausiacea compared to surrounding shelf waters. We hypothesize that wind-induced erosion of a weak thermocline in the inner part of the coastal front as well as transfrontal water exchange in subthermocline layers result in nutrient enrichment of the euphotic layer in the coastal fronts and coastal domains in summer time. This leads to prolonged high primary production and high phytoplankton biomass. In this paper a new type of front—the shelf partition front located 45–55 km to the north-east off St. Paul Island—is described, which is assumed to be formed by the flux of oceanic domain waters onto the shelf. This front features a high abundance of phytoplankton and a high level of primary production compared to the adjacent middle shelf. Near the southwestern periphery of the front a mesozooplankton peak occurred, composed of C. marshallae, with biomass in the subthermocline layer, reaching values typical for the shelf break front and the highest for the area. High abundance of phyto- and zooplankton as well as heterotrophic nanoplankton and elevated primary production were most often observed in the area adjacent to the shelf break front at its oceanic side. The phyto- and mesozooplankton peaks here were formed by oceanic community species. The summer levels of phytoplankton numbers, biomass and primary production in the shelf break frontal area were similar to those reported for the outer and middle shelf during the spring bloom and the coastal domains and coastal fronts in summer. In the environment with a narrow shelf to the south of St. George Island, the mesozooplankton peak was observed at the inner side of the shelf break front as close as 20 km from the island shore and was comprised of a “mixed” community of shelf and oceanic species. The biomass in the peak reached the highest values for the Pribilof area at 2.5 g mean wet weight m⁻³ in the 0–100 m layer. Details of the taxonomic composition and the numbers and production of phytoplankton hint at the similarity of processes that affect the phytoplankton summer community in the coastal domains of the islands, at the coastal fronts, and at the oceanic side of the shelf break front. The middle front was the only one that had no effect on plankton composition or its quantitative characteristics in June and July. Location of a variety of frontal productive areas within 100 km of the Pribilof Islands creates favorable foraging habitat for higher trophic level organisms, including sea birds and marine mammals, populating the islands.     

The role of the Spitsbergen shear zone in determining morphology,segmentation and evolution of the Knipovich Ridge

In 1989–1990 the SeaMARC II side-looking sonar and swath bathymetric system imaged more than 80 000 km² of the seafloor in the Norwegian-Greenland Sea and southern Arctic Ocean. One of our main goals was to investigate the morphotectonic evolution of the ultra-slow spreading Knipovich Ridge from its oblique (115° ) intersection with the Mohns Ridge in the south to its boundary with the Molloy Transform Fault in the north, and to determine whether or not the ancient Spitsbergen Shear Zone continued to play any involvement in the rise axis evolution and segmentation. Structural evidence for ongoing northward rift propagation of the Mohns Ridge into the ancient Spitsbergen Shear Zone (forming the Knipovich Ridge in the process) includes ancient deactivated and migrated transforms, subtle V-shaped-oriented flank faults which have their apex at the present day Molloy Transform, and rift related faults that extend north of the present Molloy Transform Fault. The Knipovich Ridge is segmented into distinct elongate basins; the bathymetric inverse of the very-slow spreading Reykjanes Ridge to the south. Three major fault directions are detected: the N-S oriented rift walls, the highly oblique en-echelon faults, which reside in the rift valley, and the structures, defining the orientation of many of the axial highs, which are oblique to both the rift walls and the faults in the axial rift valley. The segmentation of this slow spreading center is dominated by quasi stationary, focused magma centers creating (axial highs) located between long oblique rift basins. Present day segment discontinuities on the Knipovich Ridge are aligned along highly oblique, probably strike-slip faults, which could have been created in response to rotating shear couples within zones of transtension across the multiple faults of the Spitsbergen Shear Zone. Fault interaction between major strike slip shears may have lead to the formation of en-echelon pull apart basins. The curved stress trajectories create arcuate faults and subsiding elongate basins while focusing most of the volcanism through the boundary faults. As a result, the Knipovich Ridge is characterized by Underlapping magma centers, with long oblique rifts. This style of basin-dominated segmentation probably evolved in a simple shear detachment fault environment which led to the extreme morphotectonic and geophysical asymmetries across the rise axis. The influence of the Spitsbergen Shear Zone on the evolution of the Knipovich Ridge is the primary reason that the segment discontinuities are predominantly volcanic. Fault orientation data suggest that different extension directions along the Knipovich Ridge and Mohns Ridge (280° vs. 330°, respectively) cause the crust on the western side of the intersection of these two ridges to buckle and uplift via compression as is evidenced by the uplifted western wall province and the large 60 mGal free air gravity anomalies in this area. In addition, the structural data suggest that the northwards propagation of the spreading center is ongoing and that a `normal' pure shear spreading regime has not evolved along this ridge. This revised version was published online in November 2006 with corrections to the Cover Date.     

Jusa and Barsuchi Log Volcanogenic Massive Sulfide Deposits from the Southern Urals of Russia: Devonian Analogs of the Kuroko Deposits of NE Honshu, Japan

Chemical analysis of 60 samples from the Jusa and Barsuchi Log volcanogenic massive sulfide (VMS) deposits by inductively coupled plasma–mass spectrometry shows that, on average, the Jusa deposit is more enriched in the chalcophilic elements than the Barsuchi Log deposit, whereas the Barsuchi Log deposit is more enriched in the lithogenous elements and Te. In addition, the yellow ores in these deposits are more enriched on average in Cu, As and Mo and the black ores more enriched in Zn, Ga, Cd, Sb, Ba , Hg and Pb relative to each other. Both these deposits are similar in composition to the Kuroko deposits of NE Honshu and may be considered to be analogs of these deposits. The Kuroko deposits, however, contain much higher concentrations of As, Ag, Sb, Ba, Hg and lower contents of Te on average than the Jusa and Barsuchi Log deposits. Based on the higher contents of Te in the Barsuchi Log deposit compared to the Jusa deposit, as well as on textural considerations, it is concluded that the Barsuchi Log deposit is intermediate between the Urals- and Kuroko-type deposits, whereas the Jusa deposit is more analogous to the Kuroko-type deposits. Based on the compositional data presented here, the Jusa and Barsuchi Log deposits may be described as Zn-Pb-Cu-Ba deposits rather than as Zn-Cu-Ba deposits, as the Baimak-type deposits of the west Magnitogrosk zone have previously been described.