A Study of the Thermodynamics and Kinetics of Copper Adsorption Using Chemically Modified Rice Husk

The use of rice husk as a low cost adsorbent for the removal of copper from wastewater has been explored in a laboratory scale experiment. The rice husk used for the study was treated with alkali to increase the sorption properties. The influence of metal ion concentration, weight of biosorbent, stirring rates, temperature and pH were also evaluated, and the results are fitted using adsorption isotherm models. From the experimental results it was observed that almost 90–98% of the copper could be removed using treated rice husk. The Langmuir adsorption isotherm, Freundlich isotherm and Tempkin isotherm models were used to describe the distribution of copper between the liquid and solid phases in batch studies, and it was observed that the Langmuir isotherm better represented the adsorption phenomenon. The experimental rate constant, activation energy, Gibbs free energy, enthalpy and entropy of the reaction were calculated in order to determine the mechanism of the sorption process.     

Effects of water extraction in a vulnerable phreatic aquifer: Consequences for groundwater contamination by pesticides, Sint-Jansteen area, The Netherlands

Pesticides are a potential threat to the quality of extracted groundwater when the water-supply area is used for agricultural activities. This problem is discussed for the water-supply area of Sint-Jansteen, The Netherlands, where measured pesticide concentrations in the extracted water regularly exceed EU limits (0.1 μg/L). Groundwater samples taken from the aquifer within the water-supply area show low contamination, but samples taken from the extracted water occasionally contain pesticides, making the water inadequate for drinking-water purposes. The more intense contamination of the extracted water is caused by the change in the natural groundwater flow pattern near the extraction wells. In this area, pesticide use cannot be avoided easily, and an approach is given to differentiate pesticide use in the area according to expected travel time toward the wells and the chemical characteristics of the pesticides. A groundwater flow model for the area is developed and the effects of groundwater extraction on the natural flow pattern are evaluated. Using particle tracking, the travel-time zones are determined. Combining these results and the degradation behavior of certain pesticides led to an optimal scheme to integrate agricultural activities and groundwater extraction in the area. This is illustrated for five different types of pesticides (atrazine, simazine, bentazone, MCPA, and mecoprop). Received, October 1998/Revised, July 1999, September 1999/Accepted, November 1999     

Evaluation of RADARSAT ScanSAR synthetic aperture radar data for rice crop inventory and monitoring

Radarsat ScanSAR Narrow (SN2) data acquired on July 24 and August 17, 1997 were used to analyse the signature of rice crop in West Bengal, India. The analysis showed that the lowland practice of cultivation gives a distinct signature to rice due to the initial water background. The relatively stable backscatter from water bodies in temporal data enhanced the separability of rice fields from water using two date data. Around 94 per cent classification accuracy was achieved for rice crop using two date data. It was feasible to discriminate rice sub-classes based on their planting period like early and late crop. The analysis indicates the suitability of ScanSAR data for large area rice crop monitoring as it has a wide swath of 300 km.     

Quantification of stability improvement of a dump through biological reclamation

An integrated study on biological stabilisation of a dump slope has indicated that biological reclamation with grass and tree species should be considered for long term stability of this coal mine dump in India. The grasses have greater soil binding capacity and help to control soil erosion and improve dump stability. Native grasses such as Bamboo (Dendrocalmus strictus) and Kashi (Saccharum spontaneum) are the important constituents of grass species which can stabilise the dump slopes. Field observation of growth performance of grasses have indicated that mean grass height, root depth and below-ground root biomass are 185 cm (±68), 45 cm (±5) and 467 g m^–2 (±170), respectively after three years of grass growth on Mudidih overburden dump slope in India. The growth performance of tree species, namely Sisum (Dalbergia sisoo) and Subabool (Leucena lecocephala), in terms of height, diameter increment, below-ground biomass and root depth have shown mean values of 219 cm (±94), 48 mm (±6), 4.0 kg m^–2 (±1.5) and 1 m (±0.1), respectively. This acts as biological fertility which helps in root proliferation and enhancement of dump stability. From the numerical modelling it is suggested that roots of these grass and tree species have significantly enhanced the factor of safety of dump from 1.4 to 1.8 and therefore have a positive role in maintaining long term stability.     

