Geochronological data on recent magmatism of the Aegean Sea

Radiometric ages and chemical character of the Tertiary and Quaternary volcanics of the Aegean Sea indicate a gap between the Recent calc-alkaline volcanism and the Tertiary one. This latter reached its climax in the Oligocene—Late Miocene. The two calc-alkaline magmatisms are related to distinct subduction processes.     

Magnetic properties and cation ordering of nanopowders of the synthetic analogue of kuramite, Cu3SnS4

An extensive characterisation of the magnetic properties of synthetic powders of kuramite, with formal composition Cu₃SnS₄, was performed. Powders were investigated through superconducting quantum interference device (SQUID) magnetometry, electron paramagnetic resonance (EPR) spectroscopy, X-ray powder diffraction (XRPD), scanning and transmission electron microscopies (SEM and TEM) and microanalysis. SEM and TEM reveal the presence of nanodimensioned particles. XRPD clearly shows that Cu₃SnS₄ crystallised in a cubic sphalerite-type structural model, in spite of the stannite-type tetragonal structure described for the natural phase. This difference arises from a full random distribution of cations. Synthetic kuramite nanopowders exhibit a marked paramagnetism, originated by the presence of Cu(II), definitely assessed by EPR measurements. Moreover, the overall magnetic behaviour of the sample cannot be simply ascribed to diluted paramagnetism, and this suggests the presence of strong superexchange interactions among Cu(II) ions even at room temperature. The main consequences of these results are the definitive assessment of the chemical formula Cu(I)₂Cu(II)SnS₄ and of a random distribution of Cu(II), Cu(I) and Sn(IV) ions within the available tetrahedral sites.     

Drying and dying of a subducted slab: Coupled Li and B isotope variations in Western Anatolia Cenozoic Volcanism

In lavas spanning ~ 10Ma of subduction-related volcanism in Western Anatolia, we observe remarkably similar patterns of δ⁷Li and δ¹¹B variation. In this setting, magmatism records a transition from calc–alkaline to ultrapotassic character, consistent with overall lower mean extents of melting, and a changing mantle source that reflects a fractionating, higher temperature slab input consistent with the gradual cessation of subduction. Subsequent rift-related intraplate magmatism record δ⁷Li signatures within the range observed for MORBs and OIBs, indicating an abrupt transition to a mantle source unmodified by subduction.     

The campanian ignimbrite: a major prehistoric eruption in the Neapolitan area (Italy)

A geological, chemical and petrographical study of the Campanian ignimbrite, a pyroclastic flow deposit erupted about 30,000 years ago on the Neapolitan area (Italy), is reported. The ignimbrite covered an area of at least 7,000 km²; it consists of a single flow unit, and the lateral variations in both pumice and lithic fragments indicate that the source was located in the Phlegraean Fields area. Textural features, areal distribution and its morphological constraints suggests that the eruption was of the type of highly expanded low-temperature pyroclastic cloud. The original composition was strongly modified by post-depositional chemical changes involving most of the major and trace elements. No primary differences in the composition of the magma have been recognized. The Campanian ignimbrite is a nearly saturated potassic trachyte, similar to many other trachytes of the Quaternary volcanic province of Campania. Its chemistry indicates an affinity with the so-called «low-K association» of the Roman volcanic province.     

Esterase activities in the bivalve mollusc Adamussium colbecki as a biomarker for pollution monitoring in the Antarctic marine environment

Marine environments are continuously being threatened by a large number of xenobiotics from anthropogenic sources. Even in sparsely populated and relatively pristine areas, such as Antarctica, hazardous chemicals can pose a serious environmental problem. The main aims of the present study were to (1) validate and optimize an analytical technique utilizing a microtitre-plate photometer to ascertain background levels of esterase activities in the Antarctic bivalve Adamussium colbecki, (2) carry out in situ monitoring of esterase activities to assess any potential environmental impacts of the Italian Scientific Antarctic Base "Terra Nova Bay" on the surrounding marine area. Results showed the presence of organophosphorous-sensitive cholinesterase (ChE) and carboxylesterase (CbE) activities in the gills of A. colbecki and optimal assay conditions were comparable with those found for bivalve species from temperate areas. A higher sensitivity of ChE versus acetylthiocholine activity in A. colbecki to chlorpyrifos compared to species from temperate areas may also be inferred. The in situ study indicated no differences in the environmental quality of the three study sites located around the Italian Base.     

