On the production of traveling ionospheric disturbances by atmospheric gravity waves

This paper deals with how atmospheric gravity waves produce the traveling ionospheric disturbances (TIDs) that are observed by ionosondes. It is shown that, rather than directly producing variations of ionospheric height, a likely mechanism involves changes in ionization density by gradients in the horizontal atmospheric gravity wave air motion. These density changes can be observed as variations of the height of an ionospheric isodensity surface (the usual way of measuring TIDs). This mechanism involving enhancement/depletion of ionospheric density requires quite moderate atmospheric gravity wave air motion speeds, and works well at almost all latitudes.     

Changes in physicochemical properties of biodiesel after degradation and remediation

Biodiesel is the main substitute for petrodiesel being constituted by several alkyl esters including unsaturated compounds. It can undergo partial oxidation when stored for long periods and transported over long distances. The aims of this study were to analyze the impact of the oxidation process on the physicochemical properties of biodiesel and its remediation through distillation and esterification. Due to its high susceptibility to oxidation, sunflower biodiesel was used as a model. Specific mass, cloud point, cold filter plugging point, oxidation stability and iodine value were the properties analyzed. The results revealed that the treatments affected each sample differently, and in some cases the product after remediation had properties close to or even better than the initial biodiesel. The results reported here indicate that although biodiesel undergoes degradation during storage and transport, this does not mean the affected fuel cannot be marketed. Some important properties can be recovered with simple treatment.     

Lidar observations of atmospheric sodium at an equatorial location

Lidar measurements of upper atmospheric sodium were made at Alcântara (2°20′ S, 44°30′ W), Brazil, on 8 days during the month of November 1996. These are the first sodium measurements to be reported from an almost equatorial location. The average sodium distribution at Alcântara was found to be very similar to the annual mean for São José dos Campos (23° S), but about 1 km higher than the November mean value of 92 km for the latter site. Only one, weak, sporadic sodium layer was observed during more than 26 h of observations, an occurrence frequency much less than that seen at low latitude sites in the northern hemisphere. A survey of the observations of sporadic layers at various locations suggests that both magnetic dip and declination angles might influence their rate of occurrence.     

Detection of integron integrase genes on King George Island,Antarctica

The presence and diversity of class 1 integrase gene (intI) sequences were evaluated by PCR using previously designed primers. Two clone libraries were constructed from DNA in sediment and microbial ma...     

Expansion of an invasive coral species over Abrolhos Bank,Southwestern Atlantic

Invasive coral species of the genus Tubastraea have been increasingly recorded in Southwestern Atlantic waters since the 1980s. Their invasion and infestation are mainly related to port and oil exploration activities. For the first time the presence of Tubastraea tagusensis colonies is reported in Espírito Santo State, colonizing a port shore area, and incrusting oil/gas platform structures situated in the southern Abrolhos Bank, which is part of the most important coral reef system of the South Atlantic Ocean. Tubastraea colonies exhibit fast growth and high recruitment rates, and colonized 40% of the analyzed structures in just four years. The projection of port and oil/gas industry growth for the Espírito Santo State (more than 300%) highlights an alert to the dispersal of this alien species to natural areas.     

Input of geophysics to understand hydrogeology towards the assessment of geoenvironmental conditions in Beira city,Mozambique

As the fourth largest city in Mozambique, and located right beside the Indian Ocean, Beira faces sanitary and environmental problems that are a strong concern to the local and national authorities. One of the major problems that Beira city has to deal with is the existence of undrinkable groundwater in many dug-wells that supply a large amount of the city population. The cooperation project among Direcção Nacional de Geologia of Mozambique, the Laboratório Nacional de Energia e Geologia of Portugal and the Instituto de Apoio ao Desenvolvimento Português that took place from 2007 to 2011 has as one of its main goals the production of the Geological and Geoenvironmental Maps of Beira at scale 1:50,000, intending to create a tool to support the implementation of governmental policies regarding sustainable groundwater and natural resources exploitations, land management and environmental protection. These goals were achieved through the identification, characterization and mapping of the different geological units and the evaluation of the city environmental problems regarding water and soil contamination in urban areas, involving the use of several methodologies that were subsequently integrated and jointly interpreted. These comprised remote sensing techniques, hydrogeology analysis and evaluation and the use of geochemistry and electrical geophysical methods. This work emphasizes the input of geophysical and hydrogeological methods to assess the geoenvironmental conditions of Beira, namely those related with the prediction of occurrence of saline and brackish water in the shallow dug-wells that supply a large amount of Beira populations, especially in the crowded suburbs. Several geophysical surveys using electrical and electromagnetic methods were conducted and interpreted regarding the evaluation of the several hypotheses that were stood for this feature. Results are related with hydrogeological conditions and organic and inorganic hydrochemical analysis. Considering these facts, this study was an important input for mapping areas with saline and brackish water imprisoned in the subsurface geological formations, using a wider set of methodologies that were integrated in these results.     