Gravitational Field of Domain Walls in Higher Dimension

In this paper, we study the gravitational field of domain wall in fivedimensional space-time. Exact solutions of Einstein's equations for a scalarfield with a potential V(Ø) are presented, describing thegravitational field of plane symmetric domain walls. The solution showsthat the energy density as well as pressure in the perpendicular directionon both sides of the walls to be reflection symmetric with respect to thewalls.PACS numbers: 98.80 cq, 0450     

A subsidiary fast-diffusing substitution mechanism of Al in forsterite investigated using diffusion experiments under controlled thermodynamic conditions

Diffusion of Al in synthetic forsterite was studied at atmospheric pressure from 1100 to 1500 °C in air along [100] with activities of SiO₂, MgO and Al₂O₃ (a_SiO2, a_MgO and a_Al2O3) buffered. At low a_SiO2, the buffer was forsterite + spinel + periclase (fo + sp + per) at all temperatures, while at high a_SiO2 and subsolidus conditions a variety of three-phase assemblages containing forsterite and two other phases from spinel, cordierite, protoenstatite or sapphirine were used at 1100–1350 °C. Experiments at high a_SiO2 and 1400 °C used forsterite + protoenstatite + melt (fo + en + melt), and at 1500 °C, fo + melt. The resulting diffusion profiles were analysed by LA–ICP–MS in scanning mode. Diffusion profiles in the high a_SiO2 experiments were generally several hundred microns in length, but diffusion at low a_SiO2 was three orders of magnitude slower than in high a_SiO2 experiments carried out at the same temperature, producing short profiles only a few microns in length and close to the spatial resolution of the analytical method. Interface concentrations of Al in the forsterite, obtained by extrapolating the diffusion profiles to the crystal/buffer interface, were only a fraction of those expected at equilibrium, and varied among the differing buffer assemblages according to (a_Al2O3)^1/2 and (a_SiO2)^3/4, pointing to the substitution of Al in forsterite by an octahedral-site, vacancy-coupled (OSVC) component with the stoichiometry Al _4/3 ³⁺ vac_2/3SiO₄, whereas the main substitution expected from previous equilibrium studies would be the coupled substitution of 2 Al for Mg + Si, giving the stoichiometry MgAl₂O₄. It is proposed that this latter substitution is not seen on the length scales of the present experiments because it requires replacement of Si by Al on tetrahedral sites, and is accordingly rate-limited by the slow diffusivity of Si. Instead, diffusion of Al by the OSVC mechanism is relatively fast, and at high a_SiO2, even faster than Fe–Mg interdiffusion.     

A study on soil physico-chemical, microbial and metal content in Sukinda chromite mine of Odisha, India

Soil samples from chromite mining site and its adjacent overburden dumps and fallow land of Sukinda, Odisha, were analysed for their physico-chemical, microbial and metal contents. Chromite mine soils were heterogenous mixture of clay, mud, minerals and rocks. The pH of the soils ranges between 5.87 and 7.36. The nutrient contents of the mine soils (N, P, K and organic C) were found to be extremely low. Analysis of chromite mine soils revealed accumulation of a number of metals in high concentrations (Fe > Cr > Mn > Ni > Zn > Pb > Sr) which exceeded ecotoxicological limits in soil. Correlation and cluster analysis of metals revealed a strong relation between Cr, Ni, Fe, Mn among the different attributes studied. Assessment of different microbial groups such as fungi, actinomycetes and bacteria (heterotrophic, spore forming, free-living nitrogen fixing, phosphate solubilising and cellulose degrading) from mine soils were found to be either extremely low or absent in some soil samples. Further chromium tolerant bacteria (CTB) were isolated using 100 mg/L Cr(VI) enriched nutrient agar medium and were screened for their tolerance towards increasing concentrations of hexavalent chromium and other toxic metals. Out of 23 CTB isolates, three bacteria tolerated up to 900 mg/L, 6 up to 500 mg/L, 20 up to 200 mg/L of Cr(VI). These bacteria were also found to be sensitive towards Cu > Co > Cd and very few CTB strains could show multiple metal tolerance. These strains have great scope for their application in bioremediation of toxic chromium ions in presence of other metals ions, which needs to be explored for their biotechnological applications.     