Interpreting the role of proximity on Industrial District competitiveness using a complexity science-based view and Systems Dynamics simulation

The paper investigates how proximity affects Industrial District competitiveness. We adopt the complexity theory by analyzing the influence of the proximity on the Industrial District adaptive capacity. Our argument in fact is that the more adaptive the Industrial District, the more the competitive success. Based on the complexity theory, we identify the structural features that allow Industrial District adaptation and their best values. Then, by developing a computational model based on the Systems Dynamics, we conduct a simulation analysis to evaluate the influence of proximity on the values of Industrial District structural features affecting its adaptive capacity. Results show that too much proximity is detrimental for the Industrial District competitiveness.     

Experimental models of extension of continental lithosphere weakened by percolation of asthenospheric melts

Analogue models are used to investigate extension of a continental lithosphere weakened by asthenospheric melts percolating through the upper mantle, a process that has been hypothesised to control the opening of the Ligurian Tethys. Models were performed in a centrifuge apparatus and reproduced, by using materials such as sand and viscous mixtures, extension of 60-km thick, three-layer continental lithosphere floating above the asthenosphere. The percolated lithospheric mantle was assumed to be characterised by a rheological behaviour similar to that of the asthenosphere. Two sets of experiments investigated the influence on deformation of (1) the thickness of the percolated mantle and the associated strength contrast between the normal and weakened lithosphere, and (2) the lateral width of the weakened zone. Model results suggest that mantle percolation by asthenospheric melts is able to promote strong localised thinning of the continental lithosphere, provided that a significant thickness of the lithospheric mantle is weakened by migrating melts within a narrow region. Strain localisation is maximised for percolation of the whole lithospheric mantle and strong strength contrast between the normal and weakened lithosphere. Under these conditions, the thickness of the lithosphere may be reduced to less than 12 km in 3 Ma of extension. Conversely, localised thinning is strongly reduced if the thickness of the percolated zone is ≤1/3 of the thickness of the whole lithospheric mantle and/or the lithosphere is weakened over wide regions. Overall, model results support the working hypothesis that mantle percolation by asthenospheric melts is a controlling factor in the transition from distributed continental deformation to localised oceanic spreading.     

A continuous stable isotope record from the penultimate glacial maximum to the Last Interglacial (159–121 ka) from Tana Che Urla Cave (Apuan Alps,central Italy)

Relatively few radiometrically dated records are available for the central Mediterranean spanning the marine oxygen isotope stage 6–5 (MIS 6–5) transition and the first part of the Last Interglacial. Two flowstone cores from Tana che Urla Cave (TCU, central Italy), constrained by 19 U/Th ages, preserve an interval of continuous speleothem deposition between ca. 159 and 121 ka. A multiproxy record (δ¹⁸O, δ¹³C, growth rate and petrographic changes) obtained from this flowstone preserves significant regional-scale hydrological changes through the glacial/interglacial transition and multi-centennial variability (interpreted as alternations between wetter and drier periods) within both glacial and interglacial stages. The glacial stage shows a wetter period between ca. 154 and 152 ka, while the early to middle Last Interglacial period shows several drying events at ca. 129, 126 and 122 ka, which can be placed in the wider context of climatic instability emerging from North Atlantic marine and NW European terrestrial records. The TCU record also provides important insights into the evolution of local environmental conditions (i.e. soil development) in response to regional and global-scale climate events.     

A review of near-surface QS estimation methods using active and passive sources

Journal of Seismology - Seismic attenuation and the associated quality factor (Q) have long been studied in various sub-disciplines of seismology, ranging from observational and engineering...