Observations and model calculations of an additional layer in the topside ionosphere above Fortaleza, Brazil

Calculations using the Sheffield University plasmasphere ionosphere model have shown that under certain conditions an additional layer can form in the low latitude topside ionosphere. This layer (the F3 layer) has subsequently been observed in ionograms recorded at Fortaleza in Brazil. It has not been observed in ionograms recorded at the neighbouring station São Luis. Model calculations have shown that the F3 layer is most likely to form in summer at Fortaleza due to a combination of the neutral wind and theE × B drift acting to raise the plasma. At the location of São Luis, almost on the geomagnetic equator, the neutral wind has a smaller vertical component so the F3 layer does not form.     

Long-term TNT and DNT contamination: 1-D modeling of natural attenuation in the vadose zone: case study,Portugal

The vadose zone of a trinitrotoluene (TNT) and dinitrotoluene (DNT) contaminated site was investigated to assess the mobility of those explosives under natural conditions. Located in the left margin of the River Tejo Basin, Portugal, the site is located on unconsolidated sediments. Wastewaters associated with the 50-year explosives production were disposed in excavated ponds, from where water would infiltrate and pollute the unsaturated and saturated parts of the local aquifers. Two boreholes were drilled to 9 m depth in such a former waste pond to investigate the contaminant’s fate in the vadose zone. Sediment samples were taken every 1–2 m for analysis of the poly-nitroaromatics (p-NACs) and organic volatile compounds, pH, organic carbon content, cation exchange capacity and grain size analysis. The main contaminant was TNT representing >70 % of the total p-NACs concentration that peaked approximately 7 mg/kg in one borehole, even if the median in both boreholes was of ~1 mg/kg. DNT was 4–30 % of the total p-NACs and nitrotoluene (NT), up to 5 %. No other (volatile) organic compound was detected. The predominance of TNT as the main contaminant implies that any natural mass reduction has been inefficient to clean the site. Several 1-D model simulations of p-NACs cleaning of the vadose zone under natural conditions indicated that the most probable scenario of combined advection and partitioning will only remove TNT after 10’s of years, whereas DNT and NT will hardly be removed. Such low concentrations and long times for the p-NACs removal, suggest that by now those compounds have been washed-out to a level below standard limits.     

Diurnal and seasonal variations of the oh (8, 3) airglow band and its correlation with OI 5577 Å

In this paper the results of OH (8,3) emission intensity and rotational temperature measurements made in the Brazilian sector (23°S) from 1972 to 1974 are presented. Diurnal variations of both the parameters are found to fall into distinct classes, showing significant seasonal effects. A correlative study with the OI 5577 Å emission measured simultaneously is also presented. It is shown that both the phase and amplitude of the major part of the mean nocturnal intensity variations of the two emissions can be explained by the density and temperature perturbations caused by the solar semidiurnal tide. The OH emission is found to increase slightly during magnetic disturbances.     

Extracts of the seaweed Bifurcaria bifurcata display antifungal activity against human dermatophyte fungi

Bifurcaria bifurcata is a seaweed of the Order Fucales(Ochrophyta, Phaeophyceae) that can be found all year round along the Portuguese Atlantic shore. Although it is considered edible in some countries,its biotechnological potential has not yet been assessed in detail and here we report its antimicrobial potential against human dermatophyte fungi. Three samples were harvested from Baleal Island(Peniche, Portugal)harvested in winter(BbPe); from Aguda Beach(Arcozelo, Vila Nova de Gaia, Portugal), harvested in autumn(BbAg) and a sample obtained by culturing the Aguda sample under laboratory conditions(BbLC).A broth macrodilution assay was applied to determine the MIC(minimum inhibitory concentration) and MLC(minimum lethal concentration) of the B. bifurcata extracts. Results show that the BbPe MeOH extracts were the most effective and had higher antifungal activity against all the tested dermatophyte strains than the BbLC and BaAg extracts [Epidermophyton floccosum FF9(100-200 μg/mL MIC; 200 μg/mL MLC), Microsporum canis FF1(400 μg/mL MIC; 400 μg/mL MLC), Trichophyton mentagrophytes FF7(100 μg/mL MIC; 800 μg/mL MLC), M. gypseum CECT 2908(800 μg/mL MIC; 800 μg/mL MLC), T.mentagrophytes var. interdigitale CECT 2958(800 μg/mL MIC; 800 μg/mL MLC), T. rubrum CECT 2794(200 μg/mL MIC; 400 μg/mL MLC)]. In fact, only E. floccosum FF9 was sensitive to BbAg and BbLC MeOH extracts. To our knowledge, this is the first report of antifungal activity of B. bifurcata against human dermatophyte fungi.