A comparative study of the modelling of cement hydration and cement-rock laboratory experiments

The use of cement and concrete as fracture grouting or as tunnel seals in a geological disposal facility for radioactive wastes creates potential issues concerning chemical reactivity. From a long-term safety perspective, it is desirable to be able model these interactions and changes quantitatively. The ‘Long-term Cement Studies’ (LCS) project was formulated with an emphasis on in situ field experiments with more realistic boundary conditions and longer time scales compared with former experiments. As part of the project programme, a modelling inter-comparison has been conducted, involving the modelling of two experiments describing cement hydration on one hand and cement-rock reaction on the other, with teams representing the NDA (UK), Posiva (Finland), and JAEA (Japan).This modelling exercise showed that the dominant reaction pathways in the two experiments are fairly well understood and are consistent between the different modelling teams, although significant differences existed amongst the precise parameterisation (e.g. reactive surface areas, dependences of rate upon pH, types of secondary minerals), and in some instances, processes (e.g. partition of alkali elements between solids and liquid during cement hydration; kinetic models of cement hydration). It was not conclusive if certain processes such as surface complexation (preferred by some modellers, but not by others) played a role in the cement-rock experiment or not. These processes appear to be more relevant at early times in the experiment and the evolution at longer timescales was not affected. The observed permeability profile with time could not be matched. The fact that no secondary minerals could be observed and that the precipitated mass calculated during the simulations is minor might suggest that the permeability reduction does not have a chemical origin, although a small amount of precipitates at pore throats could have a large impact on permeability.The modelling exercises showed that there is an interest in keeping the numerical models as simple as possible and trying to obtain a reasonable fit with a minimum of processes, minerals and parameters. However, up-scaling processes and model parameterisation to the timescales appropriate to repository safety assessment are of considerable concern. Future modelling exercises of this type should focus on a suitable natural or industrial analogue that might aid assessing mineral-fluid reactions at these longer timescales.     

Observation based analysis of the growth of MJO time scale from its nonlinear scale interactions with the synoptic scales

Summary The present paper addressed the issue of growth of planetary boundary-layer fluxes on the time scale of MJO based on ECMWF reanalysis daily data of 180 days covering April–September, 2001. Diagnostic analysis of this data set utilises computations of moisture and sensible heat fluxes in the frequency domain which involve nonlinear interactions phenomena of MJO time scale with the synoptic scales. Basically the whole computations performed are based on surface similarity theory and Richardson number dependent K-theory in the surface and planetary boundary layer (PBL), respectively, both invoke triple product nonlinearilies. Present observational study shows that among the totality of the triads participating in phase-locking phenomena, a prominent band of those reside in the MJO time scales (30 to 60 days) and the synoptic time scales (3 to 7 days). The study suggests that the low frequency variability on MJO time scale in moisture and sensible heat flux arises from its nonlinear interactions with synoptic time scales. The results show that the phases of the three interacting oscillations associated with specific humidity/SST, Richardson number dependent instability factor and wind shear are positive and reasonably close to each other. The amplitudes of the synoptic scale oscillations are not insignificant compared to that of MJO. These dynamical aspects regarding the phases and amplitudes of the three participating oscillations favour the nonlinear interactions of MJO to the synoptic scales and thus lead to rapid exchange of energy transfer to the former.Visiting scientist from Indian Institute of Tropical Meteorology, Pune-411008, India.